[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/19639#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/19639","headline":"Markownikow -rule-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","name":"Markownikow -rule-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","description":"before-content-x4 Wladimir Wassiljewitsch Markownikow Markownikow-Remella \uff08Vladimir Wassiljewitsch Markownikow\u306b\u3088\u308b\u3068\uff09\u3001\u6709\u6a5f\u5316\u5b66\u3067\u306f\u3001\u975e\u5bfe\u79f0\u30a2\u30eb\u30b1\u30f3\u306e\u70ad\u7d20\u70ad\u7d20\u4e8c\u91cd\u7d50\u5408\u4e2d\u306e\u30d5\u30ed\u30b2\u30f3\u6c34\u7d20\u306e\u96fb\u6c17\u5264\u6dfb\u52a0\u306e\u7523\u7269\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u3066\u3044\u307e\u3059\u3002 [\u521d\u3081] after-content-x4 \u3053\u306e\u898f\u5247\u3067\u306f\u3001\u975e\u5bfe\u79f0\u30a2\u30eb\u30b1\u30f3\u306b\u30cf\u30ed\u30b2\u30f3\u6c34\u7d20\u3092\u4ed8\u7740\u3059\u308b\u3068\u3001\u6c34\u7d20\u539f\u5b50\u306f\u5e38\u306b\u3059\u3067\u306b\u6c34\u7d20\u304c\u8c4a\u5bcc\u306a\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u3073\u4ed8\u3051\u3089\u308c\u3066\u3044\u308b\u3068\u8ff0\u3079\u3066\u3044\u307e\u3059\u3002\u305d\u308c\u306b\u5fdc\u3058\u3066\u3001\u30cf\u30ed\u30b2\u30f3\u539f\u5b50\u306f\u4f4e\u6c34\u7d20\u3001\u3064\u307e\u308a\u3001\u7f6e\u63db\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u5408\u3057\u307e\u3059\u3002\u6c34\u306e\u6dfb\u52a0\u3067\u3082\u540c\u3058\u52b9\u679c\u304c\u89b3\u5bdf\u3067\u304d\u307e\u3059\u3002H\u539f\u5b50\u306f\u3001\u7f6e\u63db\u70ad\u7d20\u539f\u5b50\u306e\u4f4e\u4e0b\u306b\u7d50\u5408\u3057\u3001OH\u30b0\u30eb\u30fc\u30d7\u306f\u3088\u308a\u9ad8\u3044\u3082\u306e\u306b\u7f6e\u304d\u63db\u3048\u3089\u308c\u307e\u3057\u305f\u3002\u3060\u304b\u3089\u3042\u306a\u305f\u306f\u305d\u308c\u3092\u4e00\u822c\u5316\u3057\u305f\u3068\u8a00\u3046\u3053\u3068\u304c\u3067\u304d\u307e\u3059 +d \u30a8\u30ec\u30af\u30ed\u30d5\u30a3\u30eb – \u30cc\u30af\u30ed\u30d5\u30a3\u30eb D B Propide \u3053\u306e\u30eb\u30fc\u30eb\u306f\u6b21\u306e\u3068\u304a\u308a\u3067\u3059\uff08\u4f8b\u5916\uff1a\u4ee5\u4e0b\u3092\u53c2\u7167\uff09\u3002 [2]","datePublished":"2023-06-18","dateModified":"2023-06-18","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/6f\/VladimirMarkovnikov.jpg\/220px-VladimirMarkovnikov.jpg","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/6f\/VladimirMarkovnikov.jpg\/220px-VladimirMarkovnikov.jpg","height":"250","width":"220"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/19639","wordCount":893,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4 Wladimir Wassiljewitsch Markownikow  Markownikow-Remella \uff08Vladimir Wassiljewitsch Markownikow\u306b\u3088\u308b\u3068\uff09\u3001\u6709\u6a5f\u5316\u5b66\u3067\u306f\u3001\u975e\u5bfe\u79f0\u30a2\u30eb\u30b1\u30f3\u306e\u70ad\u7d20\u70ad\u7d20\u4e8c\u91cd\u7d50\u5408\u4e2d\u306e\u30d5\u30ed\u30b2\u30f3\u6c34\u7d20\u306e\u96fb\u6c17\u5264\u6dfb\u52a0\u306e\u7523\u7269\u306b\u3064\u3044\u3066\u8aac\u660e\u3057\u3066\u3044\u307e\u3059\u3002 [\u521d\u3081]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u3053\u306e\u898f\u5247\u3067\u306f\u3001\u975e\u5bfe\u79f0\u30a2\u30eb\u30b1\u30f3\u306b\u30cf\u30ed\u30b2\u30f3\u6c34\u7d20\u3092\u4ed8\u7740\u3059\u308b\u3068\u3001\u6c34\u7d20\u539f\u5b50\u306f\u5e38\u306b\u3059\u3067\u306b\u6c34\u7d20\u304c\u8c4a\u5bcc\u306a\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u3073\u4ed8\u3051\u3089\u308c\u3066\u3044\u308b\u3068\u8ff0\u3079\u3066\u3044\u307e\u3059\u3002\u305d\u308c\u306b\u5fdc\u3058\u3066\u3001\u30cf\u30ed\u30b2\u30f3\u539f\u5b50\u306f\u4f4e\u6c34\u7d20\u3001\u3064\u307e\u308a\u3001\u7f6e\u63db\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u5408\u3057\u307e\u3059\u3002\u6c34\u306e\u6dfb\u52a0\u3067\u3082\u540c\u3058\u52b9\u679c\u304c\u89b3\u5bdf\u3067\u304d\u307e\u3059\u3002H\u539f\u5b50\u306f\u3001\u7f6e\u63db\u70ad\u7d20\u539f\u5b50\u306e\u4f4e\u4e0b\u306b\u7d50\u5408\u3057\u3001OH\u30b0\u30eb\u30fc\u30d7\u306f\u3088\u308a\u9ad8\u3044\u3082\u306e\u306b\u7f6e\u304d\u63db\u3048\u3089\u308c\u307e\u3057\u305f\u3002\u3060\u304b\u3089\u3042\u306a\u305f\u306f\u305d\u308c\u3092\u4e00\u822c\u5316\u3057\u305f\u3068\u8a00\u3046\u3053\u3068\u304c\u3067\u304d\u307e\u3059 +d \u30a8\u30ec\u30af\u30ed\u30d5\u30a3\u30eb – \u30cc\u30af\u30ed\u30d5\u30a3\u30eb D B Propide \u3053\u306e\u30eb\u30fc\u30eb\u306f\u6b21\u306e\u3068\u304a\u308a\u3067\u3059\uff08\u4f8b\u5916\uff1a\u4ee5\u4e0b\u3092\u53c2\u7167\uff09\u3002 [2] [\u521d\u3081] \u4ee5\u4e0b\u304c\u691c\u8a0e\u3055\u308c\u3066\u3044\u307e\u3059\uff1a\u300c\u8ab0\u304c\u4e0e\u3048\u3089\u308c\u3066\u3044\u308b\u304b\u300d\u3002 \u3053\u306e\u30b3\u30fc\u30b9\u306e\u539f\u56e0\u306f\u3001\u4e2d\u9593\u30ec\u30d9\u30eb\u3068\u3057\u3066\u306e\u96fb\u6c17\u6804\u990a\u6027\u6dfb\u52a0\u306b\u3088\u308a\u3001\u7a4d\u6975\u7684\u306b\u5e2f\u96fb\u3057\u305f\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u4f5c\u6210\u3055\u308c\u308b\u3053\u3068\u3067\u3059\u3002\u6b63\u306e\u8ca0\u8377\u304c\u4e09\u6b21\u70ad\u7d20\u539f\u5b50\u306b\u3042\u308b\u5834\u5408\u3001\u96a3\u63a5\u3059\u308b\u30a2\u30eb\u30ad\u30eb\u6b8b\u57fa\u306e3 +I\u52b9\u679c\u306b\u3088\u3063\u3066\u5b89\u5b9a\u5316\u3055\u308c\u307e\u3059\u3002\u4e8c\u6b21\u70ad\u7d20\u539f\u5b50\u306f\u30012 +I\u52b9\u679c\u3068\u4e3b\u8981\u306a\u30a8\u30d5\u30a7\u30af\u30c8\u306b\u3088\u3063\u3066\u306e\u307f\u5b89\u5b9a\u5316\u3055\u308c\u307e\u3059\u3002 +I\u52b9\u679c\u306b\u52a0\u3048\u3066\u3001\u30cf\u30a4\u30d1\u30fc\u30b3\u30f3\u30b8\u30e5\u30b2\u30fc\u30b7\u30e7\u30f3\u306f\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u3082\u5b89\u5b9a\u3055\u305b\u307e\u3059\u3002\u305d\u306e\u305f\u3081\u3001\u4e09\u6b21\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u306f\u4e8c\u6b21\u3088\u308a\u3082\u5f37\u529b\u3067\u3042\u308a\u3001\u3057\u305f\u304c\u3063\u3066\u5b89\u5b9a\u6027\u304c\u9ad8\u304f\u3001\u3053\u308c\u306f\u4e00\u6b21\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u3088\u308a\u3082\u5b89\u5b9a\u3057\u3066\u3044\u307e\u3059\u3002\u4e09\u6b21\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u306f\u307b\u307c\u6392\u4ed6\u7684\u306b\u5f62\u6210\u3055\u308c\u307e\u3059\u3002        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u6b21\u306e\u53cd\u5fdc\u3067\u306f\u30012-\u30e1\u30c1\u30eb\u30d7\u30ed\u30c3\u30d7-1-EN\u306f\u6c34\u7d20\u5869\u7d20\u3068\u53cd\u5fdc\u3057\u307e\u3059\u3002 \u30d1\u30b9a\uff09\u306b\u3088\u308b\u3068\u3001\u6c34\u7d20\u539f\u5b50\u306f\u70ad\u7d20\u539f\u5b50\u306b\u6dfb\u52a0\u3055\u308c\u3066\u304a\u308a\u3001\u3053\u308c\u306f\u3042\u307e\u308a\u7f6e\u304d\u63db\u3048\u3089\u308c\u3066\u3044\u306a\u3044\u305f\u3081\u3001\u3088\u308a\u5b89\u5b9a\u3057\u305f\u4e09\u6b21\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u304c\u4f5c\u6210\u3055\u308c\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u306e\u898f\u5247\u306b\u5f93\u3063\u3066\u4f5c\u6210\u3055\u308c\u305f\u3088\u3046\u306b\u3001\u5869\u7d20\u9178\u5869\u306e\u8ffd\u52a0\u306b\u5fdc\u3058\u3066\u3044\u308f\u3086\u308b\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u88fd\u54c1\u3092\u4f5c\u6210\u3057\u307e\u3059\u3002b\uff09\u6c34\u7d20\u539f\u5b50\u304c\u9ad8\u767a\u751f\u578b\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u5408\u3059\u308b\u65b9\u6cd5\u3067\u306f\u3001\u4e0d\u5b89\u5b9a\u306a\u4e00\u6b21\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u4f5c\u6210\u3055\u308c\u3001\u6b21\u306b\u53cd\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u7523\u7269\u304c\u4f5c\u6210\u3055\u308c\u307e\u3059\u3002 a\uff09\u306e\u65b9\u6cd5\u3067\u4e2d\u9593\u4f53\u306f\u3088\u308a\u5b89\u5b9a\u3057\u3066\u3044\u308b\u305f\u3081\u3001\u3053\u308c\u306f\u597d\u307e\u308c\u307e\u3059\u3002 [2] [\u521d\u3081] \u305f\u3060\u3057\u3001\u9077\u79fb\u72b6\u614b\u3067\u53ef\u80fd\u306a2\u3064\u306e\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u5b89\u5b9a\u6027\u304c\u3001\u30a2\u30eb\u30ad\u30eb\u7f6e\u63db\u57fa\u306e +I\u52b9\u679c\u306b\u3088\u3063\u3066\u6392\u4ed6\u7684\u306b\u6c7a\u5b9a\u3055\u308c\u306a\u3044\u5834\u5408\u3001 \u53cd\u30de\u30eb\u30b3\u30a6\u30a3\u30ad\u30d7\u30ed\u30c0\u30af\u30b7\u30e7\u30f3 \u73fe\u308c\u308b\u3002\u30a2\u30af\u30ea\u30eb\u9178\u306b\u5230\u9054\u3057\u307e\u3059\uff08ch 2 = Ch-Cooh\uff09\u3001\u305f\u3068\u3048\u3070\u30013\u5869\u7d20\u30d7\u30ed\u30d4\u30aa\u30f3\u9178\u306e\u307f\u3067\u3059\u3002\u3053\u308c\u306f\u3001\u53cd\u5fdc\u4e2d\u306e\u3088\u308a\u5b89\u5b9a\u3057\u305f\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u96fb\u5b50\u306e\u3059\u3050\u8fd1\u304f\u3067\u767a\u751f\u3057\u306a\u3044\u305f\u3081\u3067\u3059\u3002        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4Markownikwregel\u306f\u3001\u30e9\u30b8\u30ab\u30eb\u306e\u6dfb\u52a0\u3001\u6cb9\u3066\u3084\u304d\u3001\u30d2\u30c9\u30ed\u30b7\u30ea\u30eb\u5316\u306b\u3082\u9069\u7528\u3055\u308c\u307e\u305b\u3093\uff08\u6700\u521d\u306bMorris S. Kharasch\u3092\u793a\u3057\u305f\u3088\u3046\u306b\uff09\u3002\u307e\u305f\u3053\u3053\u306b\u306a\u308a\u307e\u3059 \u53cd\u30de\u30eb\u30b3\u30a6\u30a3\u30ad\u30d7\u30ed\u30c0\u30af\u30b7\u30e7\u30f3 \u30d8\u30c6\u30ed\u30a2\u30c8\u30fc\u30de\u304c\u4e0b\u4f4d\u306e\u7f6e\u63db\u70ad\u7d20\u539f\u5b50\u306b\u7d50\u5408\u3059\u308b\u5834\u6240\u3092\u53d7\u3051\u53d6\u308a\u307e\u3057\u305f\u3002 [3] Alkenes\u304c\u4e3b\u8981\u306a\u8ffd\u52a0\u306eMarkownikow\u7523\u7269\u304b\u3089\u751f\u3058\u308b\u5834\u5408\u3001Saytzeff\u30eb\u30fc\u30eb\u3068Hofmann\u88fd\u54c1\u3068\u3044\u3046\u7528\u8a9e\u3067\u3001\u6392\u9664\u306e\u65b9\u5411\uff08regioselectivity\uff09\u306b\u3064\u3044\u3066\u3055\u3089\u306b\u8a73\u3057\u304f\u8aac\u660e\u3067\u304d\u307e\u3059\u3002 \u6b74\u53f2\u7684\u306b\u91cd\u8981\u306a\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u30eb\u30fc\u30eb\u306e\u9069\u7528\u306f\u3001\u30e1\u30bd\u30e1\u30ea\u30a2\u5b89\u5b9a\u5316\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u4e2d\u9593\u751f\u6210\u7269\u3068\u3057\u3066\u5f62\u6210\u3055\u308c\u308b\u53ef\u80fd\u6027\u304c\u3042\u308b\u5834\u5408\u3001\u975e\u5bfe\u79f0\u30a2\u30eb\u30b1\u30f3\u3078\u306e\u4e88\u60f3\u3055\u308c\u308b\u6dfb\u52a0\u751f\u6210\u7269\u306b\u5bfe\u3059\u308b\u8aa4\u3063\u305f\u4e88\u6e2c\u306b\u3064\u306a\u304c\u308a\u307e\u3059\u3002\u30e1\u30bd\u30de\u30fc\u52b9\u679c\uff08\u88dc\u511f\u4ee5\u4e0a\uff09\u3092\u8a98\u5c0e\u52b9\u679c\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\u305d\u308c\u306f\u5e38\u306b\u3001\u3088\u308a\u5b89\u5b9a\u3057\u305f\u4e2d\u9593\u4f53\u3068\u3057\u3066\u30ab\u30eb\u30d9\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u3092\u4f5c\u6210\u3057\u307e\u3059\u3002\u305d\u306e\u5f8c\u3001\u8ffd\u52a0\u65b9\u5411\u306f\u81ea\u52d5\u7684\u306b\u3053\u306e\u7d50\u679c\u306b\u306a\u308a\u307e\u3059\u3002 \u2191 a b c  \u30df\u30eb\u30c8\u30f3\u30fb\u30aa\u30fc\u30ad\u30f3\u3001\u30ed\u30b8\u30e3\u30fc\u30fbS\u30fb\u30de\u30b3\u30f3\u30d0\u30fc\u3001\u30a2\u30e9\u30f3\u30fbR\u30fb\u30d4\u30f3\u30cf\u30b9\u3001R\u3002\u30de\u30fc\u30b7\u30e3\u30eb\u30fb\u30a6\u30a3\u30eb\u30bd\u30f3\uff1a \u6709\u6a5f\u5316\u5b66\u306e\u8a9e\u5f59\u3068\u6982\u5ff5\u3002 \u7b2c2\u7248\u200b\u200b\u3001John Wiley\uff06Sons\u3001Hoboken 2005\u3001ISBN 0-471-68028-1\u3001pp\u3002558\u2013559\u3002  \u2191 a b  \u30dd\u30fc\u30e9\u30fb\u30e6\u30eb\u30ab\u30cb\u30b9\u30fb\u30d6\u30eb\u30fc\u30b9\uff1a \u6709\u6a5f\u5316\u5b66\u3002 \u7b2c4\u7248\u3001Prentice-Hall\u30012003\u3001ISBN 0-131-41010-5\u3001pp\u3002148\u2013149\u3002  \u2191  Mattias Beller\u3001Jayasree Sayad\u3001Anneght Tillack\u3001Haizun Jiao\uff1a \u30a2\u30eb\u30b1\u30f3\u3068\u30a2\u30eb\u30ad\u30f3\u306e\u89e6\u5a92\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u3068\u53cd\u30de\u30eb\u30b3\u30a6\u30cb\u30b3\u30a6\u306e\u5b98\u80fd\u5316 \u3002\u306e\uff1a \u5fdc\u7528\u5316\u5b66 \u3002 \u30d0\u30f3\u30c9  116 \u3001 \u3044\u3044\u3048\u3002  26 \u30012004\u5e746\u670828\u65e5\u3001ISSN 0044-8249 \u3001 S.  3448\u20133479 \u3001doi\uff1a 10.1002\/ange.200300616 \uff08 wiley.com [2019\u5e746\u67084\u65e5\u306b\u30a2\u30af\u30bb\u30b9]\uff09\u3002         (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki10\/archives\/19639#breadcrumbitem","name":"Markownikow -rule-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2"}}]}]