[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/13695#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/13695","headline":"\u30d5\u30ed\u30b9\u30c8\u30c0\u30a4\u30a2\u30b0\u30e9\u30e0 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","name":"\u30d5\u30ed\u30b9\u30c8\u30c0\u30a4\u30a2\u30b0\u30e9\u30e0 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","description":"before-content-x4 \u3053\u306e\u8a18\u4e8b\u3067\u306f\u3001\u8981\u7d20\u306e\u3055\u307e\u3056\u307e\u306a\u9178\u5316\u30ec\u30d9\u30eb\u3067\u306e\u9084\u5143\u96fb\u4f4d\u306e\u30b0\u30e9\u30d5\u30a3\u30c3\u30af\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u3092\u6271\u3044\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u30ea\u30f3\u30b0\u578b\u306e\u5e73\u9762\u5206\u5b50\u306b\u304a\u3051\u308b\u975e\u5c40\u5728\u5316\u3055\u308c\u305f\u03c0\u8ecc\u9053\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u30ec\u30d9\u30eb\u306e\u76f8\u5bfe\u7684\u306a\u914d\u7f6e\u3092\u63a8\u5b9a\u3059\u308b\u306e\u306b\u5f79\u7acb\u3064\u971c – \u30df\u30b9\u30ea\u30f3\u56f3\u3068\u6df7\u540c\u3057\u306a\u3044\u3088\u3046\u306b\u3057\u307e\u3059\u3002 \u6b21\u306e\u91cd\u8981\u306a\u60c5\u5831\u306f\u307e\u3060\u3042\u308a\u307e\u305b\u3093\u3002 \u30bb\u30af\u30b7\u30e7\u30f3 \u89e3\u91c8 \u975e\u5e38\u306b\u521d\u6b69\u7684\u306a\uff08\u4e0d\u5b8c\u5168\uff09\u3002 after-content-x4 \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3092\u7814\u7a76\u3057\u3066\u3001 \u5165\u308c\u308b\u3002 after-content-x4 a \u971c\u306e\u56f3 \uff08\u307e\u305f \u30d5\u30ed\u30b9\u30c8\u30a8\u30d0\u30b9 – \u56f3 \u307e\u305f \u9178\u5316\u72b6\u614b\u56f3","datePublished":"2019-06-10","dateModified":"2019-06-10","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/e\/ea\/Disambig-dark.svg\/25px-Disambig-dark.svg.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/e\/ea\/Disambig-dark.svg\/25px-Disambig-dark.svg.png","height":"19","width":"25"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/13695","wordCount":5256,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4\u3053\u306e\u8a18\u4e8b\u3067\u306f\u3001\u8981\u7d20\u306e\u3055\u307e\u3056\u307e\u306a\u9178\u5316\u30ec\u30d9\u30eb\u3067\u306e\u9084\u5143\u96fb\u4f4d\u306e\u30b0\u30e9\u30d5\u30a3\u30c3\u30af\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u3092\u6271\u3044\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u30ea\u30f3\u30b0\u578b\u306e\u5e73\u9762\u5206\u5b50\u306b\u304a\u3051\u308b\u975e\u5c40\u5728\u5316\u3055\u308c\u305f\u03c0\u8ecc\u9053\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u30ec\u30d9\u30eb\u306e\u76f8\u5bfe\u7684\u306a\u914d\u7f6e\u3092\u63a8\u5b9a\u3059\u308b\u306e\u306b\u5f79\u7acb\u3064\u971c – \u30df\u30b9\u30ea\u30f3\u56f3\u3068\u6df7\u540c\u3057\u306a\u3044\u3088\u3046\u306b\u3057\u307e\u3059\u3002 \u6b21\u306e\u91cd\u8981\u306a\u60c5\u5831\u306f\u307e\u3060\u3042\u308a\u307e\u305b\u3093\u3002 \u30bb\u30af\u30b7\u30e7\u30f3 \u89e3\u91c8 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\u971c\u306e\u56f3\u306e\u52a9\u3051\u3092\u501f\u308a\u3066\u3001\u5143\u7d20\u306e\u9178\u5316\u30ec\u30d9\u30eb\u306e\u71b1\u529b\u5b66\u7684\u5b89\u5b9a\u6027\u3092\u660e\u78ba\u306b\u63d0\u793a\u3057\u3066\u8b70\u8ad6\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002 [2] \u305f\u3068\u3048\u3070\u3001\u3069\u306e\u9178\u5316\u30ec\u30d9\u30eb\u304c\u71b1\u529b\u5b66\u7684\u306b\u6700\u3082\u5b89\u5b9a\u3057\u3066\u3044\u308b\u304b\u3001\u3069\u306e\u9178\u5316\u30ec\u30d9\u30eb\u304c\u5909\u5316\u307e\u305f\u306f\u4e0d\u5747\u8861\u306b\u306a\u308b\u50be\u5411\u304c\u3042\u308b\u304b\u3092\u7c21\u5358\u306b\u8a8d\u8b58\u3067\u304d\u307e\u3059\u3002 [\u521d\u3081] [2] \u5f7c\u3089\u306f1951\u5e74\u306b\u30e9\u30c6\u30a3\u30de\u30fc\u56f3\u306e\u4ee3\u66ff\u3068\u3057\u3066\u30a2\u30fc\u30b5\u30fc\u30fb\u30d5\u30ed\u30b9\u30c8\u306b\u3088\u3063\u3066\u63d0\u6848\u3055\u308c\u307e\u3057\u305f [3] 1964\u5e74\u306bEbsworth\u304b\u3089\u3088\u308a\u3088\u304f\u77e5\u3089\u308c\u307e\u3057\u305f\u3002 [4] \u9178\u5316\u6570\uff08x\u8ef8\uff09\u304c\u30a2\u30d6\u30b7\u30c3\u30b5\u4e0a\u306b\u3042\u308a\u3001\u901a\u5e38\u306f\u7e26\u5ea7\u6a19\uff08y\u8ef8\uff09\u306b\u9178\u5316\u6570\uff08x\u8ef8\uff09\u304c\u3042\u308b\u305f\u3081\u3001\u30c7\u30ab\u30eb\u30c8\u5ea7\u6a19\u7cfb\u304c\u4f7f\u7528\u3055\u308c\u307e\u3059 \u3068 \u3068 {displaystyle with}  – \u9178\u5316\u30ec\u30d9\u30eb\u306b\u5bfe\u3059\u308b\u9178\u5316\u30ec\u30d9\u30eb\u306b\u5bfe\u3059\u308b\u534a\u5358\u4f4d\u53cd\u5fdc\u306e\u5024 0 {displaystyle 0} \uff08Z\u3002B\u3002\uff1a        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4 V2+\/ V0{displaystyle\uff01 mathrm {v} ^{2+}\uff01\/mathrm {v} ^{0}} \uff09\u3002\u5024 \u3068 \u3068 {displaystyle with} \u81ea\u7531\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u306b\u76f4\u63a5\u6bd4\u4f8b\u3057\u307e\u3059 d g {displaystyle delta g} \u5f8c\uff1a d g =  –  \u3068 f \u3068  \u21d2 \u2212\u0394GF= \u3068 \u3068 {displaystyle delta g = -zfe rightArrow {frac {-delta g} {f}} = ze} \u3057\u305f\u304c\u3063\u3066 \u3068 {displaystyle with} \u9001\u4fe1\u3055\u308c\u305f\u96fb\u5b50\u306e\u6570\u3068 f = 96485 \u00a0C\u22c5mol\u22121{displaystyle f = 96485 {rm {ccdot mol^{ –  1}}}}} \u30d5\u30a1\u30e9\u30c7\u30fc\u5b9a\u6570\u306f\u3067\u3059\u3002\u6f5c\u5728\u7684\u306a\u30c7\u30fc\u30bf\u306f\u3001\u96fb\u6c17\u5316\u5b66\u7684\u6a19\u6e96\u6761\u4ef6\uff08 25 \u2218c \u3001 {displaystyle 25\u3001^{circ}\uff01mathrm {c} ,,}  p h = 0 \u3001 {displaystyle mathrm {ph} = 0 ,,}   c = \u521d\u3081  m o l \/ l {displaystyle\uff01 c = 1 mathrm {mol} \/mathrm {l}} \uff09\u4ed6\u306e\u6761\u4ef6\u3092\u53c2\u7167\u3059\u308b\u304b\uff08\u305f\u3068\u3048\u3070  p h = 14 {displaystyle mathrm {\uff01 ph = 14}} \uff09\u3002   \u9178\u3063\u3071\u3044\u6eb6\u6db2\u4e2d\u306e\u30d0\u30ca\u30b8\u30a6\u30e0\u306e\u56f3\uff08 p h = 0 {displaystyle mathrm {ph = 0}} \uff09\uff1a \u6a19\u6e96\u306e\u96fb\u4f4d\u306f\u3001\u95a2\u9023\u3059\u308b\u30ec\u30c9\u30c3\u30af\u30b9\u7b49\u91cd\u91cf\u304b\u3089\u30c6\u30fc\u30d6\u30eb\u4f5c\u54c1\u304b\u3089\u53d6\u5f97\u3055\u308c\u307e\u3059\u3002 VO2++2\u00a0H++e\u2212\u2192VO2++H2OmitE0=+1,00V,{displaystyle mathrm {vo_ {2}^{+}+2 h^{+}+e^{ – } rightArrow vo^{2+}+h_ {2} oquad {mit}} quad e^{0} =+1 {\u3001}} 00\u3001mathrm {v} VO2++2\u00a0H++e\u2212\u2192V3++H2OmitE0=+0,34V,{displaystyle mathrm {vo^{2+}+2 h^{+}+e^{ – } rightArrow v^{3+}+h_ {2} oquad {text {mit}} quad e^{0} =+0 {\u3001} V3++e\u2212\u2192V2+mitE0=\u22120,26V,{displaystyle mathrm {v^{3+}+e^{ – } rightArrow v^{2+} quad {text {mit}} quad e^{0} = -0 {\u3001} 26\u3001mathrm {v}\u3001}}} V2++2\u00a0e\u2212\u2192V0mitE0=\u22121,13V.{displaystyle mathrm {v^{2+}+2 e^{ – } rightArrow v^{0} quad {text {mit}} quad e^{0} = -1 {\u3001} 13\u3001mathrm {v}\u3001\u3002}}} \u3053\u308c\u304b\u3089\u5f7c\u3089\u306f\u306a\u308a\u307e\u3059 n\u22c5E{displaystyle mathrm {n\uff01cdot\uff01e}} -AVALUVRE\u304c\u6c7a\u5b9a\u3057\u307e\u3057\u305f\uff1a n\u22c5E(V\/V)=0,00V,{displaystyle mathrm {ncdot e\uff08v\/v\uff09= 0 {\u3001} 00\u3001mathrm {v} ,,}} n\u22c5E(V2+\/V)=2\u22c5(\u22121,13V)=\u22122,26V,{displaylllle mathrm {ncdot e\uff08v ^ {2} \/ v\uff09= 20\u3001} 13\u3001mathrm {v}\uff09= -2 {\u3001} ,,} ,,, {v n\u22c5E(V3+\/V)=(\u22120,26V)+(\u22122,26V)=\u22122,52V,{displaylllle mathrm {ncdot e\uff08v ^ {3 +} \/ v\uff09=\uff08 –  0 {3}\uff09 +\uff08 –  0 {3}\uff09 +\uff08-2}\uff09 +\uff08-2}\uff09 +\uff08 –  2}\uff09 +\uff08-2}\uff09 +\uff08 –  2}\uff09 +\uff08 –  2}\uff09 n\u22c5E(VO2+\/V)=0,34V+(\u22122,52V)=\u22122,18V,{displaylllle mathrm {ncdot e\uff08vo ^ {2} \/ v\uff09= 0 {\u3001}} +\uff08 –  2 {\u3001}}} {\uff09= -2} ,,}\u3002 n\u22c5E(VO2+\/V)=1,06V+(\u22122,18V)=\u22121,12V.{displaylllle mathrm {ncdot e\uff08vo_ {2} \/ v\uff09= 1 {{2} \/ v\uff09= 1 {\u3001}}}} {}} {\uff09= 1 {\u3001} 12\u3001mathrm {v\u3002}\u3001\u3002}}\u3002 \u5024\u306f\u5ea7\u6a19\u7cfb\u306b\u5165\u529b\u3055\u308c\u307e\u3059\u3002 \u7279\u5225\u306a\u9178\u5316\u9084\u5143\u30d7\u30ed\u30bb\u30b9\u306b\u95a2\u3059\u308b\u60c5\u5831\u306f\u3001\u9178\u5316\u30ec\u30d9\u30eb\u304c\u6975\u5ea6\u306b\u5024\u306b\u306a\u308b\u3068\u3059\u3050\u306b\u56f3\u304b\u3089\u53d6\u5f97\u3067\u304d\u307e\u3059\u3002\u971c\u306e\u56f3\u306b\u6700\u5927\u5024\u306b\u63a5\u7d9a\u304c\u3042\u308b\u5834\u5408\u3001\u5de6\u53f3\u306e2\u3064\u306e\u6bb5\u968e\u3078\u306e\u6e1b\u8870\uff08\u4e0d\u5747\u8861\uff09\u304c\u975e\u5e38\u306b\u53ef\u80fd\u6027\u304c\u9ad8\u304f\u306a\u308a\u307e\u3059\u3002\u305f\u3060\u3057\u3001\u63a5\u7d9a\u304c\u6700\u5c0f\u306b\u3042\u308b\u5834\u5408\u30012\u3064\u306e\u96a3\u63a5\u3059\u308b\u63a5\u7d9a\u304b\u3089\u3053\u306e\u30ec\u30d9\u30eb\u306e\u9178\u5316\uff08\u30b3\u30f3\u30d7\u30ed\u30fc\u30e0\uff09\u3078\u306e\u53cd\u5fdc\u306f\u975e\u5e38\u306b\u53ef\u80fd\u6027\u304c\u9ad8\u304f\u306a\u308a\u307e\u3059\u3002 \u6c17\u8cea\u3068\u306f\u3001\u30b8\u30c1\u30aa\u30ca\u30c3\u30c8\u304c\u786b\u9178\u5869\u3068\u786b\u9178\uff08\u307e\u305f\u306f\u6c34\u6eb6\u6db2\u4e2d\u306e\u4e8c\u9178\u5316\u786b\u9ec4\u3068\u4e8c\u9178\u5316\u786b\u9ec4\uff09\u306b\u53cd\u5fdc\u3059\u308b\u5834\u5408\u3067\u3059\u3002\u306e\u53cd\u5fdc  \u306e 2+{displaystyle\uff01 v^{2+}} \u3068  \u306e o 2+{displaystyle\uff01 vo^{2+}} \u306b  \u306e 3+{displaystyle\uff01 v^{3+}} \uff08\u30b5\u30f3\u30d7\u30eb\u56f3\u3092\u53c2\u7167\uff09\u3002 \u2191 a b  Michael Binnewies\u3001Maik Finze\u3001ManfredJ\u00e4ckel\u3001Peer Schmidt\u3001Helge Willner Geoff Rayner-Canham\uff1a \u4e00\u822c\u7684\u304a\u3088\u3073\u7121\u6a5f\u5316\u5b66 \u3002 3\u756a\u76ee\u3001\u5b8c\u5168\u306b\u6539\u8a02\u3055\u308c\u305f\u30a8\u30c7\u30a3\u30b7\u30e7\u30f3\u3002\u30d9\u30eb\u30ea\u30f32016\u3001ISBN 978-3-662-45067-3\u3001 S.  306\u2013308 \u3002   \u2191 a b  \u30d4\u30fc\u30bf\u30fc\u30fbW\u30fb\u30a2\u30c8\u30ad\u30f3\u30b9\u3001\u30c6\u30a3\u30ca\u30fb\u30aa\u30fc\u30d0\u30fc\u30c8\u30f3\u3001\u30b8\u30e7\u30ca\u30b5\u30f3\u30fb\u30ed\u30fc\u30af\u3001\u30de\u30fc\u30af\u30fb\u30a6\u30a7\u30e9\u30fc\u3001\u30d5\u30ec\u30a4\u30b6\u30fc\u30fb\u30a2\u30fc\u30e0\u30b9\u30c8\u30ed\u30f3\u30b0\u3001\u30de\u30a4\u30af\u30fb\u30d8\u30a4\u30ac\u30fc\u30de\u30f3\uff1a Shriver\uff06Atkins\u306e\u7121\u6a5f\u5316\u5b66 \u3002\u7b2c5\u7248\u7248\u3002\u30aa\u30c3\u30af\u30b9\u30d5\u30a9\u30fc\u30c9\u5927\u5b66\u51fa\u7248\u5c40\u3001\u30aa\u30c3\u30af\u30b9\u30d5\u30a9\u30fc\u30c92010\u3001ISBN 978-0-19-923617-6\u3001 S.  164\u2013168\u3001387\u3001391\u3001434\u3001437\u3001594 \u3002   \u2191  \u30a2\u30fc\u30b5\u30fc\u30fb\u30a2\u30c8\u30a6\u30a9\u30fc\u30bf\u30fc\u30fb\u30d5\u30ed\u30b9\u30c8\uff1a \u9178\u5316\u96fb\u4f4d\u306e\u306a\u3044\u30a8\u30cd\u30eb\u30ae\u30fc\u56f3 \u3002 In\uff1aAmerican Chemical Society ACS\uff08HRSG\u3002\uff09\uff1a Journal of the American Chemical Society\uff08JACS\uff09 \u3002 \u30d0\u30f3\u30c9  \u4e03\u5341\u4e09 \u3001 \u3044\u3044\u3048\u3002  6 \u30011951\u5e74\u3001 S.  2680\u20132682 \u3001doi\uff1a 10.1021\/JA01150A074 \uff08\u82f1\u8a9e\uff09\u3002   \u2191  Evelyn Algernon Valentine Ebsworth\uff1a \u9178\u5316\u9084\u5143\u30b7\u30b9\u30c6\u30e0\u306e\u81ea\u7531\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u8868\u3059\u30b0\u30e9\u30d5\u30a3\u30ab\u30eb\u306a\u65b9\u6cd5 \u3002 In\uff1aRSC\uff08ed\u3002\uff09\uff1a \u5316\u5b66\u306e\u6559\u80b2 \u3002 \u30d0\u30f3\u30c9  \u521d\u3081 \u30011964\u5e74\u3001 S.  123 \u3002         (adsbygoogle = window.adsbygoogle || 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