[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/en\/wiki19\/carbonate-chloride-wikipedia\/#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/en\/wiki19\/carbonate-chloride-wikipedia\/","headline":"Carbonate chloride – Wikipedia","name":"Carbonate chloride – Wikipedia","description":"From Wikipedia, the free encyclopedia Class of chemical compounds The carbonate chlorides are double salts containing both carbonate and chloride","datePublished":"2022-05-25","dateModified":"2022-05-25","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/en\/wiki19\/author\/lordneo\/#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/en\/wiki19\/author\/lordneo\/","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/en.wikipedia.org\/wiki\/Special:CentralAutoLogin\/start?type=1x1","url":"https:\/\/en.wikipedia.org\/wiki\/Special:CentralAutoLogin\/start?type=1x1","height":"1","width":"1"},"url":"https:\/\/wiki.edu.vn\/en\/wiki19\/carbonate-chloride-wikipedia\/","about":["Wiki"],"wordCount":9237,"articleBody":"From Wikipedia, the free encyclopediaClass of chemical compoundsThe carbonate chlorides are double salts containing both carbonate and chloride anions. Quite a few minerals are known. Several artificial compounds have been made. Some complexes have both carbonate and chloride ligands. They are part of the family of halocarbonates. In turn these halocarbonates are a part of mixed anion materials.The carbonate chlorides do not have a bond from chlorine to carbon, however “chlorocarbonate” has also been used to refer to the chloroformates which contain the group ClC(O)O-.Table of ContentsFormation[edit]Natural[edit]Minerals[edit]Artificial[edit]Complexes[edit]References[edit]Formation[edit]Natural[edit]Scapolite is produced in nature by metasomatism, where hot high pressure water solutions of carbon dioxide and sodium chloride modify plagioclase.[1]Chloroartinite is found in Sorel cements exposed to air.[2]Minerals[edit]In 2016 27 chloride containing carbonate minerals were known.[3]nameformulacrystal systemspace groupunit celldensityOptics refractive indexRaman spectrumcommentsreferenceAlexkhomyakoviteK6(Ca2Na)(CO3)5Cl\u22196H2OhexagonalP63\/mcma=9.2691, c=15.8419, V=1178.72 Z = 22.25uniaxial (\u2013), \u03c9=1.543, \u03b5=1.476[4]AshburtoniteHPb4Cu4(Si4O12)(HCO3)4(OH)4Cl[3]Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)hexagonalP63a=12.695 c=5.325 V=743.2 Z=12.48uniaxial (+), \u03c9=1.523, \u03b5=1.525[5]BarstowitePb4(CO3)Cl6.H2OChlorartiniteMg2(CO3)Cl(OH).3H2OChlormagaluminite(Mg,Fe2+)4Al2(OH)12(Cl, 0.5 CO3)2\u00b72H2O6\/mmm1.98-2.09\u03b5=1.560 \u03c9=1.540[6]Davynecan substitute CO3 for SO4[7]Decrespignyite-(Y)Y4Cu(CO3)4Cl(OH)5\u00b72H2OV4 bending 694, 718 and 746; V2 bending 791, 815, 837 and 849;v3 antisymmetric stretching 1391, 1414, 1489, 1547; also OH stretching[8]light blue[9]DeferniteCa3CO3(OH,Cl)4.H2OHanksiteNa22K(SO4)9(CO3)2ClhexagonalP63\/ma = 10.46 \u00c5c = 21.19 \u00c5; Z = 2iowaiteMg6Fe2(Cl,(CO3)0.5)(OH)16\u00b74H2O[10]KampfiteBa12(Si11Al5)O31(CO3)8Cl5monoclinicCca = 31.2329, b=5.2398, c=9.0966\u03b2 = 106.933\u00b0uniaxial (\u2013), n\u03c9 = 1.642 n\u03b5 = 1.594[11]MarialiteNa4(AlSi3O8)3(Cl2,CO3,SO4)Mineevite-(Y)Na25BaY2(CO3)11(HCO3)4(SO4)2F2Cl[12]NorthupiteNa3Mg(CO3)2CloctahedralFd3Z=161.514v4 bending 714; v3 antisymmetric stretching 1554[8][13][14]PhosgenitePb2CO3Cl2tetragonala=8.15 c=8.87[13]Reederite-(Y)Na15Y2(CO3)9(SO3F)Cl[12]Sakhaite (with Harkerite)Ca48Mg16Al(SiO3OH)4(CO3)16(BO3)28\u00b7(H2O)3(HCl)3or Ca12Mg4(BO3)7(CO3)4Cl(OH)2\u00b7H2O[3]ScapoliteCa3Na5[Al8Si16O48]Cl(CO3)P42\/na=12.07899 c=7.583467 V=1106.443[15]TatarskiteCa6Mg2(SO4)2(CO3)2(OH)4Cl4\u20227H2OorthorhombicBiaxial (-) n\u03b1 = 1.567 n\u03b2 = 1.654 n\u03b3 = 1.722[16]TunisiteNaCa2Al4(CO3)4Cl(OH)8tetragonalP4\/nmma=11.198 c=6.5637 Z=2Vasilyevite(Hg2)10O6I3Br2Cl(CO3)P1 overbara 9.344, b 10.653, c 18.265, \u03b1=93.262 \u03b2=90.548 \u03b3=115.422\u00b0 V=1638.3 Z=29.57Artificial[edit]nameformulacrystal systemspace groupunit cell in \u00c5densitycommentreferenceK5Na2Cu24(CO3)16Cl3(OH)20\u202212H2OcubicF23a=15.463 V=3697.5 Z=23.044dark blue[17]Y8O(OH)15(CO3)3Cl1197.88hexagonalP63a=9.5089 c=14.6730 Z=2 V=1148.973.462[18]Lu8O(OH)15(CO3)3Cl1886.32hexagonalP63a=9.354 c=14.415 V=1092.3 Z=25.689colourless[19]Y3(OH)6(CO3)ClcubicIm3ma=12.66 V=2032 Z=83.035colourless[20]Dy3(OH)6(CO3)ClcubicIm3a=12.4754 V=1941.6 Z=84.687colourless[20]Er3(OH)6(CO3)ClcubicIm3ma=12.4127 V=1912.5 Z=84.857pink[20]K{Mg(H2O)6}2[Ru2(CO3)4Cl2]\u00b74H2O889.06monoclinicP21\/ca=11.6399 b=11.7048 c=11.8493 \u03b2=119.060 V=1411.6 Z=22.092red-brown[21]K2[{Mg(H2O)4}2Ru2(CO3)4(H2O)Cl]Cl2\u00b72H2O880.58orthorhombicFmm2a=14.392 b=15.699 c=10.741 V=2426.8 Z=42.391dark brown[21]trisodium cobalt dicarbonate chlorideNa3Co(CO3)2ClcubicFd3a=13.9959 Z=162.75spin-frustrated antiferromagnetic[3][22]trisodium manganese dicarbonate chlorideNa3Mn(CO3)2Clcubica=14.163brown[23]di-magnesium hexahydrate trihydrogencarbonate chlorideMg2(H2O)6(HCO3)3ClR3ca=8.22215 c=39.5044 V=2312.85 Z=61.61decompose 125\u00a0\u00b0C[2]tripotassium tricalcium selenite tricarbonate chlorideK3Ca3(SeO3)(CO3)3Cl579.97hexagonalP63a=10.543 c=7.060 V=706.0 Z=22.991[24]LiBa9[Si10O25]Cl7(CO3)Z=23.85layer silicate[25][26]Ba3Cl4CO3orthorhombicPnmaa=8.407, b=9.589, c=12.483 Z=4[27]Complexes[edit]The “lanthaballs” are lanthanoid atom clusters held together by carbonate and other ligands. They can form chlorides. Examples are [La13(ccnm)6(CO3)14(H2O)6(phen)18] Cl3(CO3)\u00b725H2O where ccnm is carbamoylcyanonitrosomethanide and phen is 1,10-phenanthroline. Praseodymium (Pr) or cerium (Ce) can substitute for lanthanum (La).[28] Other lanthanide cluster compounds include\u00a0:(H3O)6[Dy76O10(OH)138(OAc)20(L)44(H2O)34]\u20222CO3\u20224Cl2\u2022L\u20222OAc (nicknamed Dy76) and (H3O)6[Dy48O6(OH)84(OAc)4(L)15(hmp)18(H2O)20]\u2022CO3\u202214Cl\u20222H2O (termed Dy48-T) with OAc=acetate, and L=3-furancarboxylate and Hhmp=2,2-bis(hydroxymethyl)propionic acid.[29]Platinum can form complexes with carbonate and chloride ligands, in addition to an amino acid. Examples include the platinum compound [Pt(gluH)Cl(CO3)]2.2H2O gluH=glutamic acid, and Na[Pt(gln)Cl2(CO3)].H2O gln=glutamine.[30]Rhodium complexes include Rh2(bipy)2(CO3)2Cl (bipy=bipyridine)[31]References[edit]^ Harlov, D. E.; Budzyn, B. 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S2CID\u00a0155089115.^ Shatnawi, Razan Ahmad Mahmoud (November 2013). Synthesis and Characterization of Some Amino Acid Complexes with Metal Ions. Yarmouk University (Article).^ Davidson, G.; Ebsworth, E. A. V. (2007). Spectroscopic Properties of Inorganic and Organometallic Compounds. Royal Society of Chemistry. p.\u00a0294. ISBN\u00a0978-1-84755-506-9.  "},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/en\/wiki19\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/en\/wiki19\/carbonate-chloride-wikipedia\/#breadcrumbitem","name":"Carbonate chloride – Wikipedia"}}]}]