[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/phosphoryle-trichloride-wikipedia\/#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/phosphoryle-trichloride-wikipedia\/","headline":"Phosphoryle trichloride – Wikipedia","name":"Phosphoryle trichloride – Wikipedia","description":"before-content-x4 A wikipedia article, free l’encyclop\u00e9i. Phosphoryle trichloride Phosphoryle trichloride molecule Identification UICPA name Phosphoryle trichloride Synonyms after-content-x4 Phosphorus oxychloride","datePublished":"2020-02-03","dateModified":"2020-02-03","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/author\/lordneo\/#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/author\/lordneo\/","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/e\/e0\/Phosphorus_oxytrichloride.PNG\/150px-Phosphorus_oxytrichloride.PNG","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/e\/e0\/Phosphorus_oxytrichloride.PNG\/150px-Phosphorus_oxytrichloride.PNG","height":"158","width":"150"},"url":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/phosphoryle-trichloride-wikipedia\/","wordCount":4387,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4A wikipedia article, free l’encyclop\u00e9i. Phosphoryle trichloride  Phosphoryle trichloride molecule Identification UICPA name Phosphoryle trichloride  Synonyms        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4Phosphorus oxychloride N O CAS 10025-87-3  N O Echa 100.030.030 N O THIS 233-046-7-7 N O RTECS TH4897000 Pubchem 24813  Chebi 30336  SMILES  Inches Std. Inchi:  3D view  Inchi = 1S\/cl3op\/c1-5 (2,3) 4 Std. InChIKey\u00a0:  XHXFXVLFKHQFAL-UHFFFAOYSA-N Appearance colorless, smoking liquid, acre odor [ first ] . Chemicals Formula Cl 3 ON Pocl 3 Molar mass [ 2 ] 153.332 \u00b1 0.006 G\/MOL Cl\u00a069,36\u00a0%,  O\u00a010,43\u00a0%,  P\u00a020,2\u00a0%,  Dipolar moment 2,54 D Physical properties T\u00b0 fusion 1.2 \u00b0C [ first ] T\u00b0 boiling 106 \u00b0C [ first ] Solubility In water: reaction [ first ] Solubility parameter \u0394 19.8  J 1\/2 \u00b7 cm -3\/2 ( 25 \u00b0C ) [ 3 ] Volumic mass 1.6  g \u00b7 cm -3 [ first ] Saturating steam pressure To 27.3 \u00b0C : 5.3  kPa [ first ] Precautions SGH [ 4 ] , [ 5 ] H302 , H314 , H330 , H372 , Euh014 , Euh029 , P280 , P305 , P310 , P338 And P351        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4H302 : Harmful in case of ingestion H314 : Cause serious skin burns and eye damage H330 : Mortal by inhalation H372 : Proven risk of serious effects for organs (Indicate all affected organs, if they are known) Following repeated exhibitions or prolonged exposure (Indicate the exposure route if it is formally proven that no other exposure route leads to the same danger) Euh014 : Reacts violently in contact with water Euh029 : In contact with water, freeing toxic gases P280 : Wear protective gloves\/protective clothing\/eye\/face protective equipment. P305 : In case of contact with the eyes: P310 : Immediately call an anti -poison center or a doctor. P338 : Remove the contact lenses if the victim bears it and if they can be easily removed. Continue to rinse. P351 : Rinse with precaution with water for several minutes. Simdut [ 6 ] B6, D1A, AND, F, B6 : Flammable reactive material Remove a flammable gas in contact with water: phosphine D1A : Very toxic material with severe immediate effects Acute lethality: CL50 inhalation\/4 hours (rat) = 48  ppm AND : Corrosive material Transport of dangerous goods: Class 8 F : Dangerously reactive material reacts violently in contact with water by giving off a very toxic gas: hydrogen chloride Disclosure at 1.0% according to the ingredient disclosure list        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4NFPA 704  Transport [ 7 ] Code Kemler\u00a0: X80 : corrosive material or with a minor degree of corrosivity dangerously reacting with water) UN number: 1810 : Phosphorus oxychloride Class: 8 Label : 8 : Corrosive materials Packaging : Packaging group II : moderately dangerous materials; Ecotoxicology DL 50  36  mg \u00b7 kg -first (rats, oral) IS units and CNTP , unless otherwise stated. modifier  The phosphoryle trichloride , or phosphorus oxychloride , is an inorganic compound of the oxychloride family, of a raw pocl formula 3 .  Phosphoryle trichloride reacts with water and alcohols to give hydrogen chloride and respectively phosphoric acid and phosphate esters: Pocl 3  + 3 H2O \u2192 H3PO4 + 3 HCl.Pocl 3  peut \u00e9galement r\u00e9agir avec un acide de Lewis tel que le t\u00e9trachlorure de titane selon le sch\u00e9ma r\u00e9actionnel suivant\u00a0:Cl 3 P + -O –  + TiCl4 \u2192 Cl3P+-O\u2212-TiCl4.The Pocl compound 3 \u00b7AlCl 3  r\u00e9sultant de l’addition de chlorure d’aluminium sur le trichlorure de phosphoryle est assez stable, de sorte que POCl3 peut \u00eatre utilis\u00e9 pour \u00e9liminer le chlorure d’aluminium du m\u00e9lange r\u00e9sultant d’une r\u00e9action de Friedel-Crafts.Pocl 3  r\u00e9agit avec le bromure d’hydrog\u00e8ne en pr\u00e9sence de chlorure d’aluminium pour former le tribromure de phosphoryle POBr3.Phosphoryle trichloride can be prepared by oxygen action o 2  sur le trichlorure de phosphore PCl3 \u00e0 20-25\u00a0\u00b0C (l’air est inefficace)\u00a0:2 PCl 3  + O2 \u2192 2 O=PCl3.Alternative synthesis uses the reaction of the PCL phosphorus pentachloride 5  avec le pentoxyde de phosphore P4O10. Dans la mesure o\u00f9 ces deux compos\u00e9s sont solides, une mani\u00e8re efficace de r\u00e9aliser la r\u00e9action est de chlorer un m\u00e9lange de PCl3 et de P4O10 afin de produire le PCl5. Au fur et \u00e0 mesure que le PCl3 r\u00e9agit, le POCl3 devient le solvant de r\u00e9action\u00a0:6 PCl 3  + 6 Cl2 \u2192 6 PCl5.6 PCl 5  + P4O10 \u2192  10 POCl3.Pentachloride of phosphorus also forms phosphoryle trichloride with water, but this reaction is more difficult to control than the previous one. This product is used in the photovoltaic industry to boost phosphorus with diffusion silicon wafers in order to make a doping n On a doped substrate p (typically in the boron) in order to make a junction p – n . \u2191 a b c d e and f Phosphorus oxychloride , International chemical security sheets  \u2191 Molar mass calculated after ‘ Atomic weights of the elements 2007 \u00bb , on www.chem.qmul.ac.uk .  \u2191 (in) Yitzhak Marcus, The Properties of Solvents , vol. \u00a04, England, John Wiley & Sons Ltd, 1999 , 239 p.  (ISBN\u00a0 0-471-98369-1 )  \u2191 Index number 015-009-00-5 In Table 3.1 of Annex VI of CE Regulation N \u00b0 1272\/2008 (December 16, 2008)  \u2191 SIGMA-ALDRICH  \u2191 ‘ Phosphorus oxychloride \u00bbIn the chemical product database Reptox of the CSST (Quebec organization responsible for occupational safety and health), consulted on April 25, 2009  \u2191 Input of the case issue “10025-87-3” in the chemical database Achievement IFA (German organization responsible for occupational safety and health) ( German , English ), access on November 28, 2008 (Javascript required)  \u2191 “Phosphoryle trichloride” , on Have been , accessed February 11, 2009  Related articles [ modifier | Modifier and code ]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/all2en\/wiki32\/phosphoryle-trichloride-wikipedia\/#breadcrumbitem","name":"Phosphoryle trichloride – Wikipedia"}}]}]