[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/10927#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/10927","headline":"\u30a2\u30df\u30ce\u30ea\u30b7\u30b9 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","name":"\u30a2\u30df\u30ce\u30ea\u30b7\u30b9 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","description":"before-content-x4 \u30a2\u30df\u30ce\u30ea\u30b6 – \u3055\u307e\u3056\u307e\u306a\u7a2e\u985e\u306e\u5316\u5b66\u7269\u8cea\u3068\u30a2\u30df\u30f3\u9593\u306e\u5316\u5b66\u53cd\u5fdc\u3002\u6709\u6a5f\u5316\u5b66\u3067\u306f\u3001\u3053\u308c\u306f\u3057\u3070\u3057\u3070\u30ab\u30eb\u30dc\u30f3\u9178\u8a98\u5c0e\u4f53\u3068\u30a2\u30df\u30f3\u3068\u306e\u53cd\u5fdc\u3067\u3042\u308a\u3001\u3053\u308c\u306f\u6c42\u6838\u6027\u7f6e\u63db\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u306b\u5f93\u3063\u3066\u5b9f\u884c\u3055\u308c\u307e\u3059\u3002\u4e8c\u6b21\u30a2\u30df\u30f3\u306f\u3001\u7279\u306b\u5927\u898f\u6a21\u306a\u7a7a\u9593\u3067\u306f\u3001\u3053\u306e\u30bf\u30a4\u30d7\u306e\u53cd\u5fdc\u304c\u539f\u767a\u6027\u30a2\u30df\u30f3\u3088\u308a\u3082\u306f\u308b\u304b\u306b\u53cd\u5fdc\u6027\u304c\u4f4e\u3044\u3067\u3059 [\u521d\u3081] [2] \u3002\u901a\u5e38\u3001\u30a2\u30df\u30ce\u30ea\u30b7\u30b9\u304c\u3042\u308a\u307e\u3059\u3002 after-content-x4 \u30a2\u30df\u30ce\u30ea\u30b7\u30b9\u53cd\u5fdc\u306e\u4f8b \uff1a rcocl + r \u521d\u3081 NH 2 \u2192rconhr \u521d\u3081 + HCl","datePublished":"2020-09-22","dateModified":"2020-09-22","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/pl.wikipedia.org\/wiki\/Special:CentralAutoLogin\/start?type=1x1","url":"https:\/\/pl.wikipedia.org\/wiki\/Special:CentralAutoLogin\/start?type=1x1","height":"1","width":"1"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/10927","wordCount":1675,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4\u30a2\u30df\u30ce\u30ea\u30b6  – \u3055\u307e\u3056\u307e\u306a\u7a2e\u985e\u306e\u5316\u5b66\u7269\u8cea\u3068\u30a2\u30df\u30f3\u9593\u306e\u5316\u5b66\u53cd\u5fdc\u3002\u6709\u6a5f\u5316\u5b66\u3067\u306f\u3001\u3053\u308c\u306f\u3057\u3070\u3057\u3070\u30ab\u30eb\u30dc\u30f3\u9178\u8a98\u5c0e\u4f53\u3068\u30a2\u30df\u30f3\u3068\u306e\u53cd\u5fdc\u3067\u3042\u308a\u3001\u3053\u308c\u306f\u6c42\u6838\u6027\u7f6e\u63db\u306e\u30e1\u30ab\u30cb\u30ba\u30e0\u306b\u5f93\u3063\u3066\u5b9f\u884c\u3055\u308c\u307e\u3059\u3002\u4e8c\u6b21\u30a2\u30df\u30f3\u306f\u3001\u7279\u306b\u5927\u898f\u6a21\u306a\u7a7a\u9593\u3067\u306f\u3001\u3053\u306e\u30bf\u30a4\u30d7\u306e\u53cd\u5fdc\u304c\u539f\u767a\u6027\u30a2\u30df\u30f3\u3088\u308a\u3082\u306f\u308b\u304b\u306b\u53cd\u5fdc\u6027\u304c\u4f4e\u3044\u3067\u3059 [\u521d\u3081] [2] \u3002\u901a\u5e38\u3001\u30a2\u30df\u30ce\u30ea\u30b7\u30b9\u304c\u3042\u308a\u307e\u3059\u3002        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u30a2\u30df\u30ce\u30ea\u30b7\u30b9\u53cd\u5fdc\u306e\u4f8b \uff1a rcocl + r \u521d\u3081 NH 2 \u2192rconhr \u521d\u3081 + HCl arso 2 CL + RNH 2 \u2192arso 2 NHR + HCl \u8907\u6570\u306e\u53cd\u5fdc\u6027\u5869\u7d20\u539f\u5b50\u3092\u542b\u3080\u3044\u304f\u3064\u304b\u306e\u57fa\u8cea\u306f\u3001\u5f90\u3005\u306b\u53cd\u5fdc\u3057\u3001\u30a2\u30df\u30f3\u3092\u53cd\u5fdc\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u4f8b\uff1aPCL 3 \u4f7f\u7528\u3055\u308c\u308b\u30e2\u30eb\u6bd4\u306b\u5fdc\u3058\u3066\u30e2\u30ce\u30a4\u30c9\u3068\u30b8\u30a2\u30df\u30c9\u3092\u4f5c\u6210\u3057\u3001\u904e\u5270\u306a\u30a2\u30df\u30ca\u306f\u30c8\u30ea\u30a2\u30df\u30c3\u30c9\u306b\u3088\u3063\u3066\u5f62\u6210\u3055\u308c\u307e\u3059 [3] [4] \u3001\u4f8b\u3048\u3070\uff1a PCL 3 + rnh 2 \u2192PCL 2 NHR + HCl PCL 3 + 2rnh 2 \u2192PCL\uff08NHR\uff09 2 + 2HCl PCL 3 + 3rnh 2 \u2192P\uff08NHR\uff09 3 + 3HCl \u591a\u6a5f\u80fd\u5316\u5408\u7269\u3068\u306e\u53cd\u5fdc\u306f\u3001\u7d50\u5408= No. [5] \u3001\u4f8b\u3048\u3070\uff1a        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4PCL 5 + rnh 2 \u30fbHCl\u2192RN = PCL 3 + 3HCl \uff08RCO\uff09 2 O + R \u521d\u3081 NH 2 \u2192rconhr \u521d\u3081 + rCOOH rcoor \u521d\u3081 + r 2 NH 2 \u2192rconhr 2 + r \u521d\u3081 \u304a\u304a rcoor \u521d\u3081 + r 2 2 NH\u2192RCON\uff08r 2 \uff09\uff09 2 + r \u521d\u3081 \u304a\u304a RO -pH\uff08o\uff09\u2013OAR + r 2 NH\u2192RO -pH\uff08O\uff09\u2013NR 2 + aroh \u30e1\u30f3\u30bd 2 \u305d\u306e\u4ed6 + r 2 NH\u2192MEHSO 2 \u3044\u3044\u3048\u3002 2 + aroh \u3053\u306e\u53cd\u5fdc\u306f\u3001E1CB\u30e1\u30ab\u30cb\u30ba\u30e0\u306b\u5f93\u3063\u3066\u767a\u751f\u3057\u3001\u30a4\u30df\u30ca\u306e\u7537\u6027\u306e\u9593\u63a5\u7684\u306a\u751f\u7523= 2 \uff08\u30a2\u30df\u30f3\u306b\u3088\u308b\u57fa\u8cea\u306e\u57fa\u8cea\u3068\u30d5\u30a7\u30ce\u30fc\u30eb\u306e\u81ea\u767a\u7684\u9664\u53bb\u306e\u7d50\u679c\u3068\u3057\u3066\uff09;\u6b21\u306b\u30012\u756a\u76ee\u306e\u30a2\u30df\u30ca\u5206\u5b50\u304c\u30a4\u30df\u30ca\u306b\u53d6\u308a\u4ed8\u3051\u3089\u308c\u3001\u88fd\u54c1\u304c\u4e0e\u3048\u3089\u308c\u307e\u3059 [7] \u3002 r 2 p-net 2 +\u30aa\u30f3 2 \u2192R 2 p-day + et 2 NH RHNC\uff08O\uff09r \u521d\u3081 + menh 2 \u2192RNH 2 + meennc\uff08o\uff09r \u521d\u3081 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Amigues\u3001C\u3002Hardacre\u3001G\u3002Keane\u3001M\u3002E\u3002Migaud\u3002 PCl\u306e\u6eb6\u5a92\u5909\u8abf\u53cd\u5fdc\u6027 3 \u30a2\u30df\u30f3\u3067 \u3002 \u201e green.chem\u3002\u300d\u3002 10\uff086\uff09\u3001s\u3002 660-669\u30012008\u3002doi\uff1a 10.1039\/B718849H \u3002   \u2191  \u30a2\u30c3\u30d0\u30b9\u306f\u6b21\u306eZiba Khamoradplant\u3067\u3059\u3002 \u30ea\u30f3\uff08v\uff09\u30a2\u30b6\u30f3 – \u30c1\u30f3\uff08IV\uff09\u8907\u5408\u4f53 \u3002 \u300c\u30ea\u30f3\u3001\u786b\u9ec4\u3001\u30b7\u30ea\u30b3\u30f3\u300d\u3002 180\uff082\uff09\u3001s\u3002 527\u2013532\u30012005\u3002Doi\uff1a 10,1080\/104265090517253 \u3002   \u2191  \u30b9\u30c6\u30a3\u30fc\u30d6\u30f3\u30fbA\u30fb\u30d9\u30eb\u3001\u30bf\u30e9\u30fbY\u30fb\u30de\u30a4\u30e4\u30fc\u3001\u30b9\u30c6\u30a3\u30fc\u30d6\u30f3\u30fbJ\u30fb\u30b2\u30a4\u30d6\u3002 \u9077\u79fb\u91d1\u5c5e\u306e\u306a\u3044\u89e6\u5a92\u4e8c\u91cd\u7d50\u5408\u30e1\u30bf\u30bb\u30b7\u30b9 \u3002 \u201e J.\u5348\u524d\u3002\u5316\u5b66\u3002 soc\u3002\u300d\u3002 124\uff0836\uff09\u3001s\u3002 10698\u201310705\u30012002\u3002doi\uff1a 10.1021 \/ JA020494V \u3002   \u2191  \u30a8\u30c9\u30ef\u30fc\u30c9MCC\u3002\u30a2\u30fc\u30cd\u30c3\u30c8\u3001\u30b8\u30e7\u30f3\u30fbG\u30fb\u30df\u30e9\u30fc\u3001\u30a2\u30e9\u30f3\u30fbR\u30fb\u30c7\u30a4\u3002 \u53cd\u5fdc\u6027\u306b\u5bfe\u3059\u308b\u69cb\u9020\u306e\u5f71\u97ff\u3002 iii\u3002\u539f\u767a\u6027\u30a2\u30df\u30f3\u306b\u3088\u308b\u30a8\u30b9\u30c6\u30eb\u306e\u30a2\u30df\u30ce\u30ea\u30b7\u30b9 \u3002 \u201e J.\u5348\u524d\u3002\u5316\u5b66\u3002 soc\u3002\u300d\u3002 72\uff0812\uff09\u3001s\u3002 5635\u20135638\u30011950\u3002doi\uff1a 10.1021\/JA01168A075 \u3002   \u2191 a b  WJ\u3002 Spillane\u3001P\u3002McGrath\u3001C\u3002Brack\u3001AB\u3002\u30aa\u30d3\u30eb\u30f3\u3002 \u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u4e2d\u306e\u30b9\u30eb\u30d5\u30a1\u30e1\u30fc\u30c8\u30a8\u30b9\u30c6\u30eb\u306e\u30a2\u30df\u30ce\u30ea\u30b7\u30b9\u4e2d\u306eE1CB\u30e1\u30ab\u30cb\u30ba\u30e0\u306b\u304a\u3051\u308b\u30ec\u30fc\u30c8\u6c7a\u5b9a\u30b9\u30c6\u30c3\u30d7\u306e\u5909\u5316\u3002 \u3002 \u201e J.\u7d44\u7e54\u3002\u5316\u5b66\u3002\u300d\u3002 66\uff0819\uff09\u3001s\u3002 6313-6316\u30012001\u3002doi\uff1a 10.1021\/JO015691B \u3002 PMID\uff1a 11559180 \u3002   \u2191  M.\u30a2\u30e9\u30b8\u30e3\u30ea\u30f3\u3001C\u3002\u30ed\u30da\u30b9\u30ec\u30aa\u30ca\u30eb\u30c9\u3001P\u3002\u30e9\u30de\u30b9\u30ed\u30ec\u30f3\u30c6\u3002 \u5375\u5de3\u30a2\u30df\u30c9\uff08\u30a2\u30df\u30ce\u30db\u30b9\u30d5\u30a1\u30f3\uff09\u306e\u5316\u5b66\uff1a\u65b0\u3057\u3044\u7528\u9014\u3092\u5099\u3048\u305f\u53e4\u3044\u8a66\u85ac \u3002 \u300c\u73fe\u5728\u306e\u5316\u5b66\u306e\u30c8\u30d4\u30c3\u30af\u300d\u3002 250\u3001s\u3002 77-106\u30012005\u3002Doi\uff1a 10.1007\/B100982 \u3002   \u2191 a b  M. P. Reddy\u3001N\u3002B\u3002Hanna\u3001F\u3002Farooqui\u3002 \u30aa\u30ea\u30b4\u30cc\u30af\u30ec\u30aa\u30c1\u30c9\u306e\u9ad8\u901f\u5207\u65ad\u3068\u8131\u4fdd\u8b77 \u3002 \u201e Tetrahedron Lett\u3002\u300d\u3002 35\uff0825\uff09\u3001s\u3002 4311-4314\u30011994\u3002doi\uff1a 10.1016\/s0040-4039\uff0800\uff0973341-7 \u3002   \u2191  T. L. 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