[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/22381#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/22381","headline":"\u77ed\u3044\u7406\u8ad6 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","name":"\u77ed\u3044\u7406\u8ad6 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2","description":"before-content-x4 \u983b\u7e41\u306a\u885d\u7a81\u306b\u3088\u308a\u3001\u53cd\u5fdc\u983b\u5ea6\u306f\u6fc3\u5ea6\u3068\u3068\u3082\u306b\u5897\u52a0\u3057\u307e\u3059 \u30b7\u30e7\u30c3\u30af\u7406\u8ad6 \u307e\u305f \u885d\u7a81\u7406\u8ad6 1916\u5e74\u306e\u30de\u30c3\u30af\u30b9\u30c8\u30e9\u30a6\u30c4\u306e\u5316\u5b66\u53cd\u5fdc\u306e\u904e\u7a0b\u306e\u6a5f\u68b0\u7684\u7406\u8ad6\u3067\u3059 [\u521d\u3081] \u307e\u305f\u306f1918\u5e74\u3001\u30a4\u30ae\u30ea\u30b9\u306e\u5316\u5b66\u8005\u30a6\u30a3\u30ea\u30a2\u30e0\u30fb\u30eb\u30a4\u30b9\u306b\u3088\u308b\u3002 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    (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4 \u983b\u7e41\u306a\u885d\u7a81\u306b\u3088\u308a\u3001\u53cd\u5fdc\u983b\u5ea6\u306f\u6fc3\u5ea6\u3068\u3068\u3082\u306b\u5897\u52a0\u3057\u307e\u3059  \u30b7\u30e7\u30c3\u30af\u7406\u8ad6 \u307e\u305f \u885d\u7a81\u7406\u8ad6 1916\u5e74\u306e\u30de\u30c3\u30af\u30b9\u30c8\u30e9\u30a6\u30c4\u306e\u5316\u5b66\u53cd\u5fdc\u306e\u904e\u7a0b\u306e\u6a5f\u68b0\u7684\u7406\u8ad6\u3067\u3059 [\u521d\u3081] \u307e\u305f\u306f1918\u5e74\u3001\u30a4\u30ae\u30ea\u30b9\u306e\u5316\u5b66\u8005\u30a6\u30a3\u30ea\u30a2\u30e0\u30fb\u30eb\u30a4\u30b9\u306b\u3088\u308b\u3002 2\u3064\u306e\u53cd\u5fdc\u30d1\u30fc\u30c8\u30ca\u30fc\u306e\u9593\u306e\u9686\u8d77\u304c\u53cd\u5fdc\u306e\u305f\u3081\u306b\u884c\u308f\u308c\u306a\u3051\u308c\u3070\u306a\u3089\u306a\u3044\u3068\u60f3\u5b9a\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u305d\u3053\u3067\u306f\u3001\u30b3\u30a2\u30b3\u30a2\u63a5\u7d9a\u8ef8\u306b\u6cbf\u3063\u3066\u7279\u5b9a\u306e\u65b0\u8208\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u8d85\u3048\u306a\u3051\u308c\u3070\u306a\u308a\u307e\u305b\u3093\u3002\u885d\u6483\u7406\u8ad6\u306f\u3001\u7279\u306b\u7403\u4f53\u30a4\u30aa\u30f3\u9593\u306e\u5358\u7d14\u306a\u6c17\u76f8\u53cd\u5fdc\u306b\u5bfe\u3057\u3066\u6709\u7528\u306a\u5024\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002 \u7403\u9762\u53cd\u5fdc\u30d1\u30fc\u30c8\u30ca\u30fc\u5411\u3051 [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u6b21\u306e\u5206\u5272\u6255\u3044\u65b9\u7a0b\u5f0f\u306f\u3001\u30bf\u30a4\u30d7A+B\u2192P\u306e\u5358\u7d14\u306a\u4e8c\u5206\u5b50\u53cd\u5fdc\u306e\u305f\u3081\u306b\u8a2d\u5b9a\u3067\u304d\u307e\u3059\u3002        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4d[A]dt=  –  kde [ a ] de [ b ] {displaystyle {frac {d [a]} {dt}} =  –  {mathit {k}} cdot [a] cdot [b]} \u3068 \u30a4\u30f3\u30d1\u30af\u30c8\u7406\u8ad6\u306f\u3001\u885d\u6483\u4fc2\u6570\u306e\u8a08\u7b97\u3092\u6271\u3044\u307e\u3059\u3002 A\u306e\u6fc3\u5ea6\u3092\u5909\u66f4\u3059\u308b\u305f\u3081\u306b\u5225\u306e\u30a2\u30d7\u30ed\u30fc\u30c1\u304c\u9078\u629e\u3055\u308c\u307e\u3059\u3002 d[A]dt=  –  fde ZABNA{displaystyle {frac {d [a]} {dt}} =  –  {mathit {f}} cdot {frac {z_ {ab}} {n_ {mathrm {a}}}}}}}} \u3068        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u8981\u56e0 f = e\u2212EAR\u22c5T{displaystyle f = e^{ –  {frac {e_ {mathrm {a}}} {rcdot t}}}}} \u53cd\u5fdc\u304c\u6210\u529f\u3059\u308b\u53ef\u80fd\u6027\u306e\u305f\u3081 \u885d\u6483\u5bc6\u5ea6\u3001\u3064\u307e\u308a\u3001\u6642\u9593\u3068\u4f53\u7a4d\u306e\u5358\u4f4d\u3042\u305f\u308a\u306eA\u3068B\u306e\u9593\u306e\u30d0\u30f3\u30d7\u306e\u6570\uff1a ZAB= a de 8\u22c5kB\u22c5T\u03c0\u22c5\u03bcde NA2de [ a ] de [ b ] {displaystyle z_ {ba} = sigma cdot {sqr {8cdot {mathit {k_ {b}}} cdot t}} cdot n_ {mathrm [b]} {2} cdot [b]  \u4fc2\u6570\u3092\u633f\u5165\u3059\u308b\u3068\u3001\u885d\u6483\u5bc6\u5ea6\u304c\u63d0\u4f9b\u3057\u307e\u3059\u3002 d[A]dt=  –  a de 8\u22c5kB\u22c5T\u03c0\u22c5\u03bcde NAde e\u2212EAR\u22c5Tde [ a ] de [ b ] {displaysty {frac {d [d [d]} {dt}} = -sigma cdot {frac {8cdot {8k_ {k}}} cdot t}} cdot n_ {athrm {a} mthrm}}} {rcdot t}}}}}}}}} \u4e0a\u8a18\u306e\u6700\u521d\u306e\u65b9\u7a0b\u5f0f\u3092\u6bd4\u8f03\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001Arrhenius\u65b9\u7a0b\u5f0f\u306f\u6b21\u306e\u3068\u304a\u308a\u3067\u3059\u3002 k = \u03c3\u22c58\u22c5kB\u22c5T\u03c0\u22c5\u03bc\u22c5NA\u23dfAde e\u2212EAR\u22c5T{displaystyle k = underbrace {sigma cdot {sqr {8cdot {8cdot {k_ {b}}} cdot t}} cdot n_ {mathrm {ma} t}} cdot cdot t}}}}}}}}}}\u3002 \u5468\u6ce2\u6570\u4fc2\u6570\u307e\u305f\u306f\u524d\u8868\u73fe\u4fc2\u6570 a \u3001\u30b7\u30e7\u30c3\u30af\u6570Z\u3068\u7acb\u4f53\u56e0\u5b50P\u3067\u69cb\u6210\u3055\u308c\u3066\u3044\u307e\u3059\u3002 a = p de \u3068 {displaystyle a = pcdot z} \u4ee5\u4e0b\u306f\u3001\u7403\u9762\u53cd\u5fdc\u30b9\u30bf\u30f3\u30c9\u306b\u9069\u7528\u3055\u308c\u307e\u3059 P=1\u21d2A=Z{displaystyle p = 1 rightArrow a = z} \u975e\u7403\u9762\u53cd\u5fdc\u30d1\u30fc\u30c8\u30ca\u30fc\u5411\u3051 [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u885d\u6483\u7406\u8ad6\u306f\u3001\u30c8\u30dd\u30ed\u30b8\u30fc\u7684\u306b\u3088\u308a\u8907\u96d1\u306a\u30b7\u30b9\u30c6\u30e0\u306b\u3068\u3063\u3066\u4f7f\u7528\u3067\u304d\u307e\u305b\u3093\u3002\u53cd\u5fdc\u7269\u306e\u5f62\u304c\u7406\u60f3\u7684\u306a\u7403\u5f62\u306e\u4eba\u7269\u304b\u3089\u9038\u8131\u3059\u308b\u307b\u3069\u3001\u3055\u3089\u306b\u60aa\u3044\u3053\u3068\u306b\u306a\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u65b9\u7a0b\u5f0f\u306b\u3088\u3063\u3066\u7d4c\u9a13\u7684\u306b\u8003\u616e\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059 \u7acb\u4f53\u56e0\u5b50 P\u304c\u62e1\u5927\u3057\u3001\u5206\u5b50\u306e\u7a7a\u9593\u7684\u914d\u5411\u3092\u8003\u616e\u3057\u3066\u304f\u3060\u3055\u3044\u3002 k = \u03c3\u22c58\u22c5kB\u22c5T\u03c0\u22c5\u03bc\u22c5NA\u22c5P\u23dfAde e\u2212EAR\u22c5T{displaystyle k = underbrace {sigma cdot {sqr {8cdot {kathit {k_ {b}}} cdot t}} cdot n_ {facdot}} {rcdot t}}}}}} \u307b\u3068\u3093\u3069\u306e\u5206\u5b50\u3067\u306f\u3001\u3053\u306e\u7acb\u4f53\u56e0\u5b50\u306f1\u672a\u6e80\u3067\u3059\u3002 P\u226a1{displaystyle pll 1} P\u306e\u610f\u5473\u306e\u3042\u308b\u5024\u3092\u7406\u8ad6\u7684\u306b\u8a08\u7b97\u3059\u308b\u305f\u3081\u306b\u3001\u3088\u3046\u306a\u3088\u308a\u8907\u96d1\u306a\u7406\u8ad6B.\u79fb\u884c\u72b6\u614b\u306e\u7406\u8ad6\u3002 \u2191  \u30de\u30c3\u30af\u30b9\u30c8\u30e9\u30a6\u30c4\uff1a \u30ac\u30b9\u306e\u53cd\u5fdc\u901f\u5ea6\u3068\u5e73\u8861\u306e\u6cd5\u5247\u3002 CV-3\/2R\u306e\u6dfb\u52a0\u7269\u306e\u78ba\u8a8d\u3002\u7d71\u5408\u5b9a\u6570\u3068\u5206\u5b50\u5f84\u306e\u65b0\u3057\u3044\u6c7a\u5b9a \u3002\u306e\uff1a Journal of Inorganic and General Chemistry \u3002 \u30d0\u30f3\u30c9  96 \u3001 \u3044\u3044\u3048\u3002  \u521d\u3081 \u30011916\u5e74\u3001ISSN 1521-3749 \u3001 S.  1\u201328 \u3001doi\uff1a 10.1002 \/ zac.1960902 \u3002         (adsbygoogle = window.adsbygoogle 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