[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/9224#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/9224","headline":"\u7d30\u898b\u5f70 – Wikipedia","name":"\u7d30\u898b\u5f70 – Wikipedia","description":"\u7d30\u898b \u5f70\uff08\u307b\u305d\u307f \u3042\u304d\u3089\u3001\u662d\u548c18\u5e74\uff081943\u5e74\uff093\u6708 – \u5e73\u621030\u5e74\uff082018\u5e74\uff099\u67089\u65e5\uff09\u306f\u65e5\u672c\u306e\u5316\u5b66\u8005\uff08\u6709\u6a5f\u5316\u5b66\u30fb\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u30fb\u6709\u6a5f\u5408\u6210\u5316\u5b66\uff09\u3002\u7b51\u6ce2\u5927\u5b66\u540d\u8a89\u6559\u6388\u3002 \u5b66\u7fd2\u9662\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u4eac\u90fd\u85ac\u79d1\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u4e2d\u592e\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u65e5\u672c\u5316\u5b66\u4f1a\u30d5\u30a7\u30ed\u30fc\u3002 \u7d30\u898b\u30fb\u6afb\u4e95\u53cd\u5fdc (the Hosomi-Sakurai reaction)\u306e\u767a\u898b\u8005\u3068\u3057\u3066\u8457\u540d\u3002\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u3001\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5b66\u306b\u95a2\u3059\u308b\u548c\u6d0b\u8457\u66f8\u3084\u8ad6\u6587\u591a\u6570\uff08\u7d30\u898b\u5f70\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u53c2\u7167\u7d30\u898b\u5f70 HP\uff09\u3002\u5927\u962a\u5e9c\u5439\u7530\u5e02\u5343\u91cc\u5c71\u51fa\u8eab\u3002\u6669\u5e74\u306f\u4eac\u90fd\u5e02\u4e2d\u4eac\u533a\u306b\u5c45\u4f4f\u3002 \u5439\u7530\u5e02\u7acb\u5343\u91cc\u7b2c\u4e8c\u5c0f\u5b66\u6821\u3001\u5439\u7530\u5e02\u7acb\u7b2c\u4e00\u4e2d\u5b66\u6821\u3001\u5927\u962a\u5e9c\u7acb\u8328\u6728\u9ad8\u7b49\u5b66\u6821\u3001 \u4eac\u90fd\u5927\u5b66\u5de5\u5b66\u90e8\u3001\u540c\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u535a\u58eb\u8ab2\u7a0b\u3001\u6771\u5317\u5927\u5b66\u7406\u5b66\u90e8\u5316\u5b66\u79d1\u52a9\u6559\u6388\uff08\u3053\u306e\u9593 \u30ab\u30ea\u30d5\u30a9\u30eb\u30cb\u30a2\u5927\u5b66\u30b5\u30f3\u30c7\u30a3\u30a8\u30b4\u6821\u535a\u58eb\u7814\u7a76\u54e1\uff09\u3092\u7d4c\u3066\u3001 \u9577\u5d0e\u5927\u5b66\u85ac\u5b66\u90e8\u6559\u6388\u3001 \u7b51\u6ce2\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u3001\u7b51\u6ce2\u5927\u5b66\u5316\u5b66\u7cfb\u9577\u30fb\u8a55\u8b70\u54e1\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u5316\u5b66\u7814\u7a76\u79d1\u9577\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u9577\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u6570\u7406\u7269\u8cea\u79d1\u5b66\u7814\u7a76\u79d1\u9577\u30fb\u8a55\u8b70\u54e1\uff08\u3053\u306e\u9593\u3001\u5206\u6790\u30bb\u30f3\u30bf\u30fc\u9577\u3001\u30a2\u30a4\u30bd\u30c8\u30fc\u30d7\u30bb\u30f3\u30bf\u30fc\u9577\u3001\u30d9\u30f3\u30c1\u30e3\u30fc\u30d3\u30b8\u30cd\u30b9\u30e9\u30dc\u30e9\u30c8\u30ea\u30fc\u9577\u7b49\u3092\u6b74\u4efb\uff09\u3001 \u5927\u5b66\u8a55\u4fa1\u30fb\u5b66\u4f4d\u6388\u4e0e\u6a5f\u69cb\u6559\u6388\u3001 \u5b66\u7fd2\u9662\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001 \u4eac\u90fd\u85ac\u79d1\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001\u73fe\u5728 \u4e2d\u592e\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001","datePublished":"2018-01-31","dateModified":"2018-01-31","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/8\/8a\/OOjs_UI_icon_edit-ltr-progressive.svg\/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/8\/8a\/OOjs_UI_icon_edit-ltr-progressive.svg\/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png","height":"10","width":"10"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/9224","about":["Wiki"],"wordCount":456,"articleBody":"\u7d30\u898b \u5f70\uff08\u307b\u305d\u307f \u3042\u304d\u3089\u3001\u662d\u548c18\u5e74\uff081943\u5e74\uff093\u6708 – \u5e73\u621030\u5e74\uff082018\u5e74\uff099\u67089\u65e5\uff09\u306f\u65e5\u672c\u306e\u5316\u5b66\u8005\uff08\u6709\u6a5f\u5316\u5b66\u30fb\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u30fb\u6709\u6a5f\u5408\u6210\u5316\u5b66\uff09\u3002\u7b51\u6ce2\u5927\u5b66\u540d\u8a89\u6559\u6388\u3002 \u5b66\u7fd2\u9662\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u4eac\u90fd\u85ac\u79d1\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u4e2d\u592e\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3002\u65e5\u672c\u5316\u5b66\u4f1a\u30d5\u30a7\u30ed\u30fc\u3002  \u7d30\u898b\u30fb\u6afb\u4e95\u53cd\u5fdc (the Hosomi-Sakurai reaction)\u306e\u767a\u898b\u8005\u3068\u3057\u3066\u8457\u540d\u3002\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u3001\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5b66\u306b\u95a2\u3059\u308b\u548c\u6d0b\u8457\u66f8\u3084\u8ad6\u6587\u591a\u6570\uff08\u7d30\u898b\u5f70\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u53c2\u7167\u7d30\u898b\u5f70 HP\uff09\u3002\u5927\u962a\u5e9c\u5439\u7530\u5e02\u5343\u91cc\u5c71\u51fa\u8eab\u3002\u6669\u5e74\u306f\u4eac\u90fd\u5e02\u4e2d\u4eac\u533a\u306b\u5c45\u4f4f\u3002\u5439\u7530\u5e02\u7acb\u5343\u91cc\u7b2c\u4e8c\u5c0f\u5b66\u6821\u3001\u5439\u7530\u5e02\u7acb\u7b2c\u4e00\u4e2d\u5b66\u6821\u3001\u5927\u962a\u5e9c\u7acb\u8328\u6728\u9ad8\u7b49\u5b66\u6821\u3001 \u4eac\u90fd\u5927\u5b66\u5de5\u5b66\u90e8\u3001\u540c\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u535a\u58eb\u8ab2\u7a0b\u3001\u6771\u5317\u5927\u5b66\u7406\u5b66\u90e8\u5316\u5b66\u79d1\u52a9\u6559\u6388\uff08\u3053\u306e\u9593 \u30ab\u30ea\u30d5\u30a9\u30eb\u30cb\u30a2\u5927\u5b66\u30b5\u30f3\u30c7\u30a3\u30a8\u30b4\u6821\u535a\u58eb\u7814\u7a76\u54e1\uff09\u3092\u7d4c\u3066\u3001 \u9577\u5d0e\u5927\u5b66\u85ac\u5b66\u90e8\u6559\u6388\u3001 \u7b51\u6ce2\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u3001\u7b51\u6ce2\u5927\u5b66\u5316\u5b66\u7cfb\u9577\u30fb\u8a55\u8b70\u54e1\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u5316\u5b66\u7814\u7a76\u79d1\u9577\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u7406\u5de5\u5b66\u7814\u7a76\u79d1\u9577\u3001\u7b51\u6ce2\u5927\u5b66\u5927\u5b66\u9662\u6570\u7406\u7269\u8cea\u79d1\u5b66\u7814\u7a76\u79d1\u9577\u30fb\u8a55\u8b70\u54e1\uff08\u3053\u306e\u9593\u3001\u5206\u6790\u30bb\u30f3\u30bf\u30fc\u9577\u3001\u30a2\u30a4\u30bd\u30c8\u30fc\u30d7\u30bb\u30f3\u30bf\u30fc\u9577\u3001\u30d9\u30f3\u30c1\u30e3\u30fc\u30d3\u30b8\u30cd\u30b9\u30e9\u30dc\u30e9\u30c8\u30ea\u30fc\u9577\u7b49\u3092\u6b74\u4efb\uff09\u3001 \u5927\u5b66\u8a55\u4fa1\u30fb\u5b66\u4f4d\u6388\u4e0e\u6a5f\u69cb\u6559\u6388\u3001 \u5b66\u7fd2\u9662\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001 \u4eac\u90fd\u85ac\u79d1\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001\u73fe\u5728 \u4e2d\u592e\u5927\u5b66\u5ba2\u54e1\u6559\u6388\u3001 \u4e5d\u5dde\u5927\u5b66\u5148\u5c0e\u7269\u8cea\u5316\u5b66\u7814\u7a76\u6240\u5b66\u8853\u9867\u554f\u3001\u7b51\u6ce2\u5927\u5b66\u540d\u8a89\u6559\u6388\u3001\u65e5\u672c\u5316\u5b66\u4f1a\u30d5\u30a7\u30ed\u30fc\u3002\u3053\u306e\u9593\u3001\u65e5\u672c\u5316\u5b66\u4f1a\u7406\u4e8b\u3001\u8fd1\u757f\u5316\u5b66\u5354\u4f1a\u7406\u4e8b\u3001\u30b1\u30a4\u7d20\u5316\u5b66\u5354\u4f1a\u7406\u4e8b\u3001\u9867\u554f\u4ed6\u95a2\u9023\u5b66\u4f1a\u5f79\u54e1\u4ed6\u3001\u8af8\u5b66\u4f1a\u5f79\u54e1\u306a\u3069\u3092\u6b74\u4efb\u3002  \u5c02\u9580\u306f\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u3001\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5b66\u3001\u6709\u6a5f\u85ac\u5316\u5b66\u3092\u4e2d\u5fc3\u3068\u3059\u308b\u6709\u6a5f\u5316\u5b66\u3002\u7279\u306b\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5408\u7269\u305d\u306e\u4ed6\u6709\u6a5f\u91d1\u5c5e\u3092\u7528\u3044\u308b\u6709\u6a5f\u5408\u6210\u3067\u5148\u99c6\u7684\u7814\u7a76\u6210\u679c\u3092\u591a\u6570\uff08\u539f\u8457\u8ad6\u6587260\u7de8\u3001\u7dcf\u8aac50\u7de8\u3001\u8457\u66f820\u7de8\u5404\u3005\u4ee5\u4e0a\uff09\u3002\u6709\u6a5f\u30b1\u30a4\u7d20\u30e9\u30b8\u30ab\u30eb\u306e\u69cb\u9020\u3068\u53cd\u5fdc\u6027\u306b\u95a2\u3059\u308b\u7814\u7a76\u3092\u624b\u59cb\u3081\u306b\u3001\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5408\u7269\u3092\u7528\u3044\u308b\u7a2e\u3005\u306e\u65b0\u53cd\u5fdc\u3001\u7279\u306b\u30a2\u30ea\u30eb\u30b7\u30e9\u30f3\u304c\u03c3-\u03c0\u5171\u5f79\u306b\u3088\u308a\u9ad8\u3044HOMO\u3092\u793a\u3059\u3053\u3068\u3092\u5149\u96fb\u5b50\u30b9\u30da\u30af\u30c8\u30eb\u306e\u7814\u7a76\u306b\u3088\u308a\u5b9f\u8a3c\u3057\u3001\u3053\u306e\u73fe\u8c61\u3092\u6709\u6a5f\u5408\u6210\u306b\u5fdc\u7528\u5c55\u958b\u3057\u3066\u65b0\u3057\u3044\u70ad\u7d20\u2212\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u53cd\u5fdc\u306e\u767a\u898b\u306b\u7e4b\u3052\u305f\u3002\u7d30\u898b\u304c\u767a\u898b\u3057\u305f\u30a2\u30ea\u30eb\u30b7\u30e9\u30f3\u3092\u6c42\u6838\u7a2e\u3068\u3057\u3066\u7528\u3044\u308b\u5408\u6210\u53cd\u5fdc\u306f\u4eba\u540d\u53cd\u5fdc\u300c\u7d30\u898b\u30fb\u6afb\u4e95\u53cd\u5fdc (the Hosomi-Sakurai reaction)\u300d\u3068\u3057\u3066\u56fd\u969b\u7684\u306b\u6709\u540d\u3067\u3042\u308b\u3002\u6709\u6a5f\u30b1\u30a4\u7d20\u5316\u5408\u7269\u304b\u3089\u6709\u6a5f\u9285\u8a66\u85ac\u3078\u306e\u4ea4\u63db\u53cd\u5fdc\u3001”Tailor made” \u306e1,3-\u53cc\u6975\u5b50\u53cd\u5fdc\u5264\u306e\u958b\u767a\u3001\u6709\u6a5f\u30b1\u30a4\u7d20\u30a2\u30fc\u30c8\u5316\u5408\u7269\u306e\u5275\u6210\u3068\u6709\u6a5f\u5408\u6210\u3078\u306e\u5fdc\u7528\u3001\u30e9\u30b8\u30ab\u30eb\u53cd\u5fdc\u3092\u7528\u3044\u308b\u6709\u6a5f\u5408\u6210\u306a\u3069\u3001\u6709\u6a5f\u91d1\u5c5e\u3092\u7528\u3044\u308b\u65b0\u53cd\u5fdc\u306e\u958b\u767a\u3092\u9032\u3081\u3001\u4e16\u754c\u7684\u306b\u9ad8\u3044\u8a55\u4fa1\u3092\u53d7\u3051\u3066\u3044\u308b\u3002\u307e\u305f\u3001\u6709\u6a5f\u30e9\u30f3\u30bf\u30ce\u30a4\u30c9\u304a\u3088\u3073\u6709\u6a5f\u9077\u79fb\u91d1\u5c5e\u30a2\u30fc\u30c8\u5316\u5408\u7269\u306e\u65b0\u898f\u751f\u6210\u3068\u5408\u6210\u5316\u5b66\u3078\u306e\u5fdc\u7528\u306b\u95a2\u3057\u3066\u3082\u3001\u5927\u304d\u306a\u696d\u7e3e\u3092\u6319\u3052\u305f\u3002\u3055\u3089\u306b\u3001\u8ee2\u4f4d\u3001\u82b3\u9999\u6838\u7f6e\u63db\u3001\u74b0\u5316\u3001\u4e8c\u91cf\u5316\u3001\u4e0d\u5747\u5316\u3001\u4ed8\u52a0\u53cd\u5fdc\u306a\u3069\uff0c\u30b7\u30ea\u30eb\u30e9\u30b8\u30ab\u30eb\u306e\u95a2\u4e0e\u3059\u308b\u65b0\u898f\u7d20\u53cd\u5fdc\u3092\u6570\u591a\u304f\u767a\u898b\u3057\u3001\u305d\u306e\u5316\u5b66\u3092\u4f53\u7cfb\u5316\u3057\u305f\u3002\u65e5\u672c\u5316\u5b66\u4f1a\u9032\u6b69\u8cde\u3001\u4e95\u4e0a\u5b66\u8853\u8cde\u3001\u6709\u6a5f\u5408\u6210\u5316\u5b66\u5354\u4f1a\u8cde\u3001\u65e5\u672c\u5316\u5b66\u4f1a\u8cde\u3001\u30b1\u30a4\u7d20\u5316\u5b66\u5354\u4f1a\u8cde\u3092\u53d7\u8cde\u3057\u305f\u3002\u307e\u305f\u3001\u5316\u5b66\u306b\u304a\u3051\u308b\u56fd\u969b\u7684\u306a\u8ca2\u732e\u306b\u5bfe\u3057\u3066\u65e5\u672c\u5316\u5b66\u4f1a\u30d5\u30a7\u30ed\u30fc\u306e\u79f0\u53f7\u3092\u6388\u4e0e\u3055\u308c\u305f\u3002\u718a\u7530\u8aa0\u4eac\u90fd\u5927\u5b66\u540d\u8a89\u6559\u6388\uff08\u65e5\u672c\u5b66\u58eb\u9662\u8cde\u30fb\u6069\u8cdc\u8cde\u53d7\u8cde\uff09\u3001\u6afb\u4e95\u82f1\u6a39\u6771\u5317\u5927\u5b66\u540d\u8a89\u6559\u6388\uff08\u65e5\u672c\u5b66\u58eb\u9662\u8cde\u30fb\u6069\u8cdc\u8cde\u53d7\u8cde\u30fb\u6587\u5316\u529f\u52b4\u8005\uff09\u306e\u9580\u4e0b\u751f\u3067\u3042\u308b\u3002\u5916\u90e8\u30ea\u30f3\u30af[\u7de8\u96c6]\u7d30\u898b\u5f70 HP – \u30a6\u30a7\u30a4\u30d0\u30c3\u30af\u30de\u30b7\u30f3\uff082019\u5e741\u67081\u65e5\u30a2\u30fc\u30ab\u30a4\u30d6\u5206\uff09\u5178\u62e0\u7ba1\u7406 ISNI: 0000 0003 7700 1143NDL: 00013267VIAF: 254045969WorldCat Identities: viaf-254045969  "},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki\/archives\/9224#breadcrumbitem","name":"\u7d30\u898b\u5f70 – Wikipedia"}}]}]