[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/14925#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/14925","headline":"\u30c7\u30a3\u30dc\u30e9\u30f3 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","name":"\u30c7\u30a3\u30dc\u30e9\u30f3 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","description":"before-content-x4 \u69cb\u9020\u5f0f \u5168\u822c\u7684 \u540d\u524d \u30c7\u30a3\u30dc\u30e9\u30f3 \u4ed6\u306e\u540d\u524d \u30de\u30c3\u30b7\u30e5\u30d5\u30a9\u30fc\u30df\u30e5\u30e9 b 2 h 6 \u7c21\u5358\u306a\u8aac\u660e \u53cd\u767a\u7684\u306a\u7518\u3044\u5302\u3044\u306e\u306a\u3044\u7121\u8272\u306e\u30ac\u30b9 [\u521d\u3081] \u5916\u90e8\u8b58\u5225\u5b50\/\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9 \u7279\u6027 \u30e2\u30eb\u8cea\u91cf 27.67 g\u30fbmol -1","datePublished":"2022-08-14","dateModified":"2022-08-14","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/db\/Diborane_02.svg\/230px-Diborane_02.svg.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/db\/Diborane_02.svg\/230px-Diborane_02.svg.png","height":"177","width":"230"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/14925","wordCount":6076,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4\u69cb\u9020\u5f0f  \u5168\u822c\u7684 \u540d\u524d \u30c7\u30a3\u30dc\u30e9\u30f3 \u4ed6\u306e\u540d\u524d  \u30de\u30c3\u30b7\u30e5\u30d5\u30a9\u30fc\u30df\u30e5\u30e9 b 2 h 6 \u7c21\u5358\u306a\u8aac\u660e \u53cd\u767a\u7684\u306a\u7518\u3044\u5302\u3044\u306e\u306a\u3044\u7121\u8272\u306e\u30ac\u30b9 [\u521d\u3081] \u5916\u90e8\u8b58\u5225\u5b50\/\u30c7\u30fc\u30bf\u30d9\u30fc\u30b9  \u7279\u6027 \u30e2\u30eb\u8cea\u91cf 27.67 g\u30fbmol -1 \u7dcf\u72b6\u614b        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u6c17\u4f53 \u5bc6\u5ea6 1,17 kg\u30fbm -3 \uff0815\u00b0C\u30011\u30d0\u30fc\uff09 [\u521d\u3081] \u878d\u70b9 -164,85\u00b0C [\u521d\u3081]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u6cb8\u70b9 -92,5\u00b0C [\u521d\u3081] \u84b8\u6c17\u5727 2,8 MPa\uff080\u00b0C\uff09 [\u521d\u3081] \u5b89\u5168\u306b\u3064\u3044\u3066\u306e\u6848\u5185  \u592b\u4eba \u30b9\u30a4\u30b9\uff1a0.1 ml\u30fbm -3 \u307e\u305f\u306f0.1 mg\u30fbm -3 [2] \u71b1\u529b\u5b66\u7684\u7279\u6027 \u0394H f 0  36.4 kj \/ times [3]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u53ef\u80fd\u306a\u9650\u308a\u4e00\u822c\u7684\u306b\u3001SI\u30e6\u30cb\u30c3\u30c8\u304c\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u7279\u306b\u660e\u8a18\u3057\u306a\u3044\u9650\u308a\u3001\u63d0\u4f9b\u3055\u308c\u305f\u30c7\u30fc\u30bf\u306f\u6a19\u6e96\u6761\u4ef6\u306b\u9069\u7528\u3055\u308c\u307e\u3059\u3002 \u30c7\u30a3\u30dc\u30e9\u30f3 \u8981\u7d20\u30db\u30a6\u7d20\u3068\u6c34\u7d20\u304b\u3089\u306e\u5316\u5b66\u7684\u63a5\u7d9a\u3067\u3059\u3002\u5408\u8a08\u5f0fb\u304c\u3042\u308a\u307e\u3059 2 h 6 \u30db\u30a6\u7d20\u6c34\u7d20\u5316\u200b\u200b\u5408\u7269\uff08\u30dc\u30e9\u30f3\uff09\u306e\u751f\u5730\u30af\u30e9\u30b9\u304b\u3089\u306e\u6700\u3082\u5358\u7d14\u306a\u63a5\u7d9a\u3067\u3059\u3002 \u30b8\u30dc\u30e9\u30f3\u306f\u3001\u91d1\u5c5e\u30db\u30a6\u7d20\u306e\u52a0\u6c34\u5206\u89e3\u306b\u3088\u308a19\u4e16\u7d00\u306b\u521d\u3081\u3066\u5408\u6210\u3055\u308c\u307e\u3057\u305f\u304c\u3001\u8a73\u7d30\u306b\u306f\u691c\u67fb\u3055\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u3002 1912\u5e74\u304b\u30891936\u5e74\u307e\u3067\u3001\u30dc\u30ed\u30d2\u30c9\u30a4\u30c9\u30a2\u30eb\u30d5\u30ec\u30c3\u30c9\u30b9\u30c8\u30c3\u30af\u306e\u5316\u5b66\u306e\u5049\u5927\u306a\u5148\u99c6\u8005\u306f\u3001\u3053\u308c\u3089\u306e\u5316\u5408\u7269\u3092\u7814\u7a76\u3057\u3001\u975e\u5e38\u306b\u53cd\u5fdc\u6027\u304c\u3042\u308a\u3001\u63ee\u767a\u6027\u304c\u3042\u308a\u3001\u3057\u3070\u3057\u3070\u6bd2\u6027\u306e\u3042\u308b\u30dc\u30ea\u30c9\u30ea\u30c9\u306e\u5408\u6210\u3068\u53d6\u308a\u6271\u3044\u306e\u65b9\u6cd5\u3092\u3082\u305f\u3089\u3057\u307e\u3057\u305f\u3002\u5f7c\u306f\u6700\u521d\u306b\u30a4\u30fc\u30b5\u30f3\u306b\u4f3c\u305f\u30c7\u30a3\u30dc\u30e9\u30f3\u306e\u69cb\u9020\u3092\u63d0\u6848\u3057\u307e\u3057\u305f\u3002 [4] S.H.\u306b\u3088\u308b\u8a66\u884c\u5f8c\u306e\u96fb\u5b50\u5149\u7dda\u306e\u66f2\u304c\u308a\u30d0\u30a6\u30a2\u30fc\u306f\u5f7c\u306b\u3088\u3063\u3066\u63d0\u6848\u3055\u308c\u305f\u69cb\u9020\u3092\u652f\u6301\u3057\u305f\u3002 [5] [6] H. I. Schlesinger\u3068L. Pauling\uff08\u30a8\u30bf\u30f3\u69cb\u9020\u3082\u53d7\u3051\u5165\u308c\u305f\uff09\u3068\u306e\u30b3\u30df\u30e5\u30cb\u30b1\u30fc\u30b7\u30e7\u30f3\u3067\u306f\u30011940\u5e74\u4ee3\u521d\u982d\u306e\u53e4\u5178\u7684\u306a\u30ec\u30d3\u30e5\u30fc\u306e3\u30bb\u30f3\u30bf\u30fc\u306e\u7d46\u306f\u660e\u793a\u7684\u306b\u8b70\u8ad6\u3055\u308c\u3066\u3044\u307e\u305b\u3093\u3067\u3057\u305f\u3002 [7] \u305f\u3060\u3057\u3001\u30ec\u30d3\u30e5\u30fc\u3067\u306f\u30c1\u30a7\u30c3\u30af\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u307e\u3057\u305f 2V  – \u6df1\u304f\u69cb\u9020\uff1a\u300c\u3053\u306e\u4eee\u5b9a\u304c\u30b8\u30dc\u30e9\u30f3\u306e\u591a\u304f\u306e\u5316\u5b66\u7684\u7279\u6027\u3092\u7c21\u5358\u306b\u8aac\u660e\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3059…\u300d\u3002 1943\u5e74\u3001\u5b66\u58eb\u53f7\u306e\u5b66\u751f\u306f\u3001\u30aa\u30c3\u30af\u30b9\u30d5\u30a9\u30fc\u30c9\u30af\u30ea\u30b9\u30c8\u30d5\u30a1\u30fc\u30ed\u30f3\u30b0\u30a8\u30c3\u30c8\u30d2\u30ae\u30f3\u30ba\u306eR. P. P.\u30d9\u30eb\u3068\u4eca\u65e5\u30c7\u30a3\u30dc\u30e9\u30f3\u306e\u69cb\u9020\u3092\u767a\u8868\u3057\u307e\u3057\u305f\u3002 [8] \u3057\u304b\u3057\u3001\u3053\u308c\u306f1921\u5e74\u306b\u5f53\u6642\u306e\u30bd\u30d3\u30a8\u30c8\u9023\u90a6\u3067\u3059\u3067\u306b\u8aac\u660e\u3055\u308c\u3066\u3044\u307e\u3057\u305f\u3002 [9] [\u5341] [11] Longuet-Higgins\/Bell\u306e\u63d0\u6848\u306e\u6570\u5e74\u5f8c\u3001\u9069\u5207\u306a\u69cb\u9020\u306b\u3064\u3044\u3066\u5e83\u7bc4\u306a\u8b70\u8ad6\u304c\u3042\u308a\u307e\u3057\u305f\u3002\u8b70\u8ad6\u306f\u30011951\u5e74\u306bK. Hedberg\u3068V. Schomaker\u306b\u3088\u308b\u30a8\u30ec\u30af\u30c8\u30ed\u30f3\u5c48\u66f2\u6e2c\u5b9a\u3067\u7d42\u4e86\u3057\u307e\u3057\u305f\u3002\u3053\u308c\u306f\u3001\u3053\u308c\u307e\u3067\u8a8d\u8b58\u3055\u308c\u3066\u3044\u305f\u30c7\u30a3\u30dc\u30e9\u30f3\u306e\u69cb\u9020\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002 [12\u756a\u76ee] \u30a6\u30a3\u30ea\u30a2\u30e0\u30fb\u30cc\u30f3\u30fb\u30ea\u30c3\u30d7\u30b9\u30b3\u30e0\u30fb\u30b8\u30e5\u30cb\u30a2\u5f7c\u306f\u5f8c\u306b\u3001\u70ad\u6c34\u5316\u7269\u306e\u69cb\u9020\u3092\u542b\u3080\u540c\u69d8\u306e\u554f\u984c\u306b\u540c\u3058\u65b9\u6cd5\u3092\u4f7f\u7528\u3057\u307e\u3057\u305f\u3002 Lipscomb\u306f\u30011976\u5e74\u306b\u5f7c\u306e\u52aa\u529b\u306e\u305f\u3081\u306b\u5316\u5b66\u306e\u30ce\u30fc\u30d9\u30eb\u8cde\u3092\u53d7\u8cde\u3057\u307e\u3057\u305f\u3002 \u30c7\u30a3\u30dc\u30e9\u30f3\u306f\u81ea\u7136\u306b\u767a\u751f\u3057\u307e\u305b\u3093\u3002 \u30c7\u30a3\u30dc\u30e9\u30f3\u306e\u751f\u7523\u306b\u306f\u3044\u304f\u3064\u304b\u306e\u30aa\u30d7\u30b7\u30e7\u30f3\u304c\u3042\u308a\u307e\u3059\u3002 [13] \u6c34\u7d20\u5316\u30ea\u30c1\u30a6\u30e0\u3068\u30db\u30a6\u30e2\u30ea\u306e\u53cd\u5fdc\uff1a 6  l \u79c1 h  +  8  b F3\u21cc 6  l \u79c1 [ b F4]  +  B2H6{displaystyle mathrm {6 lih + 8 bf_ {3} rightleftharpoons 6 li [bf_ {4}] + b_ {2} h_ {6}}} \u30c6\u30c8\u30e9\u30d2\u30c9\u30ed\u30a2\u30eb\u30df\u30cd\u30fc\u30c8\u30ea\u30c1\u30a6\u30e0\u3068\u30db\u30a6\u30e2\u30ea\u3068\u30b8\u30a8\u30c1\u30eb\u30a8\u30fc\u30c6\u30eb\u3078\u306e\u53cd\u5fdc\uff1a 3  l \u79c1 [ a l H4]  +  4  b c l3\u21cc 3  l \u79c1 [ a l c l4]  +  2  B2H6{displaystyle mathrm {3 li [alh_ {4}] + 4 bcl_ {3} rightleftharpoons 3 li [alcl_ {4}] + 2 b_ {2} h_ {6}}}} \u30dc\u30e9\u30f3\u9178\u30ca\u30c8\u30ea\u30a6\u30e0\u3068\u30dc\u30eb\u30c8\u30ea\u30d5\u30eb\u30aa\u30ea\u30c9\u3068\u30b8\u30a8\u30c1\u30eb\u30a8\u30f3\u30b0\u30ea\u30b3\u30eb\u30c7\u30a3\u30e1\u30c1\u30a8\u30fc\u30c6\u30eb\u3078\u306e\u53cd\u5fdc\uff1a [14] "},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/14925#breadcrumbitem","name":"\u30c7\u30a3\u30dc\u30e9\u30f3 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2"}}]}]