[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/8987#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/8987","headline":"Azodicarbony\u9178\u30b8\u30a8\u30c1\u30eb\u30a8\u30b9\u30c6\u30eb-Wikipedia","name":"Azodicarbony\u9178\u30b8\u30a8\u30c1\u30eb\u30a8\u30b9\u30c6\u30eb-Wikipedia","description":"before-content-x4 Azodicarbony Acid Hyte Yester \u3001\u4e3b\u306b \u6b7b \uff08 d \u79c1 \u305d\u3046\u3067\u3059 \u30c6\u30a3\u30eb a \u3053\u306e\u3088\u3046\u306a d icarboxylat\uff09\u7701\u7565\u306f\u3001\u4ef2\u9593\u306e\u30c8\u30a5\u30ce\u30d6\u53cd\u5fdc\u306e\u305f\u3081\u306e\u91cd\u8981\u306a\u8a66\u85ac\u3067\u3059\u304c\u3001\u3055\u307e\u3056\u307e\u306a\u65b9\u6cd5\u3067\u4f7f\u7528\u3067\u304d\u307e\u3059\u3002 after-content-x4 \u751f\u7523\u306f\u3001\u9069\u5207\u306a\u624b\u6bb5\u306b\u3088\u3063\u3066\u8131\u6c34\u3055\u308c\u308b\u30d2\u30c9\u30e9\u30b8\u30f3\u306e\u8a98\u5c0e\u4f53\u3092\u4ecb\u3057\u3066\u884c\u308f\u308c\u307e\u3059\u3002 1\u3064\u306e\u53ef\u80fd\u6027\u306f\u3001\u55ab\u7159\u785d\u9178\u3092\u4f7f\u7528\u3057\u305f\u9178\u5316\u3067\u3059\u3002 [3]","datePublished":"2022-05-13","dateModified":"2022-05-13","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/d0\/Mitsunobu_Reaction_Mechanism.png\/550px-Mitsunobu_Reaction_Mechanism.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/d0\/Mitsunobu_Reaction_Mechanism.png\/550px-Mitsunobu_Reaction_Mechanism.png","height":"366","width":"550"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki11\/archives\/8987","wordCount":1343,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4Azodicarbony Acid Hyte Yester \u3001\u4e3b\u306b \u6b7b \uff08 d \u79c1 \u305d\u3046\u3067\u3059 \u30c6\u30a3\u30eb a \u3053\u306e\u3088\u3046\u306a d icarboxylat\uff09\u7701\u7565\u306f\u3001\u4ef2\u9593\u306e\u30c8\u30a5\u30ce\u30d6\u53cd\u5fdc\u306e\u305f\u3081\u306e\u91cd\u8981\u306a\u8a66\u85ac\u3067\u3059\u304c\u3001\u3055\u307e\u3056\u307e\u306a\u65b9\u6cd5\u3067\u4f7f\u7528\u3067\u304d\u307e\u3059\u3002        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u751f\u7523\u306f\u3001\u9069\u5207\u306a\u624b\u6bb5\u306b\u3088\u3063\u3066\u8131\u6c34\u3055\u308c\u308b\u30d2\u30c9\u30e9\u30b8\u30f3\u306e\u8a98\u5c0e\u4f53\u3092\u4ecb\u3057\u3066\u884c\u308f\u308c\u307e\u3059\u3002 1\u3064\u306e\u53ef\u80fd\u6027\u306f\u3001\u55ab\u7159\u785d\u9178\u3092\u4f7f\u7528\u3057\u305f\u9178\u5316\u3067\u3059\u3002 [3] \u3053\u306e\u53cd\u5fdc\u306f\u3001\u5869\u7d20\u3092\u9178\u5316\u5264\u3068\u3057\u3066\u4f7f\u7528\u3057\u3066\u3082\u6210\u529f\u3057\u307e\u3059\u3002 [4] \u6b7b\u8005\u306f\u6bd2\u6027\u304c\u3042\u308a\u3001\u30b7\u30e7\u30c3\u30af\u3068\u5149\u306b\u654f\u611f\u3067\u3001\u71b1\u7684\u306b\u4e0d\u5b89\u5b9a\u3067\u3059\u3002\u3053\u306e\u63a5\u7d9a\u306f\u3001\u30b9\u30d7\u30ec\u30f3\u30b7\u30f3\u30b0\u6cd5\u306e\u610f\u5473\u3067\u306e\u7206\u767a\u306e\u89b3\u70b9\u304b\u3089\u5371\u967a\u3067\u3042\u308a\u3001\u305d\u3053\u306e\u30d5\u30a1\u30d6\u30ea\u30c3\u30af\u30b0\u30eb\u30fc\u30d7A\u306b\u5272\u308a\u5f53\u3066\u3089\u308c\u307e\u3059\u3002 [5] \u30b9\u30c1\u30fc\u30eb\u30b9\u30ea\u30fc\u30d6\u30c6\u30b9\u30c8\u3067\u306f\u3001\u7269\u8cea\u306f\u5883\u754c\u76f4\u5f8420 mm\u3067\u975e\u5e38\u306b\u6fc0\u3057\u304f\u53cd\u5fdc\u3057\u307e\u3059\u3002 [6] \u611f\u5ea6\u306f\u308f\u305a\u304b4\u5e74\u3067\u3059\u3002 [6] \u30ea\u30fc\u30c9\u30d6\u30ed\u30c3\u30af\u30c6\u30b9\u30c8\u3067\u306f\u300133 ml\/10 g\u306e\u5ef6\u9577\u304c\u89b3\u5bdf\u3055\u308c\u307e\u3059\u3002 [6] 100\u00b0C\u3092\u8d85\u3048\u308b\u3068\u3001\u5206\u89e3\u71b1\u304c-1466 kj\u30fbkg\u306e\u5f37\u304f\u767a\u71b1\u6027\u5206\u89e3\u304c\u898b\u3064\u304b\u308a\u307e\u3059 -1 \u307e\u305f\u306f-255 kj\u30fbmol -1 \u305d\u308c\u4ee5\u5916\u306e\u3002 [6] \u3057\u305f\u304c\u3063\u3066\u3001\u305d\u308c\u306f\u307b\u3068\u3093\u3069\u304c\u6eb6\u89e3\u3057\u305f\u5f62\u3067\u3001\u305f\u3068\u3048\u3070\u30c8\u30eb\u30aa\u30fc\u30eb\u3067\u5e02\u8ca9\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u6b7b\u8005\u306f\u3001\u30a2\u30e1\u30ea\u30ab\u306e\u7d14\u7c8b\u306a\u7269\u8cea\u3068\u3057\u3066\u9001\u3089\u308c\u3066\u306f\u306a\u308a\u307e\u305b\u3093\u3002\u3053\u308c\u3089\u306e\u30bb\u30ad\u30e5\u30ea\u30c6\u30a3\u30ea\u30b9\u30af\u306e\u305f\u3081\u3001\u6b7b\u4ea1\u306e\u4f7f\u7528\u304c\u6e1b\u5c11\u3057\u305f\u305f\u3081\u3001\u901a\u5e38\u3001\u3088\u308a\u5b89\u5b9a\u3057\u305f\u30b8\u30a4\u30bd\u30d7\u30ed\u30d4\u30e9\u30be\u30c7\u30a3\u30ab\u30eb\u30dc\u30f3\u9178\uff08DIAD\uff09\u306b\u7f6e\u304d\u63db\u3048\u3089\u308c\u307e\u3059\u3002 \u84b8\u7559\u6642\u306b\u6b7b\u8005\u306f\u7206\u767a\u3059\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u9069\u5207\u306a\u5b89\u5168\u4e0a\u306e\u6ce8\u610f\u4e8b\u9805\u3092\u3068\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u76f4\u63a5\u5149\u6e90\u3092\u4fdd\u8b77\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002 [4]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4Table of ContentsMitsunobu-Reaktion [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30a8\u30ce\u30d5\u30a3\u30eb [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30b8\u30a8\u30ce\u30d5\u30a3\u30eb [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30de\u30a4\u30b1\u30eb\u30a2\u30af\u30bb\u30d7\u30bf\u30fc [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30d4\u30e9\u30be\u30ea\u30f3\u8a98\u5c0e\u4f53\u306e\u5408\u6210 [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] Mitsunobu-Reaktion [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u6b7b\u304b\u3089\u306e\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u306e\u53e4\u5178\u7684\u306a\u9818\u57df\u306f\u3001\u30a2\u30eb\u30b3\u30fc\u30eb\u304b\u3089\u306e\u30a8\u30b9\u30c6\u30eb\u30f3\u3001\u30a4\u30fc\u30b5\u30eb\u30f3\u3001\u30a2\u30df\u30f3\u3001\u30c1\u30aa\u30a8\u30fc\u30c6\u30eb\u306e\u5408\u6210\u306b\u5f79\u7acb\u3064\u30df\u30c4\u30ce\u30d6\u53cd\u5fdc\u3067\u3059\u3002 \u30a8\u30ce\u30d5\u30a3\u30eb [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u6b7b\u304b\u3089\u306e\u5225\u306e\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u9818\u57df\u306f\u3001\u305f\u3068\u3048\u3070EN\u53cd\u5fdc\u306b\u304a\u3044\u3066\u30a8\u30ce\u30d5\u30a3\u30ea\u30c3\u30af\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002 [7] \u30b8\u30a8\u30ce\u30d5\u30a3\u30eb [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u60aa\u30d5\u30a3\u30eb\u3068\u3057\u3066\u306e\u4f7f\u7528\u306f\u3001\u6587\u732e\u306b\u3082\u8a18\u8f09\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u30b7\u30af\u30ed\u30da\u30f3\u30bf\u30c7\u30a3\u30a8\u30f3\u304b\u3089\u306e\u30d3\u30b7\u30af\u30ed[2.1.0]\u4e94\u89d2\u5f62\u306e\u5408\u6210\u304c\u6210\u529f\u3057\u307e\u3057\u305f\u3002 [8]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u30de\u30a4\u30b1\u30eb\u30a2\u30af\u30bb\u30d7\u30bf\u30fc [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] Dead\u306eAZ\u30b0\u30eb\u30fc\u30d7\u3082Michael Acceptor\u3067\u3059\u3002\u9285\u89e6\u5a92\u306e\u5b58\u5728\u4e0b\u3067\u3001\u6b7b\u3093\u3060\u306e\u306f\u3001\u5bfe\u5fdc\u3059\u308b\u6cb9\u5727\u306e\u591a\u7528\u306b\u03b2-\u30b1\u30c8\u30a8\u30b9\u30c6\u30eb\u306b\u8ffd\u52a0\u3055\u308c\u307e\u3059\u3002 [9] \u540c\u69d8\u306b\u3001Cu\uff08II\uff09\u306f\u3001\u307b\u307c\u5b9a\u91cf\u7684\u53ce\u7387\u3067\u306e\u30dc\u30ed\u30f3\u9178\u30a8\u30b9\u30c6\u30eb\u306e\u7f6e\u63db\u3082\u89e6\u5a92\u3057\u307e\u3059\u3002 [\u5341] \u30d4\u30e9\u30be\u30ea\u30f3\u8a98\u5c0e\u4f53\u306e\u5408\u6210 [ \u7de8\u96c6 | \u30bd\u30fc\u30b9\u30c6\u30ad\u30b9\u30c8\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u6b7b\u8005\u306f\u3001\u30d8\u30c6\u30ed\u30b5\u30a4\u30af\u30eb\u306e\u5408\u6210\u306b\u3082\u4f7f\u7528\u3067\u304d\u307e\u3059\u3002\u3053\u306e\u3088\u3046\u306b\u3057\u3066\u3001\u30d4\u30e9\u30be\u30fc\u30eb\u30c7\u30a3\u30f3\u30c0\u30fc\u306f\u3001\u03b1\u3001\u03b2\u306b\u98e2\u3048\u305f\u30b1\u30c8\u30f3\u3078\u306e\u51dd\u7e2e\u3092\u901a\u3058\u3066\u4fdd\u5b58\u3067\u304d\u307e\u3059\u3002 [11] \uff1a \u30af\u30ec\u30a4\u30c7\u30f3\u3001\u30b0\u30ea\u30fc\u30d6\u30b9\u3001\u30a6\u30a9\u30fc\u30ec\u30f3\uff06\u30a6\u30a9\u30b6\u30b9\uff1a \u6709\u6a5f\u5316\u5b66\u3002 \u30aa\u30c3\u30af\u30b9\u30d5\u30a9\u30fc\u30c9\u5927\u5b66\u51fa\u7248\u5c40\u30012004\u5e748\u6708\u3001ISBN 0-19-850346-6 O. Mitsunobu, M. Wada, T. Sano: \u7acb\u4f53\u7279\u7570\u7684\u304a\u3088\u3073\u7acb\u4f53\u9078\u629e\u7684\u53cd\u5fdc\u3002 I.\u30a2\u30eb\u30b3\u30fc\u30eb\u304b\u3089\u306e\u30a2\u30df\u30f3\u306e\u8abf\u88fd J. Am\u3067\u3002\u5316\u5b66\u3002 Soc\u3002 94\uff081972\uff09679\u2013680\u3001doi\uff1a 10.1021\/JA00757A085 \u3002 R. F. C.\u30d6\u30e9\u30a6\u30f3\u3001W\u3002R\u3002\u30b8\u30e3\u30af\u30bd\u30f3\u3001T\u3002D\u3002\u30de\u30c3\u30ab\u30fc\u30b7\u30fc\uff1a \u30d5\u30e9\u30d0\u30f3-3-OLS\u3078\u306e\u6f5c\u5728\u7684\u306a\u30eb\u30fc\u30c8\u3001\u30d1\u30fc\u30c82\uff1a\u30d1\u30e9\u30aa\u30ad\u30b7\u30b2\u30f3\u5316\u30d9\u30f3\u30b8\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u30df\u30c4\u30ce\u30d6\u53cd\u5fdc Tetrahedron 50\uff081994\uff095469\u20135488\u3001doi\uff1a 10.1016\/s0040-4020\uff0801\uff0980702-x \u3002 \uff08\u30e1\u30bd\u30c3\u30c9\u958b\u767a\uff09 O. Mitsunobu: \u5929\u7136\u7523\u7269\u306e\u5408\u6210\u3068\u5909\u63db\u306b\u304a\u3051\u308b\u30a2\u30be\u30c7\u30a3\u30ab\u30eb\u30dc\u30f3\u9178\u30b8\u30c1\u30eb\u9178\u30b8\u30a8\u30c1\u30eb\u3068\u30c8\u30ea\u30d8\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306e\u4f7f\u7528 \u5408\u62101981\u30011\u201328\u3001doi\uff1a 10.1055\/S-1981-29317 \u3002 \uff08\u6982\u8981\uff09 \u2191 a b  \u3078\u306e\u30a8\u30f3\u30c8\u30ea diazendicarbony\u9178\u30b8\u30a8\u30c1\u30eb\u30a8\u30b9\u30c6\u30eb \u3002\u306e\uff1a \u30aa\u30f3\u30e9\u30a4\u30f3\u3067r\u00f6mpp\u3002 Georg Thieme Verlag\u30012014\u5e7412\u670828\u65e5\u306b\u30a2\u30af\u30bb\u30b9\u3002  \u2191 a b c d \u305d\u3046\u3067\u3059  \u30c7\u30fc\u30bf\u30b7\u30fc\u30c8 \u30b8\u30a8\u30c1\u30eb\u30a2\u30be\u30c7\u30a3\u30ab\u30eb\u30dc\u30f3\u9178\u300197\uff05 2019\u5e7412\u670826\u65e5\u306b\u30a2\u30af\u30bb\u30b9\u3057\u305fAlfaaesar\u3067\uff08 PDF \uff09\uff09 \uff08JavaScript\u304c\u5fc5\u8981\uff09 \u3002  \u2191  \u30ce\u30fc\u30de\u30f3\u30e9\u30d6\u30b8\u30e7\u30f3\uff1a \u30a8\u30c1\u30eb\u30a2\u30be\u30c7\u30a3\u30ab\u30eb\u30dc\u30f3\u9178 \u306e\uff1a \u6709\u6a5f\u5408\u6210 \u3002 28\u30011948\u3001S\u300258\u30012\uff1a 10.15227\/orgsyn.028.0058 ; coll\u3002 Vol\u3002 3\u30011955\u3001S\u3002375\uff08 PDF \uff09\u3002  \u2191 a b  J. 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