[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/9018#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/9018","headline":"\u30b7\u30a2\u30f3\u5316\u6c34\u7d20 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","name":"\u30b7\u30a2\u30f3\u5316\u6c34\u7d20 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178","description":"before-content-x4 \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u30cd\u30fc\u30df\u30f3\u30b0 \u4f53\u7cfb\u7684\u306a\u547d\u540d\u6cd5\uff08IUPAC\uff09 \u7f8e\u8853\u3002 after-content-x4 \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u4e0b Metylidynoazan addyt\u3002 Hydridonitridogiel after-content-x4 \u4ed6\u306e\u540d\u524d\u3068\u30de\u30fc\u30ad\u30f3\u30b0 formonitryl;\u6c34\u6eb6\u6db2\uff1a\u5869\u9178\u3001\u30d7\u30ed\u30a4\u30bb\u30f3\u9178 \u4e00\u822c\u60c5\u5831 \u307e\u3068\u3081 HCN \u305d\u306e\u4ed6\u306e\u30c7\u30b6\u30a4\u30f3 h –","datePublished":"2023-02-10","dateModified":"2023-02-10","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/44a4cee54c4c053e967fe3e7d054edd4?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/3\/34\/Hydrogen-cyanide-2D.png\/160px-Hydrogen-cyanide-2D.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/3\/34\/Hydrogen-cyanide-2D.png\/160px-Hydrogen-cyanide-2D.png","height":"44","width":"160"},"url":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/9018","wordCount":6937,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4\u30b7\u30a2\u30f3\u5316\u6c34\u7d20  \u30cd\u30fc\u30df\u30f3\u30b0  \u4f53\u7cfb\u7684\u306a\u547d\u540d\u6cd5\uff08IUPAC\uff09 \u7f8e\u8853\u3002         (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u4e0b  Metylidynoazan addyt\u3002  Hydridonitridogiel        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u4ed6\u306e\u540d\u524d\u3068\u30de\u30fc\u30ad\u30f3\u30b0 formonitryl;\u6c34\u6eb6\u6db2\uff1a\u5869\u9178\u3001\u30d7\u30ed\u30a4\u30bb\u30f3\u9178 \u4e00\u822c\u60c5\u5831 \u307e\u3068\u3081 HCN \u305d\u306e\u4ed6\u306e\u30c7\u30b6\u30a4\u30f3 h  –  c \u559c\u3093\u3067 n  \u30de\u30f3\u30c0\u30fc 27.03 g\/mol \u5916\u89b3 \u82e6\u3044\u30a2\u30fc\u30e2\u30f3\u30c9\u306e\u5302\u3044\u304c\u3059\u308b\u7121\u8272\u306e\u63ee\u767a\u6027\u6db2\u4f53 [\u521d\u3081] [2] [3] [4] [5]        (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4\u8eab\u5143 Numer CAS 74-90-8  Pubchem 768  \u30a4\u30f3\u30c1 inchi = 1s\/chn\/c1-2\/h1h inchikey lelowrisymnnnsu-uhfffaoysa-n \u30d7\u30ed\u30d1\u30c6\u30a3  \u5bc6\u5ea6 0,6876 g\/cm\u00b3\uff0820\u00b0C\uff09 [7] ;\u6db2\u4f53  \u6c34\u6eb6\u6027 \u6df7\u5408 [6] \u4ed6\u306e\u6eb6\u5a92\u3067 \u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u3001\u30af\u30ed\u30ed\u30db\u30eb\u30e0\u3001\u30d9\u30f3\u30bc\u30f3\u3001Meoh\u3068\u6df7\u5408 [6] \u3001etoh i eterem [7] ; disulphide\uff085\uff05\uff09\u3001\u77f3\u70ad\u56db\u91cd\u5c64\uff085\uff05\uff09 [6] [3] [4] [5]  \u878d\u70b9 -13,29\u00b0C [7] \u6cb8\u70b9 25,70\u00b0C [9] \u91cd\u8981\u306a\u30dd\u30a4\u30f3\u30c8 183,5\u00b0C [9] ; 5,4 MPa [\u5341] logp -0,25 [8] \u9178\u6027\u5ea6\uff08pk a \uff09\uff09 9.36 [9] \u7c98\u5ea6 0,183 MPa\u30fbs [11] \u8868\u9762\u5f35\u529b 18.33 mn\/m\uff0820\u00b0C\uff09 [9]   \u540c\u69d8\u306e\u95a2\u4fc2 \u540c\u69d8\u306e\u95a2\u4fc2 \u30b7\u30a2\u30cb\u30a2\u30f3\u3001\u30b7\u30a2\u30ce\u30f3\u3001\u30c1\u30aa\u30b7\u30a2\u30cb\u3001\u30a2\u30bb\u30c1\u30ec\u30f3 \u7279\u306b\u63d0\u4f9b\u3055\u308c\u306a\u3044\u9650\u308a\u3001\u30c7\u30fc\u30bf\u304c\u9069\u7528\u3055\u308c\u307e\u3059 \u6a19\u6e96\u72b6\u614b\uff0825\u00b0C\u30011000 hPa\uff09   \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u3001HCN-\u6c34\u7d20\u3001\u77f3\u70ad\u3001\u7a92\u7d20\u3067\u69cb\u7bc9\u3055\u308c\u305f\u7121\u6a5f\u5316\u5408\u7269\u3002\u3053\u308c\u306f\u3001\u7121\u8272\u3067\u3001\u63ee\u767a\u6027\u304c\u3042\u308a\u3001\u5f37\u304f\u6709\u6bd2\u306a\u6db2\u4f53\u3067\u3001\u82e6\u3044\u30a2\u30fc\u30e2\u30f3\u30c9\u306e\u5302\u3044\u304c\u3057\u307e\u3059\uff08\u305f\u3060\u3057\u3001\u4e00\u90e8\u306e\u4eba\u3005\u306f\u611f\u899a\u3067\u304d\u306a\u3044\u5834\u5408\u304c\u3042\u308a\u307e\u3059\uff09\u3002\u6c34\u3067\u3001\u5869\u9178\u304c\u8ca7\u5f31\u306b\u306a\u308a\u307e\u3059\uff08 \u30d7\u30ed\u30a4\u30bb\u30f3\u9178 \uff09\u3001\u305d\u306e\u5869\u306f\u30b7\u30a2\u30f3\u5316\u7269\u3068\u547c\u3070\u308c\u307e\u3059\u3002\u5f7c\u306f\u5316\u5b66\u5408\u6210\u3068\u5206\u6790\u3001\u304a\u3088\u3073\u8fb2\u85ac\u3068\u3057\u3066\u306e\u5fdc\u7528\u3092\u767a\u898b\u3057\u307e\u3057\u305f\u3002\u7b2c\u4e8c\u6b21\u4e16\u754c\u5927\u6226\u4e2d\u3001\u305d\u308c\u306f\u30b5\u30a4\u30af\u30ed\u30f3B\u3068\u3044\u3046\u540d\u524d\u3067\u4f7f\u7528\u3055\u308c\u3001\u30c9\u30a4\u30c4\u306e\u7d76\u6ec5\u30ad\u30e3\u30f3\u30d7\u3067\u56da\u4eba\u3092\u6bd2\u6bba\u3057\u307e\u3057\u305f\u3002\u3053\u308c\u306f\u3001\u4e00\u822c\u7684\u306a\u6709\u6bd2\u306a\u6226\u95d8\u63aa\u7f6e\u306b\u542b\u307e\u308c\u3066\u304a\u308a\u3001\u5316\u5b66\u5175\u5668\u306e\u8d64\u3061\u3083\u3093\u306b\u95a2\u3059\u308b\u7b2c3\u6761\u7d04\u306e\u30ea\u30b9\u30c8\u306b\u5165\u529b\u3055\u308c\u3066\u3044\u307e\u3059\u3002 1780\u5e74\u306b\u89e3\u6c7a\u7b56\u306e\u5f62\u3067\u6700\u521d\u306b\u53d7\u3051\u53d6\u3089\u308c\u307e\u3057\u305f [16] 1782\u5e74 [17] \u30ab\u30fc\u30eb\u30fb\u30b7\u30fc\u30ec\u306b\u3088\u308b\u5e74\u3002\u7d14\u7c8b\u306a\u5f62\u3067\u306f\u30011815\u5e74\u306b\u30b8\u30e7\u30bb\u30d5\u30fb\u30b2\u30a4\u30fb\u30ed\u30b5\u30c3\u30af\u306b\u3088\u3063\u3066\u4f5c\u6210\u3055\u308c\u307e\u3057\u305f [17] \u3002 \u81ea\u7136\u754c\u3067\u306f\u3001\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u30d8\u30c6\u30ed\u30b5\u30a4\u30c9\u306b\u95a2\u9023\u3059\u308b\u5f62\u3067\u767a\u751f\u3057\u307e\u3059\u3002\u7a2e\u5b50\u3068\u30d1\u30b9\u30c6\u30eb\u306e\u8449\u3001\u305f\u3068\u3048\u3070\u3001\u30d3\u30bf\u30fc\u30a2\u30fc\u30e2\u30f3\u30c9\u3001\u6843\u3001\u30a2\u30d7\u30ea\u30b3\u30c3\u30c8\u306e\u7a2e\uff08\u30a2\u30df\u30b0\u30c0\u30ea\u30f3\u3092\u542b\u3080\uff09\u3001\u767d\u3044\u30af\u30ed\u30fc\u30d0\u30fc\uff08\u30ea\u30ca\u30de\u30ea\u30ca\u3068\u30ed\u30c8\u30d0\u30b9\uff09\u306f\u7279\u306b\u8c4a\u5bcc\u3067\u3059\u3002 [3] [4] [5] \u3002\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3082\u30bf\u30d0\u30b3\u306e\u7159\u306b\u5b58\u5728\u3057\u307e\u3059 [3] \u3002 Table of Contents\u30e9\u30dc [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u7523\u696d\u898f\u6a21 [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30a2\u30f3\u30c9\u30e9\u30b9\u30d7\u30ed\u30bb\u30b9 [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] BMA [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30b7\u30e3\u30a6\u30a3\u30cb\u30ac\u30f3\u30c8\u30e9\u30a4\u30a2\u30eb [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30e9\u30dc [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] Carl Scheele\u306fPrussian Blue\u304b\u3089HCN\u3092\u53d7\u3051\u53d6\u308a\u307e\u3057\u305f\u3001 fek [fe\uff08cn\uff09 6 ] \uff08\u3057\u305f\u304c\u3063\u3066\u3001\u305d\u306e\u53e3\u8a9e\u7684\u306a\u30c9\u30a4\u30c4\u306e\u540d\u524d\u306f\u7531\u6765\u3057\u307e\u3057\u305f \u9752\u9178  – \u300c\u9752\u9178\u300d\u3068\u82f1\u8a9e \u30d7\u30eb\u3042\u308a\u9178 \u305d\u3057\u3066\u30e9\u30c6\u30f3\u8a9e Acid Prussicum  – \u300c\u30d7\u30ed\u30a4\u30bb\u30f3\u9178\u300d\uff09 [16] \u3002 \u73fe\u5728\u3001\u5b9f\u9a13\u5ba4\u306e\u91cd\u8981\u6027\u306f\u3001\u30b7\u30a2\u30f3\u5316\u7269\u306e\u53cd\u5fdc\uff08\u307e\u305f\u306f\u30d8\u30ad\u30b5\u30a4\u30e0\uff08II\uff09\u30d8\u30ad\u30b5\u30b7\u30a2\u306a\u3069\u306e\u30d8\u30ad\u30b7\u30e5\u30fc\u30eb – \u30b2\u30fc\u30c8\uff08II\uff09\u3067\u3042\u308a\u3001\u5f37\u9178\u3068\u7d50\u679c\u3068\u3057\u3066\u751f\u3058\u308b\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306e\u30ea\u30b5\u30a4\u30af\u30eb\u3092\u4f34\u3046 [\u521d\u3081] [18] \uff1a 2kcn + h 2 \u305d\u308c\u3067 4 \u21922HCN + K 2 \u305d\u308c\u3067 4 NACN + HCL\u2192HCN + NACL k 4 [Fe\uff08CN\uff09 6 ] + 6HCl\u21926HCN + 4KCL + FECL 2 \u307e\u305f\u306f\u3001\u6c38\u4e45\u7684\u306a\u6c34\u9280\u30b7\u30a2\u30f3\u5316\u7269\u306e\u4e0a\u306b\u786b\u5316\u6c34\u7d20\u30da\u30a2\u3092\u901a\u904e\u3059\u308b\uff08II\uff09 [\u521d\u3081] \uff1a h 2 S + HG\uff08CN\uff09 2 \u21922HCN + HGS \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u3001\u30e1\u30bf\u30ce\u30fc\u30eb\uff08\u89e6\u5a92\u3092\u4f34\u3046600\u301c950\u00b0C\u3067\u306e\u7a7a\u6c17\u30a2\u30af\u30bb\u30b9\u306a\u3057\uff09\u307e\u305f\u306f\u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\uff081100\u301c1300\u00b0C\uff09\u3092\u52a0\u71b1\u3057\u3001\u6e29\u5ea6\u306e\u4e0a\u6607\u3068\u6e1b\u5c11\u5727\u529b\u3067\u30db\u30eb\u30e0\u30a2\u30df\u30c9\u306e\u71b1\u5206\u5e03\u3092\u4ecb\u3057\u3066\u52a0\u71b1\u3059\u308b\u3053\u3068\u3067\u5f97\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002 [18] \uff1a ch 3 OH + NH 3 \u2192HCN +H\u3002 2 o + h 2 ch 3 CN + NH 3 2HCN + 2H 2 HCHH 2 \u2192HCN +H\u3002 2 o \u7523\u696d\u898f\u6a21 [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u904e\u53bb\u306b\u306f\u3001\u30b7\u30a2\u30f3\u5316\u7269\u3092\u9178\u6027\u5316\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u304c\u5de5\u696d\u7684\u306b\u5f97\u3089\u308c\u307e\u3057\u305f\uff08\u4f8b\uff1aNACN\u307e\u305f\u306f CA\uff08CN\uff09 2 \uff09\uff09 [19] \u3002\u73fe\u5728\u30013\u3064\u306e\u7523\u696d\u30d7\u30ed\u30bb\u30b9\u304c\u4f7f\u7528\u3055\u308c\u3066\u304a\u308a\u3001\u30b7\u30a2\u30f3\u5316\u6c34\u7d20 – \u30a2\u30f3\u30c9\u30eb\u30b7\u306e\u30d7\u30ed\u30bb\u30b9\u3001BMA\u30d7\u30ed\u30bb\u30b9\u3001\u30b7\u30e3\u30a6\u30a3\u30cb\u30ac\u30f3\u30d7\u30ed\u30bb\u30b9\u3092\u53d6\u5f97\u3057\u3066\u3044\u307e\u3059\u3002\u305f\u3060\u3057\u3001\u6c34\u7d20\u306e\u4e16\u754c\u751f\u7523\u306e\u7d0425\uff05\u306e\u5834\u5408\u3001Sohio\u30d7\u30ed\u30bb\u30b9\u304c\u8cac\u4efb\u3092\u8ca0\u3044\u307e\u3059\u3002\u3053\u306e\u30d7\u30ed\u30bb\u30b9\u3067\u306f\u3001HCN\u306f\u30d7\u30ed\u30d4\u30ec\u30f3\u3068\u30a2\u30f3\u30e2\u30cb\u30a2\u304b\u3089\u30a2\u30af\u30ea\u30ed\u30cb\u30c8\u30ea\u30eb\u3092\u53d6\u5f97\u3059\u308b\u3053\u3068\u306eby -product\u3068\u3057\u3066\u4f5c\u6210\u3055\u308c\u307e\u3059\u3002 [20] \u3002 \u30a2\u30f3\u30c9\u30e9\u30b9\u30d7\u30ed\u30bb\u30b9 [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3092\u5f97\u308b\u7523\u696d\u306e\u6700\u3082\u91cd\u8981\u306a\u65b9\u6cd5\u306f\u3001\u30a2\u30f3\u30c9\u30e9\u30b9\u30d7\u30ed\u30bb\u30b9\u3067\u3059\uff081927\u5e74\u306b\u30ec\u30aa\u30cb\u30fc\u30c9\u30a2\u30f3\u30c9\u30ed\u30c3\u30bd\u30a6\u306b\u3088\u3063\u3066\u767a\u898b\u3055\u308c\u305f\u53cd\u5fdc\u306b\u57fa\u3065\u3044\u3066\u3044\u307e\u3059 [21] \uff09\u3001\u7a7a\u6c17\u304b\u3089\u306e\u9178\u7d20\u306e\u95a2\u4e0e\u3092\u4f34\u3046\u30e1\u30bf\u30f3\u3068\u30a2\u30f3\u30e2\u30cb\u30a2\u3068\u306e\u767a\u71b1\u53cd\u5fdc\u304c\u8d77\u3053\u308b [22] \uff1a ch 4 + nh 3 +1\u00bdo 2 \u2192HCN + 3H 2 o \uff08 \u0394H= \u2212474 kJ\/mol \uff09\uff09 [9] \u53cd\u5fdc\u306f\u30d7\u30e9\u30c1\u30ca\u307e\u305f\u306f\u305d\u306e\u8db3\u306b\u3088\u3063\u3066\u5bb6\u65cf\u307e\u305f\u306f\u30a4\u30ea\u30b8\u30a6\u30e0\u3068\u89e6\u5a92\u3055\u308c\u307e\u3059 [19] \uff08\u6700\u3082\u4e00\u822c\u7684\u306b\u4f7f\u7528\u3055\u308c\u308b\u306e\u306f\u300190\uff05\u30d7\u30e9\u30c1\u30ca\u3068\u30d5\u30a1\u30df\u30ea\u30fc\u89e6\u5a92\u306e10\uff05\u3067\u3059 [23] \uff09\u3002\u3053\u306e\u30d7\u30ed\u30bb\u30b9\u306f\u30011000\u00b0C\u3092\u8d85\u3048\u308b\u6e29\u5ea6\u3067\u5b9f\u884c\u3055\u308c\u307e\u3059\u3002\u9162\u9178\u5f8c\u306e\u30ac\u30b9\u306f\u3001\u786b\u9178\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u306e\u6eb6\u6db2\u3092\u786b\u9178\u3068\u6eb6\u6db2\u3067\u6d17\u6d44\u3057\u307e\u3059\u3002\u305d\u306e\u5f8c\u3001\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u6c34\u306b\u5438\u53ce\u3055\u308c\uff08\u786b\u9178\u3067\u9178\u6027\u304c\u4f4e\u3044\uff09\u3001\u3053\u306e\u6eb6\u6db2\u304b\u3089\u84b8\u7559\u3055\u308c\u307e\u3057\u305f [24] \u3002\u3053\u306e\u30d7\u30ed\u30bb\u30b9\u306e\u5229\u70b9\u306f\u3001\u89e6\u5a92\u3001\u5b9f\u8a3c\u6e08\u307f\u306e\u6280\u8853\u3001\u304a\u3088\u3073\u5f97\u3089\u308c\u305f\u88fd\u54c1\u306e\u9ad8\u7d14\u5ea6\u306e\u9577\u3044\u52b4\u50cd\u6642\u9593\u3067\u3059\u304c\u3001\u4f7f\u7528\u6e08\u307f\u306e\u89e6\u5a92\u306f\u30e1\u30bf\u30f3\u306b\u5b58\u5728\u3059\u308b\u6c5a\u67d3\u7269\u8cea\u306e\u4e2d\u6bd2\u3092\u53d7\u3051\u3084\u3059\u304f\uff08\u9ad8\u70ad\u5316\u7269\u3001\u786b\u9ec4\u5316\u5408\u7269\u3001\u30ea\u30f3\u5316\u5408\u7269\uff09\u3001\u9ad8\u7d14\u5ea6\u7d14\u5ea6\u304c\u5fc5\u8981\u3067\u3059\u3002 [9] \u3002 BMA [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3082BMA\u30d7\u30ed\u30bb\u30b9\u3067\u5f97\u3089\u308c\u307e\u3059\uff08\u30c9\u30a4\u30c4\u8a9e \u30d6\u30eb\u30fc\u30b7\u30f3\u9178 – \u30e1\u30bf\u30f3\u30b3\u30ec\u30af\u30bf\u30fc \u3001\u307e\u305f\uff1adeguss\u30d7\u30ed\u30bb\u30b9 [25] \uff09\u3002\u9ad8\u6e29\u306e\u30a2\u30f3\u30e2\u30cb\u30a2\u3068\u306e\u30e1\u30bf\u30f3\u53cd\u5fdc\u304c\u3042\u308a\u3001\u30d7\u30e9\u30c1\u30ca\u89e6\u5a92\u3082\u4f7f\u7528\u3057\u307e\u3059 [\u521d\u3081] \uff1a ch 4 + nh 3 \u2192HCN + 3H 2 \uff08 \u0394H= +252 kJ\/mol \uff09\uff09 [9] \u30d7\u30ed\u30bb\u30b9\u306e\u5438\u71b1\u306b\u3088\u308a\u3001\u71b1\u3092\u63d0\u4f9b\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u53cd\u5fdc\u7089\u3067\u3001\u53cd\u5fdc\u7089\u3067\u3001\u89e6\u5a92\u306e\u5c64\u3067\u5185\u5074\u304b\u3089\u306e\u713c\u7d50\u9178\u5316\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u306e\u30d1\u30a4\u30d7\u3092\u6881\u3092\u6e21\u3059\u3053\u3068\u306b\u3088\u308a\u3001\u539f\u6750\u6599\u3092\u6e21\u3059\u3053\u3068\u306b\u3088\u3063\u3066\u5b9f\u88c5\u3055\u308c\u307e\u3059\u3002\u305d\u3053\u3067\u306f\u3001\u53cd\u5fdc\u6df7\u5408\u7269\u30921200\u00b0C\u4ee5\u4e0a\u306b\u52a0\u71b1\u3057\u307e\u3059\u3002\u30d1\u30a4\u30d7\u3092\u96e2\u308c\u305f\u5f8c\u3001\u30ac\u30b9\u306f300\u00b0C\u306b\u51b7\u5374\u3055\u308c\u307e\u3059\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u3001\u30a2\u30f3\u30c9\u30ed\u30b7\u30a2\u306e\u30d7\u30ed\u30bb\u30b9\u3068\u540c\u69d8\u306e\u65b9\u6cd5\u3067\u6d17\u6d44\u304a\u3088\u3073\u5206\u6ccc\u3055\u308c\u3001\u6700\u521d\u306e\u30d7\u30ed\u30bb\u30b9\u3068\u6bd4\u8f03\u3057\u3066\u30dd\u30b9\u30c8\u53cd\u5fdc\u30ac\u30b9\u306e\u542b\u6709\u91cf\u304c\u591a\u3044\u305f\u3081\u3001\u88c5\u7f6e\u306e\u30b5\u30a4\u30ba\u3068\u30b3\u30b9\u30c8\u3092\u524a\u6e1b\u3067\u304d\u307e\u3059\u3002 [9] \u3002 \u30b7\u30e3\u30a6\u30a3\u30cb\u30ac\u30f3\u30c8\u30e9\u30a4\u30a2\u30eb [ \u7de8\u96c6 | \u30b3\u30fc\u30c9\u3092\u7de8\u96c6\u3057\u307e\u3059 ] \u3053\u306e\u30d7\u30ed\u30bb\u30b9\u3067\u306f\u3001\u96fb\u6c17\u7684\u306b\u52a0\u71b1\u3055\u308c\u305f\u30b3\u30fc\u30ad\u30f3\u30b0\u6db2\u4e2d\u306e\u30a2\u30f3\u30e2\u30cb\u30a2\u3092\u542b\u3080\u30ac\u30b9\u70ad\u5316\u6c34\u7d20\uff08\u901a\u5e38\u306f\u30d7\u30ed\u30d1\u30f3\uff09\uff1a NH 3 + c 3 h 8 \u21923HCN + 7H 2 \uff08 \u0394H= +634 kJ\/mol \uff09\uff09 \u3053\u306e\u30d7\u30ed\u30bb\u30b9\u306f\u30011500\u00b0C\u3092\u8d85\u3048\u308b\u6e29\u5ea6\u3067\u767a\u751f\u3057\u3001\u89e6\u5a92\u306e\u4f7f\u7528\u3092\u5fc5\u8981\u3068\u3057\u307e\u305b\u3093\u3002\u307e\u305f\u3001\u5c11\u306a\u304f\u3068\u308285\uff05\u306b\u9054\u3059\u308b\u305f\u3081\u3001\u30a2\u30f3\u30e2\u30cb\u30a2\u5438\u53ce\u88c5\u7f6e\u3092\u4f7f\u7528\u3059\u308b\u5fc5\u8981\u306f\u3042\u308a\u307e\u305b\u3093\u3002\u305f\u3060\u3057\u3001\u5927\u304d\u306a\u4e0d\u5229\u306a\u70b9\u306f\u3001\u96fb\u529b\u6d88\u8cbb\u91cf\u304c\u9ad8\u3044\u3053\u3068\u3067\u3042\u308a\u3001\u3053\u306e\u30d7\u30ed\u30bb\u30b9\u306e\u4f7f\u7528\u3092\u5b89\u4fa1\u306a\u30a8\u30ea\u30a2\u306b\u5236\u9650\u3057\u307e\u3059 [9] \u3002 \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u3001\u82e6\u3044\u30a2\u30fc\u30e2\u30f3\u30c9\u306e\u5f37\u3044\u5302\u3044\u3092\u6301\u3064\u7121\u8272\u306e\u6db2\u4f53\u3067\u3059 – \u30d5\u30a7\u30eb\u30c8\u306e\u3057\u304d\u3044\u5024\u306f0.002\u301c0.005 mg\/dm\u00b3\u306e\u7a7a\u6c17\u3067\u3059 [3] [4] \u3002\u3057\u304b\u3057\u3001\u305d\u308c\u3092\u611f\u3058\u306a\u3044\u4eba\u3082\u3044\u308b\u304b\u3082\u3057\u308c\u307e\u305b\u3093 [26] \u3002\u305d\u308c\u306f\u9ad8\u3044\u30dc\u30e9\u30c6\u30a3\u30ea\u30c6\u30a3\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002\u6c34\u3068\u30a2\u30eb\u30b3\u30fc\u30eb\u3068\u7c21\u5358\u306b\u6df7\u305c\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u7a7a\u4e2d\u3067\u306f\u3001\u9752\u3044\u708e\u3067\u71c3\u3048\u307e\u3059 [17] \u3002\u540c\u6642\u306b\u3001\u53cd\u5fdc\u306f\u6b21\u306e\u3068\u304a\u308a\u3067\u3059 [27] \uff1a 4HCN + 5O 2 2H 2 O + 2N 2 + 4co 2 \u304b\u306a\u308a\u306e\u91cf\u306e\u7a92\u7d20\u9178\u5316\u7269\u3082\u53cd\u5fdc\u3067\u767a\u751f\u3059\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u6e29\u5ea6\u3001\u9178\u7d20\u3078\u306e\u30a2\u30af\u30bb\u30b9\u3001\u89e6\u5a92\u306e\u5b58\u5728\u306b\u4f9d\u5b58\u3057\u307e\u3059\u3002\u30b7\u30a2\u30f3\u30b9\u9178\u306e\u6df7\u5408\u7269\u3067\u3042\u308b\u6c38\u4e45\u88fd\u54c1\u306e\u6642\u6298\u5f62\u6210\u3082\u767a\u898b\u3055\u308c\u307e\u3057\u305f \uff08hocn\uff09 3 \u3001\u30b5\u30a4\u30af\u30ec\u30fc\u30c9 \uff08hocn\uff09_ {n }\u3001\u30b7\u30a2\u30f3\u9178\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0 NH 4 OCN \u3068\u5c3f\u7d20 \uff08NH 2 \uff09\uff09 2 co [27] \u3002 \u305d\u306e\u30da\u30a2\u306f\u3001\u7a7a\u6c17\u3068\u306e\u7206\u767a\u7684\u306a\u6df7\u5408\u7269\u3092\u5f62\u6210\u3057\u307e\u3059\uff08\u4f53\u7a4d\u306e6\u301c41\uff05\u4ee5\u5185\uff09 [28] \u3002\u793e\u4f1a\u306f\u975e\u5e38\u306b\u5f31\u3044\uff08PKA = 9.36\uff09 [9] \u3002 \u6761\u4ef6\u306b\u5fdc\u3058\u3066\u3001\u305d\u308c\u306f\u91cd\u5408\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059 – \u305d\u306e\u30aa\u30ea\u30b4\u30de\u30fc\u306b\u306f\u3001\u30a2\u30df\u30ce\u30de\u30ed\u30cb\u30c8\u30ea\u30eb\uff08\u30c8\u30ea\u30de\u30fc\uff09\u3068\u30b8\u30a2\u30df\u30ce\u30de\u30ed\u30cb\u30c8\u30ea\u30eb\uff08\u56db\u91cf\u4f53\uff09\u304c\u542b\u307e\u308c\u307e\u3059 [29] \u3002\u30b7\u30ab\u30f3\u9178\u3092\u5f62\u6210\u3059\u308b\u7a7a\u6c17\u4e2d\u304a\u3088\u3073\u30b7\u30a2\u30f3\u306e\u91cf\u306e\u52a0\u71b1\u4e2d\u306e\u6c34\u7d20\u9178\u5316\uff08300-650\u00b0C\uff09 [30] \uff1a hcn + o 2 2\u30db\u30c3\u30af 4hcn + o 2 \u21922\uff08CN\uff09 2 + 2H 2 o \u53cd\u5fdc\u306f\u91d1\u3068\u9280\u306b\u3088\u3063\u3066\u89e6\u5a92\u3055\u308c\u3001\u9280\u89e6\u5a92\u304c\u30b7\u30a2\u30f3\u5316\u7269\u306e\u7372\u5f97\u306b\u3064\u306a\u304c\u308a\u307e\u3059\u3002 \u30eb\u30fc\u30eb\u3068\u306e\u53cd\u5fdc\u3067\u306f\u3001\u9069\u5207\u306a\u30b7\u30a2\u30f3\u5316\u7269\u304c\u4f5c\u6210\u3055\u308c\u307e\u3059 [30] \uff1a HCN + NAOH\u2192NACN +H\u3002 2 o 2HCN + CA\uff08OH\uff09 2 \u2192CA\uff08CN\uff09 2 + h 2 o 2HCN + NA 2 co 3 \u21922NACN + H 2 o + what 2 [29] \u53cd\u5fdc\u306f\u3001\u30a2\u30eb\u30c7\u30d2\u30c9\u306e\u30ab\u30eb\u30dc\u30cb\u30eb\u57fa\u3068\u30b7\u30a2\u30ce\u30d2\u30c9\u30ea\u30f3\u306e\u8702\u8d77\u3092\u4f34\u3046\u307b\u3068\u3093\u3069\u306e\u30b1\u30c8\u30f3\u306b\u53cd\u5fdc\u3057\u307e\u3059\u3002 rcor \u2032 + hcn\u2192rc\uff08oh\uff09\uff08cn\uff09r’ \u3053\u306e\u53cd\u5fdc\u306f\u7523\u696d\u7684\u306b\u91cd\u8981\u3067\u3042\u308a\u3001\u305d\u306e\u4f4e\u901f\u306e\u305f\u3081\u3001\u901a\u5e38\u3001\u89e6\u5a92\u3068\u3057\u3066\u8ca7\u3057\u3044\u30eb\u30fc\u30eb\uff08\u4f8b\u3048\u3070\u30b7\u30a2\u30f3\u5316\u30ab\u30ea\u30a6\u30e0\uff09\u3092\u4f7f\u7528\u3057\u3066\u5b9f\u884c\u3055\u308c\u307e\u3059 [30] \u3002 \u6c34\u751f\u6eb6\u6db2\u3067\u306f\u3001\u975e\u6bd2\u6027\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a2\u30ea\u306b\u52a0\u6c34\u5206\u89e3\u3057\u307e\u3059 [\u6700\u521d\u306b30] \uff1a hcn + 2 h 2 O\u2192HCOONH 4 \u3053\u308c\u306f\u3001\u90e8\u5c4b\u3001\u4f8b\u3048\u3070\u8239\u3084\u5009\u5eab\u306e\u6d88\u6bd2\u3068\u8131\u578b\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u5869\u306e\u5f62\u3067\u3001\u51b6\u91d1\u7523\u696d\u3001\u4e9c\u925b\u3081\u3063\u304d\u3001\u53e4\u5178\u7684\u306a\u5316\u5b66\u5206\u6790\uff08\u30a4\u30aa\u30f3\u3067\u4f7f\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002 CN  –  \u5f37\u304f\u8907\u96d1\u306a\u9077\u79fb\u91d1\u5c5e\uff09 [3] [4] [5] \u3002 \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u3001\u4e3b\u306b\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u7523\u696d\u306b\u304a\u3051\u308b\u30e1\u30c1\u30eb\u30e1\u30bf\u30af\u30ea\u30eb\u9178\u30e1\u30c1\u30eb\u306e\u751f\u7523\u3068\u3001\u30b7\u30a2\u30f3\u5316\u30ab\u30ea\u30a6\u30e0\u3068\u30b7\u30a2\u30f3\u5316\u30ca\u30c8\u30ea\u30a6\u30e0\u3001\u30a2\u30c7\u30a3\u30dd\u30cb\u30c8\u30ea\u30eb\u3001\u30e1\u30c1\u30aa\u30cb\u30f3\u3001\u5869\u5316\u7269\u30b7\u30a2\u30f3\u30fc\u30eb\u3001\u30b7\u30a2\u30f3\u5316\u7269\u3001\u30b7\u30a2\u30f3\u5316\u7269\u3001\u30cb\u30c8\u30ea\u30ed\u30c3\u30c8\u30ea\u30b1\u30c3\u30c8\u9178\u3001\u304a\u3088\u3073\u3044\u304f\u3064\u304b\u306e\u30c8\u30ea\u30a2\u30b8\u3092\u5f97\u308b\u305f\u3081\u306e\u5408\u6210\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002 [17] \u3002 \u307e\u305f\u3001\u30ac\u30b9\u5ba4\u3067\u6b7b\u5211\u3092\u79d1\u3059\u305f\u3081\u306b\u3082\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u7b2c\u4e8c\u6b21\u4e16\u754c\u5927\u6226\u4e2d\u3001\u305d\u308c\u306f\u30c9\u30a4\u30c4\u306e\u7d76\u6ec5\u30ad\u30e3\u30f3\u30d7\u306e\u5927\u8846\u6bba\u4eba\u306e\u30b3\u30de\u30fc\u30b7\u30e3\u30eb\u540d\u30b5\u30a4\u30af\u30ed\u30f3B\u306e\u4e0b\u3067SS\u306b\u3088\u3063\u3066\u4f7f\u7528\u3055\u308c\u307e\u3057\u305f\u3002\u7b2c\u4e00\u6b21\u4e16\u754c\u5927\u6226\u4e2d\u3001\u305d\u308c\u3092\u6226\u95d8\u4e2d\u306e\u30a8\u30fc\u30b8\u30a7\u30f3\u30c8\u3068\u3057\u3066\u4f7f\u7528\u3057\u3088\u3046\u3068\u3057\u307e\u3057\u305f\u304c\u3001\u30dc\u30e9\u30c6\u30a3\u30ea\u30c6\u30a3\u304c\u9ad8\u3044\u305f\u3081\u306b\u30aa\u30fc\u30d7\u30f3\u30b9\u30da\u30fc\u30b9\u3067\u6709\u6bd2\u306a\u6fc3\u5ea6\u3092\u9054\u6210\u3059\u308b\u306e\u304c\u96e3\u3057\u3044\u305f\u3081\u3001\u7279\u306b\u6210\u529f\u3059\u308b\u3053\u3068\u306f\u3042\u308a\u307e\u305b\u3093\u3067\u3057\u305f [32] \u3002\u3053\u306e\u76ee\u7684\u3067\u306e\u4f7f\u7528\u306b\u95a2\u3059\u308b\u7814\u7a76\u306f\u30011915\u5e74\u306b\u65e9\u304f\u3082\u5b9f\u65bd\u3055\u308c\u3001\u4eca\u5e74\u306e\u7d42\u308f\u308a\u306b\u306f\u3001\u30d5\u30e9\u30f3\u30b9\u306e\u30df\u30b5\u30a4\u30eb\u756a\u53f7\u3067\u30af\u30ed\u30ed\u30db\u30eb\u30e0\u3001\u30d2\u7d20\u30c8\u30ea\u30af\u30ed\u30eb\u3001\u5869\u5316\u7269\uff08IV\uff09\u3068\u6df7\u5408\u3055\u308c\u307e\u3057\u305f\u3002 4 [33] \u3002 1916\u5e747\u6708\u306b\u30d5\u30e9\u30f3\u30b9\u306b\u3088\u308b\u6226\u95d8\u4f5c\u6226\u3067\u6700\u521d\u306b\u4f7f\u7528\u3055\u308c\u307e\u3057\u305f\u3002\u5f7c\u306e\u8ecd\u4e8b\u30de\u30fc\u30ad\u30f3\u30b0\u306f\u5f53\u6642\u3067\u3057\u305f \u68ee\u6797 \uff08\u30d5\u30e9\u30f3\u30b9\uff09\u3068CK\uff08\u30a2\u30e1\u30ea\u30ab\u3068\u30a4\u30ae\u30ea\u30b9\uff09 [34] \u3002\u73fe\u5728\u3001\u305d\u308c\u306f\u5316\u5b66\u5175\u5668\u306e\u7981\u6b62\u306b\u95a2\u3059\u308b\u7b2c3\u56de\u6761\u7d04\u306e\u30ea\u30b9\u30c8\u3067\u30ab\u30d0\u30fc\u3055\u308c\u3066\u3044\u307e\u3059 [35] \u3002 \u7a7a\u6c17\u4e2d\u306e\u6fc3\u5ea6\u306b\u5fdc\u3058\u3066HCN\u30a2\u30af\u30b7\u30e7\u30f3 [3] [5] HCN\u6fc3\u5ea6 [mg\/m\u00b3] \u30a2\u30af\u30b7\u30e7\u30f3\u306e\u5f71\u97ff 300 \u5373\u6b7b 200 10\u5206\u5f8c\u306e\u6b7b 120\u2013150 0.5-1\u6642\u9593\u5f8c\u306e\u6b7b 20\u201340 \u66dd\u9732\u6570\u6642\u9593\u5f8c\u306e\u75c7\u72b6\u304c\u60aa\u3044 \u305d\u308c\u306f\u5f37\u304f\u6709\u6bd2\u3067\u3059\uff0860 kg\u306e\u7537\u6027\u306e\u81f4\u547d\u7684\u306a\u7528\u91cf\u306f\u7d0450\u301c60 mg\u3067\u3059\uff09 [3] [4] [5] \u3002\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306f\u3001\u80ba\u3001\u76ae\u819a\u3001\u6d88\u5316\u5668\u7cfb\u3092\u4ecb\u3057\u3066\u4f53\u5185\u306b\u7c21\u5358\u306b\u5438\u53ce\u3055\u308c\u3001\u305d\u3053\u3067\u89e3\u96e2\u3057\u3001\u7d50\u679c\u3068\u3057\u3066\u751f\u3058\u308b\u30b7\u30a2\u30f3\u5316\u30a4\u30aa\u30f3\u304c CN  –  \u305d\u308c\u3089\u306f\u30a4\u30aa\u30f3\u306b\u7c21\u5358\u306b\u95a2\u9023\u4ed8\u3051\u3089\u308c\u307e\u3059 fe 3+ \u9175\u7d20\u30b7\u30c8\u30af\u30ed\u30e0\u30aa\u30ad\u30b7\u30c0\u30fc\u30bc\u7cfb\u3092\u5f37\u304f\u963b\u5bb3\u3057\u307e\u3059\u3002\u305d\u306e\u7d50\u679c\u3001\u30aa\u30ad\u30b7\u30d8\u30e2\u30b0\u30ed\u30d3\u30f3\u30aa\u30ad\u30b7\u30d8\u30e2\u30b0\u30ed\u30d3\u30f3\u306f\u7d44\u7e54\u306b\u30d6\u30ed\u30c3\u30af\u3055\u308c\u307e\u3059\uff08\u30b7\u30a2\u30f3\u5316\u7269\u4e2d\u6bd2\u306e\u9759\u8108\u8840\u306f\u3001\u901a\u5e38\u306f\u52d5\u8108\u8840\u306e\u7279\u5fb4\u3067\u3042\u308b\u660e\u308b\u3044\u8d64\u8272\u3067\u3059\uff09\u3002\u547c\u5438\u9175\u7d20\u3092\u30d6\u30ed\u30c3\u30af\u3059\u308b\u3053\u3068\u306f\u53ef\u9006\u7684\u3067\u3042\u308a\u3001\u8ca0\u50b7\u8005\u306e\u6cbb\u7642\u4e2d\u306b\u4f7f\u7528\u3055\u308c\u307e\u3059 –  CN  –  \u5f7c\u3089\u306f\u30e1\u30c8\u30e1\u30b0\u30ed\u30d3\u30f3\u306b\u6709\u610f\u306a\u89aa\u548c\u6027\u3092\u6301\u3063\u3066\u3044\u308b\u305f\u3081\u3001\u6bd2\u5316\u3055\u308c\u305f\u3082\u306e\u306b\u30a4\u30bd\u30a2\u30df\u30eb\u307e\u305f\u306f\u4e9c\u785d\u9178\u30ca\u30c8\u30ea\u30a6\u30e0\u304c\u4e0e\u3048\u3089\u308c\u3001\u30e1\u30c8\u30e1\u30b0\u30ed\u30d3\u30f3\u8840\u75c7\u3092\u5f15\u304d\u8d77\u3053\u3057\u3001\u7d30\u80de\u306b\u9178\u7d20\u3092\u8f38\u9001\u3059\u308b\u53ef\u80fd\u6027\u3092\u56de\u5fa9\u3057\u307e\u3059\u3002 [3] [4] [5] \u3002 \u2191 a b c d   \u30d3\u30a8\u30e9\u30b9\u30ad\u30fc2010\u306f\u3053\u3061\u3089 \u3001s\u3002 743\u3002  \u2191  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u3001 [\u306e\uff1a] \u6280\u8853\u767e\u79d1\u4e8b\u5178\u3002\u5316\u5b66 \u3001 w\u0142adys\u0142aw \u306e\u3002  \u30ac\u30b8\u30a7\u30d5\u30b9\u30ad\u30fc \uff08\u7de8\uff09\u3001\u7de82\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1awydawnictwo naukowo-techniczne\u30011966\u3001p\u3002141\u3001oclc 864218327  \u3002  \u2191 a b c d \u305d\u3046\u3067\u3059 f g h \u79c1  \u73fe\u4ee3\u306e\u6bd2\u7269\u5b66 \u3001 \u30a6\u30a3\u30c8\u30eb\u30c9 \u306e\u3002  se\u0144czuk \uff08\u7de8\uff09\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1a\u5dde\u306e\u533b\u7642\u51fa\u7248\u793e\u30012005\u3001pp\u3002459\u2013463  \u3002  \u2191 a b c d \u305d\u3046\u3067\u3059 f g  Tadeusz T.  Dutkiewicz  Tadeusz T. \u3001 \u6bd2\u6027\u5316\u5b66 \u3001\u7de82\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1a\u5dde\u533b\u5b66\u51fa\u7248\u793e\u30011968\u5e74\u3001174\u301c178\u30da\u30fc\u30b8  \u3002  \u2191 a b c d \u305d\u3046\u3067\u3059 f g  \u6bd2\u7269\u5b66\u306e\u57fa\u672c \u3001 \u30b8\u30e7\u30fc\u30b8 J.  Piotrowski \uff08\u7de8\uff09\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1aWydawnictwo Naukowo-Techniczne\u30012006\u3001pp\u3002208\u2013212  \u3002  \u2191 a b c  A.W. A.W.  \u30d5\u30e9\u30f3\u30b7\u30b9  A.W. A.W. \u3001 \u30b7\u30a2\u30f3\u5316\u7269\u6db2\u4f53\u306e\u6d41\u7523\u95a2\u4fc2 \u3001\u300c\u7269\u7406\u5316\u5b66\u306e\u30b8\u30e3\u30fc\u30ca\u30eb\u300d\u300163\uff085\uff09\u30011959\u3001s\u3002 753\u2013755\u3001doi\uff1a 10.1021\/J150575A033   \uff08 \u3002 \uff09\uff09 \u3002  \u2191 a b c   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 3 -286\u3002  \u2191  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3001\u51dd\u7e2e \u3001\u56fd\u969b\u5316\u5b66\u5b89\u5168\u30ab\u30fc\u30c9\u3001\u56fd\u969b\u52b4\u50cd\u7d44\u7e54 [\u30a2\u30af\u30bb\u30b92015-03-10]   \uff08 pol\u3002 \u2022 \u3002 \uff09\uff09 \u3002  \u2191 a b c d \u305d\u3046\u3067\u3059 f g h \u79c1 j k l  \u30a8\u30eb\u30f3\u30b9\u30c8 \u3068\u3002  \u30b2\u30a4\u30eb  \u30a8\u30eb\u30f3\u30b9\u30c8 \u3068\u3002 \u79c1\u306f\u30a4\u30cb \u3001 \u30b7\u30a2\u30ce\u5316\u5408\u7269\u3001\u7121\u6a5f \u3001 [\u306e\uff1a] \u30a6\u30eb\u30de\u30f3\u306e\u7523\u696d\u5316\u5b66\u767e\u79d1\u4e8b\u5178 \u3001\u30ef\u30a4\u30f3\u30cf\u30a4\u30e0\uff1a\u30ef\u30a4\u30ea\u30fc-VCH\u30012000\u3001doi\uff1a 10,1002\/14356007.A08_159   \uff08 \u3002 \uff09\uff09 \u3002  \u2191   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 6 -62\u3002  \u2191   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 15 -18\u3002  \u2191   2009\u5e74\u306e\u3088\u3046\u306b\u2193 \u3001s\u3002 9 -56\u3002  \u2191  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 …\uff05  \uff08 \u3002 \uff09\uff09 \u6b27\u5dde\u5316\u5b66\u6a5f\u95a2\u306e\u5206\u985e\u3068\u30de\u30fc\u30ad\u30f3\u30b0\u306e\u30ea\u30b9\u30c8\u3002 [\u30a2\u30af\u30bb\u30b92015-03-10]\u3002  \u2191 a b  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20 \u3001[W\uff1a] Chemidplus [\u30aa\u30f3\u30e9\u30a4\u30f3]\u3001\u7c73\u56fd\u56fd\u7acb\u533b\u5b66\u56f3\u66f8\u9928 [\u30a2\u30af\u30bb\u30b92015-03-10]   \uff08 \u3002 \uff09\uff09 \u3002  \u2191  \u5316\u5b66\u30c7\u30fc\u30bf\u30b7\u30fc\u30c8\uff1a\u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3001\u7121\u6c34\u3001\u5b89\u5b9a\u5316\uff08\u5438\u53ce\uff09 \u3001\u30ab\u30e1\u30aa\u5316\u5b66\u7269\u8cea\u3001\u56fd\u7acb\u6d77\u6d0b\u304a\u3088\u3073\u5927\u6c17\u5c40 [\u30a2\u30af\u30bb\u30b92015-03-10]   \uff08 \u3002 \uff09\uff09 \u3002  \u2191 a b  \u30a2\u30ec\u30af\u30b5\u30f3\u30c0\u30fc A.  \u30de\u30b3\u30fc\u30ec\u30fc  \u30a2\u30ec\u30af\u30b5\u30f3\u30c0\u30fc A. \u3001 \u4e00\u822c\u7684\u306a\u4f7f\u7528\u306e\u305f\u3081\u306e\u533b\u5b66\u8f9e\u66f8 \u3001J\u3002Ebner\u30011841\u3001pp\u3002115\u2013116 [\u30a2\u30af\u30bb\u30b92020-05-07]   \uff08 niem\u3002 \uff09\uff09 \u3002  \u2191 a b c d   Patnaik 2003\u2193 \u3001s\u3002 362\u3002  \u2191 a b   Patnaik 2003\u2193 \u3001s\u3002 363\u3002  \u2191 a b   \u30b0\u30ea\u30fc\u30f3\u30a6\u30c3\u30c9I\u30a2\u30fc\u30f3\u30b7\u30e7\u30fc1997\u2193 \u3001s\u3002 321\u3002  \u2191  Sanggyu S.  \u30ea\u30fc  Sanggyu S. \u3001 \u30e1\u30bf\u30f3\u3068\u305d\u306e\u8a98\u5c0e\u4f53 \u3001t\u3002 70\u3001\u305d\u3046\u306a\u308b\u3067\u3057\u3087\u3046 \u5316\u5b66\u7523\u696d \u3001CRC Press\u30011996\u3001s\u3002 267\u3001ISBN 978-0-8247-9754-6  \u3002  \u2191  L. L.  \u30a2\u30f3\u30c9\u30ed\u30c3\u30bd\u30a6  L. L. \u3001 \u6d41\u308c\u308b\u30ac\u30b9\u3068\u30a2\u30f3\u30e2\u30cb\u30a2\u9178\u5316\u306b\u304a\u3051\u308b\u6025\u901f\u306b\u5b9f\u884c\u3055\u308c\u308b\u89e6\u5a92\u30d7\u30ed\u30bb\u30b9\u306b\u3064\u3044\u3066\uff08V\uff09 \u3001\u300c\u30c9\u30a4\u30c4\u5316\u5b66\u5354\u4f1a\u306e\u5831\u544a\u300d\u300160\uff088\uff09\u30011927\u3001p\u30022005\u20132018\u3001doi\uff1a 10.1002\/cber.19270600857   \uff08 niem\u3002 \uff09\uff09 \u3002  \u2191  L. L.  \u30a2\u30f3\u30c9\u30ed\u30c3\u30bd\u30a6  L. L. \u3001 \u30a2\u30f3\u30e2\u30cb\u30a2\u30e1\u30bf\u30f3\u6df7\u5408\u7269\u306e\u70ad\u5316\u91cd\u9178\u3078\u306e\u89e6\u5a92\u9178\u5316\u306b\u3064\u3044\u3066 \u3001\u300cApplied Chemistry\u300d\u300148\uff0837\uff09\u30011935\u3001p\u3002593\u2013595\u3001doi\uff1a 10.1002\/ange.19350483702   \uff08 niem\u3002 \uff09\uff09 \u3002  \u2191  \u30bc\u30f3 \u3068\u3002  \u3068  \u30bc\u30f3 \u3068\u3002 \u3001 \u30d5\u30e9\u30f3\u30b7\u30b9\u30b3 F.  \u30bc\u30e9  \u30d5\u30e9\u30f3\u30b7\u30b9\u30b3 F. \u3001 \u91d1\u5c5e\u306b\u3088\u308b\u4e0d\u5747\u4e00\u6027\u89e6\u5a92 \u3001 [\u306e\uff1a] \u7121\u6a5f\u5316\u5b66\u767e\u79d1\u4e8b\u5178 \u3001 R.\u30d6\u30eb\u30fc\u30b9 R.B.  \u738b \uff08\u8d64\uff09\u3001WYD\u3002 2\u3001t\u3002 I\u3001Chichester\uff1aWiley\u30012005\u3001s\u3002 2\u3001ISBN 978-0-470-86078-6  \u3002  \u2191  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u3092\u5f97\u308b\u305f\u3081\u306e\u30a2\u30f3\u30c9\u30e9\u30b7\u306e\u65b9\u6cd5 \u3001 [\u306e\uff1a] \u6280\u8853\u767e\u79d1\u4e8b\u5178\u3002\u5316\u5b66 \u3001 w\u0142adys\u0142aw \u306e\u3002  \u30ac\u30b8\u30a7\u30d5\u30b9\u30ad\u30fc \uff08\u7de8\uff09\u3001\u7de82\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1awydawnictwo naukowo-techniczne\u30011966\u3001p\u300237\u3001oclc 864218327  \u3002  \u2191  degussa D.  \u3067  degussa D. \u3001 \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306e\u751f\u7523\u65b9\u6cd5 \u3001\u7279\u8a31 PL 124280 \u30011985\u5e74\u306e15\u8ed2\u306e\u5bb6 [\u30a2\u30af\u30bb\u30b92020-05-07]  \u3002  \u2191  \u30b7\u30a2\u30f3\u5316\u6c34\u7d20\u306e\u533b\u7642\u7ba1\u7406\u30ac\u30a4\u30c9\u30e9\u30a4\u30f3 \u3001\u6bd2\u6027\u7269\u8cea\u304a\u3088\u3073\u75be\u60a3\u30ec\u30b8\u30b9\u30c8\u30ea\u306e\u4ee3\u7406\u5e97\u30013 Marca 2011 [\u30a2\u30af\u30bb\u30b92011-04-10] [\u30a2\u30fc\u30ab\u30a4\u30d6 \u4f4f\u6240 2007-07-08]   \uff08 \u3002 \uff09\uff09 \u3002  \u2191 a b  \u30d9\u30eb\u30f3\u30cf\u30eb\u30c8 B.  \u30ce\u30a4\u30de\u30f3  \u30d9\u30eb\u30f3\u30cf\u30eb\u30c8 B. \u3001 \u30ae\u30e5\u30f3\u30b5\u30fc G.  \u9003\u3059  \u30ae\u30e5\u30f3\u30b5\u30fc G. \u3001 \u30b7\u30a2\u30f3\u306e\u6c34\u7d20\u306e\u89e6\u5a92\u9178\u5316 \u3001\u300cJournal of Electrochemistry and Applied Physical Chemistry\u300d\u300135\uff0810\uff09\u30011929\u3001p\u3002751\u2013765\u3001doi\uff1a 10.1002\/BBPC.19290351002   \uff08 niem\u3002 \uff09\uff09 \u3002  \u2191   Patnaik 2003\u2193 \u3001s\u3002 366\u3002  \u2191 a b  \u30c8\u30df\u30b9\u30e9\u30d5 T.  \u30d5\u30ea\u30b7\u30c3\u30af  \u30c8\u30df\u30b9\u30e9\u30d5 T. \u3001 \u30ec\u30ca\u30fc\u30c9 L.  MacGillivray  \u30ec\u30ca\u30fc\u30c9 L. \u3001 \u70ad\u7d20\uff1a\u7121\u6a5f\u5316\u5b66 \u3001 [\u306e\uff1a] \u7121\u6a5f\u5316\u5b66\u767e\u79d1\u4e8b\u5178 \u3001 R.\u30d6\u30eb\u30fc\u30b9 R.B.  \u738b \uff08\u8d64\uff09\u3001WYD\u3002 2\u3001t\u3002 I\u3001Chichester\uff1aWiley\u30012005\u3001s\u3002 7\u3001ISBN 978-0-470-86078-6  \u3002  \u2191 a b c   Patnaik 2003\u2193 \u3001s\u3002 364\u3002  \u2191  \u5316\u5b66\u5175\u5668\u3068\u5316\u5b66\u5175\u5668\u306b\u95a2\u3059\u308b1000\u8a9e \u3001 zygfryd \u3068\u3002  witkiewicz \uff08\u7de8\uff09\u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1aWydawnictwo\u56fd\u9632\u7701\u30011987\u3001p\u300262\u3001ISBN 83-11-07396-1 \u3001OCLC 19360683  \u3002  \u2191   Konopski 2009\u2193 \u3001s\u3002 52\u3002  \u2191   Konopski 2009\u2193 \u3001s\u3002 41\u3002  \u2191   Konopski 2009\u2193 \u3001s\u3002 50\u3002  \u2191  \u30b9\u30b1\u30b8\u30e5\u30fc\u30eb3\u5316\u5b66\u5175\u5668\u6761\u7d04 \u3001\u5316\u5b66\u5175\u5668\u7981\u6b62\u306e\u7d44\u7e54 [\u30a2\u30af\u30bb\u30b92015-04-06]   \uff08 \u3002 \uff09\uff09 \u3002  \u30a2\u30c0\u30e0 A.  \u30d3\u30a8\u30e9\u30b9\u30ad\u30fc  \u30a2\u30c0\u30e0 A. \u3001 \u7121\u6a5f\u5316\u5b66\u306e\u57fa\u790e \u3001\u7de86\u3001Vol\u30022\u3001Warsaw\uff1aPWN Scientific Publishing House\u30012010\u3001ISBN 978-83-01-16282-5  \u3002 \u79c1\u306f\u301c\u306b\u306a\u308b L.  \u30b3\u30ce\u30d7\u30ad\u30fc  \u79c1\u306f\u301c\u306b\u306a\u308b L. \u3001 \u5316\u5b66\u5175\u5668\u306e\u6b74\u53f2 \u3001\u30ef\u30eb\u30b7\u30e3\u30ef\uff1a2009\u5e74\u3001\u30d9\u30ed\u30fc\u30ca\u3001ISBN 978-83-11-11643-6  \u3002 \u30c7\u30d3\u30c3\u30c9R. D.R.  \u82e6\u3057\u3080  \u30c7\u30d3\u30c3\u30c9R. D.R. \uff08\u8d64\u3002\uff09\u3001 CRC\u5316\u5b66\u3068\u7269\u7406\u5b66\u30cf\u30f3\u30c9\u30d6\u30c3\u30af \u3001WYD\u3002 90\u3001\u30dc\u30ab\u30e9\u30c8\u30f3\uff1aCRC Press\u30012009\u3001ISBN 978-1-4200-9084-0   \uff08 \u3002 \uff09\uff09 \u3002 \u30d7\u30e9\u30c7\u30a3\u30e7\u30c3\u30c8 P.  \u30d1\u30c8\u30ca\u30a4\u30af  \u30d7\u30e9\u30c7\u30a3\u30e7\u30c3\u30c8 P. \u3001 \u7121\u6a5f\u5316\u5b66\u7269\u8cea\u306e\u30cf\u30f3\u30c9\u30d6\u30c3\u30af \u3001\u30ed\u30f3\u30c9\u30f3\uff1aMcGraw-Hill\u30012003\u3001ISBN 0-07-049439-8   \uff08 \u3002 \uff09\uff09 \u3002      (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/all2jp\/wiki47\/archives\/9018#breadcrumbitem","name":"\u30b7\u30a2\u30f3\u5316\u6c34\u7d20 – \u30a6\u30a3\u30ad\u30da\u30c7\u30a3\u30a2\u3001\u7121\u6599\u200b\u200b\u767e\u79d1\u4e8b\u5178"}}]}]