[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/5018#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/5018","headline":"\u30ea\u30f3Pentachlorore-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","name":"\u30ea\u30f3Pentachlorore-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","description":"before-content-x4 \u30ea\u30f3pentachlorore \u30cd\u30fc\u30df\u30f3\u30b0 \u4f53\u7cfb\u7684\u306a\u547d\u540d\u6cd5\uff08IUPAC\uff09 \u7f8e\u8853\u3002 after-content-x4 \u30ea\u30f3pentachlorore\u3001\u5869\u5316\u30ea\u30f3\uff08V\uff09 \u4e0b \u30da\u30f3\u30bf\u30af\u30ed\u30ed – \u03bb 5-FOSFAN addyt\u3002 Pentachlorydofosfor after-content-x4 \u4ed6\u306e\u540d\u524d\u3068\u30de\u30fc\u30ad\u30f3\u30b0 \u30b9\u30c8\u30c3\u30af \u5869\u5316\u30ea\u30f3\uff08V\uff09 \u4ed6\u306e daw.\u30ea\u30f3\u30da\u30f3\u30bf\u30b4\u30f3","datePublished":"2022-10-17","dateModified":"2022-10-17","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/65\/Phosphorus-pentachloride-2D-dimensions.png\/120px-Phosphorus-pentachloride-2D-dimensions.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/65\/Phosphorus-pentachloride-2D-dimensions.png\/120px-Phosphorus-pentachloride-2D-dimensions.png","height":"109","width":"120"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/5018","wordCount":3696,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4\u30ea\u30f3pentachlorore    \u30cd\u30fc\u30df\u30f3\u30b0  \u4f53\u7cfb\u7684\u306a\u547d\u540d\u6cd5\uff08IUPAC\uff09 \u7f8e\u8853\u3002         (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u30ea\u30f3pentachlorore\u3001\u5869\u5316\u30ea\u30f3\uff08V\uff09 \u4e0b  \u30da\u30f3\u30bf\u30af\u30ed\u30ed – \u03bb 5-FOSFAN addyt\u3002  Pentachlorydofosfor        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u4ed6\u306e\u540d\u524d\u3068\u30de\u30fc\u30ad\u30f3\u30b0 \u30b9\u30c8\u30c3\u30af  \u5869\u5316\u30ea\u30f3\uff08V\uff09 \u4ed6\u306e  daw.\u30ea\u30f3\u30da\u30f3\u30bf\u30b4\u30f3 \u4e00\u822c\u60c5\u5831 \u307e\u3068\u3081 PCL 5  \u30de\u30f3\u30c0\u30fc 208.22 g\/mol        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u5916\u89b3 \u767d\u307e\u305f\u306f\u9ec4\u8272\u3001\u56db\u89d2\u5f62\u306e\u5438\u6e7f\u6027\u7d50\u6676 [\u521d\u3081] \u92ed\u3044\u5302\u3044\u3067 [2] \u8eab\u5143 Numer CAS 10026-13-8     \u5371\u967a \u7279\u6027\u30ab\u30fc\u30c9\uff1a \u5916\u90e8\u30c7\u30fc\u30bf Sigma-Aldrich [\u30a2\u30af\u30bb\u30b92015-07-21]  \u30b0\u30ed\u30fc\u30d0\u30eb\u306b\u8abf\u548c\u3057\u305f\u30b7\u30b9\u30c6\u30e0 \u5316\u5b66\u7269\u8cea\u306e\u5206\u985e\u3068\u30de\u30fc\u30ad\u30f3\u30b0 CLP\u898f\u5236\u306b\u57fa\u3065\u3044\u3066\u3001\u4ed8\u9332VI [4]   \u30d5\u30ec\u30fc\u30bah H302\u3001 H314\u3001 H330\u3001 H373\u3001 EUH014\u3001 EUH029 \u30d5\u30ec\u30fc\u30bap P260\u3001 P280\u3001 P284\u3001 P305+P351+P338\u3001 P310[5] \u7269\u8cea\u306e\u30e8\u30fc\u30ed\u30c3\u30d1\u306e\u30de\u30fc\u30ad\u30f3\u30b0  \u30de\u30fc\u30ad\u30f3\u30b0\u306f\u6b74\u53f2\u7684\u306a\u91cd\u8981\u6027\u306b\u3059\u304e\u307e\u305b\u3093  CLP\u898f\u5236\u306b\u57fa\u3065\u3044\u3066\u3001\u4ed8\u9332VI [4] Silnietoksyczny(T+) r\u3092\u8fd4\u3057\u307e\u3059 R14\u3001 R22\u3001 R26\u3001 R34\u3001 R48\/20 \u30d5\u30ec\u30fc\u30bas S1\/2\u3001 S7\/8\u3001 S26\u3001 S36\/37\/39\u3001 S45  NFPA 704 Na podstawiepodanego \u017ar\u00f3d\u0142a[6] numer rtecs TB6125000 \u81f4\u547d\u7684\u306a\u7528\u91cf Ld 50660 mg\/kg\uff08\u30cd\u30ba\u30df\u3001\u7d4c\u53e3\uff09 [2]\u540c\u69d8\u306e\u95a2\u4fc2 \u540c\u69d8\u306e\u95a2\u4fc2 PCL 3 \u3001 pocl 3  \u7279\u306b\u63d0\u4f9b\u3055\u308c\u306a\u3044\u9650\u308a\u3001\u30c7\u30fc\u30bf\u304c\u9069\u7528\u3055\u308c\u307e\u3059 \u6a19\u6e96\u72b6\u614b\uff0825\u00b0C\u30011000 hPa\uff09  \u30ea\u30f3pentachlorore \uff08\u540d\u524d\u30b9\u30c8\u30c3\u30af\uff1a\u5869\u5316\u30ea\u30f3\uff08V\uff09\uff09 PCL 5  – \u9178\u6027\u5869\u5316\u7269\u306e\u30b0\u30eb\u30fc\u30d7\u304b\u3089\u306e\u7121\u6a5f\u5316\u5408\u7269\u3002 PCL 5 \u5869\u7d20\u5316\u53cd\u5fdc\u3067\u5f97\u3089\u308c\u307e\u3059 PCL 3 \u3002 2000\u5e74\u306e\u3053\u306e\u65b9\u6cd5\u3067\u306f\u3001\u7d0410,000\u4eba\u3067\u751f\u7523\u3055\u308c\u307e\u3057\u305f\u3002\u8abf\u5b50 [7] \u3002 PCL 3 + cl 2  \u21c4 PCL 5 \uff08\u0394H= \u2212124 kJ\/mol\uff09 PCL 5 \u3068\u306e\u30d0\u30e9\u30f3\u30b9\u304c\u53d6\u308c\u3066\u3044\u307e\u3059 PCL 3 \u304a\u3088\u3073\u5869\u7d20\u3002 180\u00b0C\u3067\u306f\u3001\u89e3\u96e2\u306e\u7a0b\u5ea6\u306f\u7d0440\uff05\u3067\u3059 [7] \u3002\u305d\u306e\u3088\u3046\u306a\u30d0\u30e9\u30f3\u30b9\u304c\u5b58\u5728\u3059\u308b\u305f\u3081\u3001\u30b5\u30f3\u30d7\u30eb PCL 5 \u305d\u308c\u3089\u306f\u3057\u3070\u3057\u3070\u5869\u7d20\u3092\u542b\u307f\u3001\u7269\u8cea\u306e\u9ec4\u7dd1\u8272\u306e\u8272\u3092\u5f15\u304d\u8d77\u3053\u3057\u307e\u3059\u3002 \u30ac\u30b9\u3068\u6db2\u76f8\u3067 PCL 5 \u4e09\u89d2\u30d0\u30a4\u30d7\u30e9\u30df\u30c3\u30c9\u5bfe\u79f0\u6027\u3092\u6301\u3064\u7121\u95a2\u5fc3\u306a\u5206\u5b50\u3067\u3059\uff08D 3H \uff09\u30013\u3064\u306e\u6a19\u6e96\u5171\u6709\u7d50\u5408\u3092\u542b\u3080 p  –  cl \u96fb\u6c17\u9762\u30681\u3064\u306e\u30e9\u30a4\u30f33-\u30bb\u30f3\u30c8\u30e9\u30e04\u30a8\u30ec\u30af\u30c8\u30ed\u30f3\u7d50\u5408 cl  –  p  –  cl \u30012\u3064\u306e\u8ef8\u65b9\u5411\u5869\u7d20\u539f\u5b50\u304c\u95a2\u4e0e\u3057\u307e\u3059\u3002\u5206\u5b50\u306b\u306f\u540c\u69d8\u306e\u69cb\u9020\u304c\u3042\u308a\u307e\u3059 PCL 5 \u975e\u6975\u6027\u6eb6\u5a92\u306e\u6eb6\u6db2\u3001\u4f8b\u3048\u3070 CS 2 \u79c1 CCL 4 [8] \u3002 \u4e00\u5b9a\u306e\u72b6\u614b\u3067 PCL 5 \u30a4\u30aa\u30f3\u69cb\u9020\u304c\u3042\u308a\u3001\u56db\u9762\u4f53\u30ab\u30c1\u30aa\u30f3\u304c\u3042\u308a\u307e\u3059 PCL + 4 \u304a\u3088\u3073\u30aa\u30af\u30a8\u30c9\u30ea\u30c3\u30af\u30a2\u30cb\u30aa\u30f3 PCL  –  6 [7] \u3002\u540c\u69d8\u306e\u30a4\u30aa\u30f3\u304c\u6fc3\u7e2e\u6eb6\u6db2\u3067\u89b3\u5bdf\u3055\u308c\u307e\u3059 PCL 5 \u81ea\u5df1\u8010\u6027\u306e\u7d50\u679c\u3068\u3057\u3066\u306e\u6975\u6027\u6eb6\u5a92\u3067 [9] \uff1a 2PCL 5  \u21c4 [PCL + 4 ] [PCL  –  6 ] \u4ee5\u524d\u306f\u30c0\u30a4\u30de\u30fc\u306b\u8a2d\u7acb\u3055\u308c\u307e\u3057\u305f p 2 cl \u5341 \u30e9\u30de\u30f3\u306e\u5206\u5149\u6cd5\u3067\u306f\u78ba\u8a8d\u3055\u308c\u3066\u3044\u307e\u305b\u3093\u3002 \u6975\u6027\u6eb6\u5a92\u4e2d\u306e\u5e0c\u91c8\u6eb6\u6db2\u3067\u306f\u3001\u30aa\u30fc\u30c8\u30c0\u30c7\u30a3\u30bd\u30b7\u30a8\u30fc\u30b7\u30e7\u30f3\u306b\u306f\u7570\u306a\u308b\u30b3\u30fc\u30b9\u304c\u3042\u308a\u307e\u3059\u3002 PCL 5  \u21c4 [PCL + 4 ] cl  –  \u5869\u7d20\u5316\u304a\u3088\u3073\u89e6\u5a92\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u5869\u7d20\u5316\u53cd\u5fdc\u306e\u4f8b\uff1a \u30ab\u30eb\u30dc\u30f3\u9178 + PCl 5 \u2192\u5869\u5316\u30a2\u30b7\u30eb + POCL 3 + HCl \u30a2\u30eb\u30b3\u30fc\u30eb + PCL 5 \u2192\u5869\u5316\u30a2\u30eb\u30ad\u30eb + POCL 3 + HCl r 2 c = O + PCL 5 \u2192R 2 CCL 2 + pocl 3 PCL 5 + 2NO 2 \u2192PCL 3 + 2NO 2 cl \u3055\u3089\u306b\u3001\u305d\u308c\u306fvilsmeier\u8a66\u85ac\u306e\u5f62\u6210\u3068\u3068\u3082\u306b\u30b8\u30e1\u30c1\u30eb\u30db\u30eb\u30e0\u30a2\u30df\u30c9\u3068\u53cd\u5fdc\u3057\u307e\u3059\u3001 [\uff08ch 3 \uff09\uff09 2 ncclh] cl \u3001\u30d9\u30f3\u30ba\u30a2\u30eb\u30c7\u30d2\u30c9\u306e\u8a98\u5c0e\u4f53\u3092\u53d7\u3051\u53d6\u308b\u305f\u3081\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002 PCL 5 \u5f7c\u306f\u307e\u305f\u3001\u30b9\u30c6\u30a3\u30ec\u30f3\u3068\u53cd\u5fdc\u3057\u3001\u30db\u30b9\u30db\u30cd\u30fc\u30c8\u8a98\u5c0e\u4f53\u3092\u4e0e\u3048\u307e\u3059\u3002 \u2191 a b c d \u305d\u3046\u3067\u3059 f   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 4 -80\u3002  \u2191 a b c d \u305d\u3046\u3067\u3059  \u4e94\u5869\u5316\u30ea\u30f3 \u3001 [\u306e\uff1a] -IT-STOFFDATENBANK [\u30aa\u30f3\u30e9\u30a4\u30f3]\u3001 \u30c9\u30a4\u30c4\u306e\u4e8b\u6545\u4fdd\u967a\u306e\u52b4\u50cd\u5b89\u5168\u304a\u3088\u3073\u52b4\u50cd\u5b89\u5168\u5354\u4f1a \u3001ZVG\uff1a3000 [\u30a2\u30af\u30bb\u30b92015-07-21]   \uff08 niem\u3002 \u2022 \u3002 \uff09\uff09 \u3002  \u2191   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 6 -53\u3002  \u2191 a b  \u30ea\u30f3pentachlorore  \uff08 \u3002 \uff09\uff09 \u6b27\u5dde\u5316\u5b66\u6a5f\u95a2\u306e\u5206\u985e\u3068\u30de\u30fc\u30ad\u30f3\u30b0\u306e\u30ea\u30b9\u30c8\u3002 [\u30a2\u30af\u30bb\u30b92015-07-21]\u3002  \u2191  \u30ea\u30f3Pentachlorore\uff08No\u300279590\uff09 -Sigma-Aldrich\uff08Merck KGAA\uff09\u88fd\u54c1\u7279\u6027\u30ab\u30fc\u30c9\u3078\u306e\u30dd\u30fc\u30e9\u30f3\u30c9\u3002 [\u30a2\u30af\u30bb\u30b92015-07-21]\u3002 \uff08\u7279\u6027\u30ab\u30fc\u30c9\u306e\u6b63\u3057\u3044\u30d0\u30fc\u30b8\u30e7\u30f3\u304c\u8868\u793a\u3055\u308c\u3066\u3044\u306a\u3044\u5834\u5408\u306f\u8aad\u3093\u3067\u304f\u3060\u3055\u3044\uff09  \u2191  \u30ea\u30f3pentachlorore \u3001\u56fd\u969b\u5316\u5b66\u5b89\u5168\u30ab\u30fc\u30c9\u3001\u56fd\u969b\u52b4\u50cd\u7d44\u7e54 [\u30a2\u30af\u30bb\u30b92015-07-21]   \uff08 pol\u3002 \u2022 \u3002 \uff09\uff09 \u3002  \u2191 a b c  A.F.\u30db\u30fc\u30eb\u30de\u30f3\u3001E\u3002\u30a6\u30a3\u30d0\u30fc\u30b0\uff1a \u7121\u6a5f\u5316\u5b66 \u3002\u30b5\u30f3\u30c7\u30a3\u30a8\u30b4\uff1a\u30a2\u30ab\u30c7\u30df\u30c3\u30af\u30d7\u30ec\u30b9\u30012001\u5e74\u3002ISBN 0-12-352651-5 \u3002  \u2191  D.E.C.\u30b3\u30fc\u30d6\u30ea\u30c3\u30b8\uff1a \u30ea\u30f3\uff1a\u305d\u306e\u5316\u5b66\u3001\u751f\u5316\u5b66\u3001\u6280\u8853\u306e\u6982\u8981 \u3002 WYD\u3002 5.\u30a2\u30e0\u30b9\u30c6\u30eb\u30c0\u30e0\uff1aElsevier\u30011995\u3002ISBN 0-444-89307-5 \u3002  \u2191  R.W. Suter\u3001H.C\u3002\u30ca\u30c1\u30a7\u30eb\u3001V.P\u3002\u30da\u30c8\u30ed\u3001J.H\u3002 howatson i inni\u3002 \u30a4\u30aa\u30f3\u5316\u304a\u3088\u3073\u975e\u56fa\u5b9a\u6eb6\u5a92\u4e2d\u306e\u5869\u5316\u30ea\u30f3\uff08V\uff09\u306e\u6027\u8cea \u3002 \u201e J. Amer\u3002\u5316\u5b66\u3002 soc\u3002\u300d\u3002 95\u3001s\u3002 1474\u20131479\u30011973\u3002Doi\uff1a 10.1021 \/ ja00786a021 \u3002         (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/5018#breadcrumbitem","name":"\u30ea\u30f3Pentachlorore-\u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178"}}]}]