[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/321829#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/321829","headline":"\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc – Wikipedia","name":"\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc – Wikipedia","description":"\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\uff08\u30a4\u30aa\u30f3-\u3076\u3093\u3057\u306f\u3093\u306e\u3046\u3001\u82f1: ion-molecular reaction\uff09\u306f\u3001\u30a4\u30aa\u30f3\u3068\u5206\u5b50\u306b\u3088\u308b\u885d\u7a81\u3067\u8d77\u3053\u308b\u53cd\u5fdc\u3001\u304a\u3088\u3073\u305d\u308c\u3089\u306e\u53cd\u5fdc\u904e\u7a0b\u306e\u7dcf\u79f0\u3092\u8a00\u3046\u3002\u5206\u5b50\u96f2\u306a\u3069\u306e\u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u306b\u304a\u3044\u3066\u306f\u3001\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u306e\u3088\u3046\u306a\u969c\u58c1\u306e\u4f4e\u3044\u53cd\u5fdc\u304c\u4e3b\u306b\u8d77\u3053\u308b\u3068\u8003\u3048\u3089\u308c\u308b[1]\u3002 Table of Contents \u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u4e0b\u3067\u306e\u5316\u5b66[\u7de8\u96c6]\u5206\u5b50\u96f2\u3067\u306e\u4e3b\u306a\u30a4\u30aa\u30f3\uff0d\u5206\u5b50\u53cd\u5fdc[\u7de8\u96c6]\u5206\u5b50\u96f2\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u30e2\u30c7\u30eb[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6] \u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u4e0b\u3067\u306e\u5316\u5b66[\u7de8\u96c6] \u96fb\u8377\u3092\u6301\u305f\u306a\u3044\u5206\u5b50\u540c\u58eb\u304c\u7d50\u5408\u3092\u7d44\u307f\u66ff\u3048\u308b\u53cd\u5fdc\u3067\u3001\u305f\u3068\u3048\u3070 AB + C \u2192 [A\u2026B\u2026C]\u2021 \u2192 A + BC \u3068\u3044\u3046\u7d20\u53cd\u5fdc\u3092\u8003\u3048\u308b\u3068\u304d\u3001\u9077\u79fb\u72b6\u614b [A\u2026B\u2026C]\u2021","datePublished":"2022-04-19","dateModified":"2022-04-19","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/cd810e53c1408c38cc766bc14e7ce26a?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/cd810e53c1408c38cc766bc14e7ce26a?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/9\/9b\/Ionmolreaction.png\/200px-Ionmolreaction.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/9\/9b\/Ionmolreaction.png\/200px-Ionmolreaction.png","height":"117","width":"200"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/321829","about":["wiki"],"wordCount":788,"articleBody":"\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\uff08\u30a4\u30aa\u30f3-\u3076\u3093\u3057\u306f\u3093\u306e\u3046\u3001\u82f1: ion-molecular reaction\uff09\u306f\u3001\u30a4\u30aa\u30f3\u3068\u5206\u5b50\u306b\u3088\u308b\u885d\u7a81\u3067\u8d77\u3053\u308b\u53cd\u5fdc\u3001\u304a\u3088\u3073\u305d\u308c\u3089\u306e\u53cd\u5fdc\u904e\u7a0b\u306e\u7dcf\u79f0\u3092\u8a00\u3046\u3002\u5206\u5b50\u96f2\u306a\u3069\u306e\u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u306b\u304a\u3044\u3066\u306f\u3001\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u306e\u3088\u3046\u306a\u969c\u58c1\u306e\u4f4e\u3044\u53cd\u5fdc\u304c\u4e3b\u306b\u8d77\u3053\u308b\u3068\u8003\u3048\u3089\u308c\u308b[1]\u3002  Table of Contents\u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u4e0b\u3067\u306e\u5316\u5b66[\u7de8\u96c6]\u5206\u5b50\u96f2\u3067\u306e\u4e3b\u306a\u30a4\u30aa\u30f3\uff0d\u5206\u5b50\u53cd\u5fdc[\u7de8\u96c6]\u5206\u5b50\u96f2\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u30e2\u30c7\u30eb[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]\u4f4e\u6e29\u30fb\u4f4e\u5bc6\u5ea6\u74b0\u5883\u4e0b\u3067\u306e\u5316\u5b66[\u7de8\u96c6]\u96fb\u8377\u3092\u6301\u305f\u306a\u3044\u5206\u5b50\u540c\u58eb\u304c\u7d50\u5408\u3092\u7d44\u307f\u66ff\u3048\u308b\u53cd\u5fdc\u3067\u3001\u305f\u3068\u3048\u3070AB + C \u2192 [A\u2026B\u2026C]\u2021 \u2192 A + BC\u3068\u3044\u3046\u7d20\u53cd\u5fdc\u3092\u8003\u3048\u308b\u3068\u304d\u3001\u9077\u79fb\u72b6\u614b [A\u2026B\u2026C]\u2021 \u306f A-B \u306e\u7d50\u5408\u3082 B-C \u306e\u7d50\u5408\u3082\u5b89\u5b9a\u72b6\u614b\u306b\u3042\u3089\u305a\u3001\u53cd\u5fdc\u306b\u304a\u3044\u3066\u8d85\u3048\u308b\u3079\u304d\u30a8\u30cd\u30eb\u30ae\u30fc\u969c\u58c1\u3068\u306a\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u53cd\u5fdc\u306f\u5206\u5b50\u96f2\u306e\u3088\u3046\u306a\u4f4e\u6e29\u74b0\u5883 (\u304a\u3088\u305d 80 K \u4ee5\u4e0b\u3001\u661f\u9593\u7269\u8cea\u3092\u53c2\u7167) \u306b\u304a\u3044\u3066\u3001\u767a\u71b1\u53cd\u5fdc\u3067\u3082\u53cd\u5fdc\u901f\u5ea6\u304c\u9045\u3044\u3002  \u96fb\u8377\u3092\u6301\u305f\u306a\u3044\u5206\u5b50\u540c\u58eb\u3067\u3082\u3001\u305f\u3068\u3048\u3070\u30e9\u30b8\u30ab\u30eb\u540c\u58eb\u306e\u53cd\u5fdc\u306e\u3088\u3046\u306b\u3082\u3068\u3082\u3068\u306e\u5206\u5b50\u304c\u4e0d\u5b89\u5b9a\u72b6\u614b\u306b\u3042\u308b\u3001D\u2022 + E\u2022 \u2192 D-E\u3068\u3044\u3063\u305f\u53cd\u5fdc\u306f\u969c\u58c1\u306f\u7121\u3044\u3002\u3057\u304b\u3057\u3001\u3053\u306e\u53cd\u5fdc\u3067\u306f DE \u304c\u5f97\u305f\u7d50\u5408\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u4ed6\u306b\u9003\u304c\u3059\u3053\u3068\u304c\u3067\u304d\u305a\u3001\u305f\u3060\u3061\u306b\u3001\u9006\u53cd\u5fdc\u306b\u3088\u3063\u3066\u89e3\u96e2\u3057\u3066\u3057\u307e\u3046\u3002\u53cd\u5fdc\u304c\u4e0d\u53ef\u9006\u7684\u306b\u9032\u3080\u305f\u3081\u306b\u306f\u3001D + E + M \u2192 D-E + M\u306e\u3088\u3046\u306a\u4e09\u4f53\u53cd\u5fdc\u3067\u306a\u3051\u308c\u3070\u3044\u3051\u306a\u3044\u3002\u3057\u304b\u3057\u3053\u306e\u3088\u3046\u306a\u53cd\u5fdc\u306f\u4f4e\u5bc6\u5ea6\uff08\u304a\u3088\u305d10-15\u6c17\u5727\uff09\u306e\u5206\u5b50\u96f2\u3067\u306f\u8d77\u3053\u3089\u306a\u3044\uff083\u7c92\u5b50\u304c\u4e00\u5ea6\u306b\u885d\u7a81\u3059\u308b\u3053\u3068\u304c\u307b\u3068\u3093\u3069\u3042\u308a\u5f97\u306a\u3044\uff09\u3002\u4ee5\u4e0a\u306e\u3088\u3046\u306a\u3053\u3068\u304b\u3089\u3001\u4f4e\u6e29\u3067\u4f4e\u5bc6\u5ea6\u306a\u5206\u5b50\u96f2\u3067\u8d77\u3053\u308b\u53cd\u5fdc\u306f\u3001\u7d50\u5408\u306e\u7d44\u307f\u66ff\u3048\u306e\u8d77\u3053\u308b\u53cd\u5fdc\u3067\u3001\u304b\u3064\u969c\u58c1\u306e\u4f4e\u3044\u53cd\u5fdc\u3067\u306a\u3051\u308c\u3070\u3044\u3051\u306a\u3044\u3002    \u969c\u58c1\u306e\u7121\u3044\u30a4\u30aa\u30f3\u5206\u5b50\u53cd\u5fdc\u306e\u53cd\u5fdc\u5ea7\u6a19\u306b\u305d\u3063\u305f\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u9762\u306e\u4f8b\u4e0b\u8a18\u306e\u3088\u3046\u306a\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u3067\u306f\u4e2d\u9593\u4f53 [A-B-C]+ \u5f62\u6210\u6642\u3001\u5143\u306e\u7d50\u5408\u3092\u4f38\u3070\u3059\u306e\u306b\u5fc5\u8981\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u30af\u30fc\u30ed\u30f3\u529b\u306b\u3088\u308b\u5b89\u5b9a\u5316\u306b\u3088\u3063\u3066\u88dc\u3048\u308b\u306e\u3067\u3001\u969c\u58c1\u306f\u7121\u3044\u304b\u3054\u304f\u4f4e\u3044\u53cd\u5fdc\u3068\u306a\u308b\u3002AB+ + C \u2192 [A-B-C]+ \u2192 A + BC+\u307e\u305f\u7d50\u5408\u3092\u7d44\u307f\u66ff\u3048\u308b\u53cd\u5fdc\u306a\u306e\u3067\u3001\u7d50\u5408\u89e3\u96e2\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u751f\u6210\u7269\u306e\u904b\u52d5\u30a8\u30cd\u30eb\u30ae\u30fc\u3078\u9003\u304c\u3059\u3053\u3068\u304c\u3067\u304d\u308b\u3002\u3088\u3063\u3066\u3001\u4f4e\u6e29\u3067\u4f4e\u5bc6\u5ea6\u306a\u5206\u5b50\u96f2\u306b\u304a\u3044\u3066\u306f\u3001\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u304c\u4e3b\u306b\u9032\u884c\u3057\u3001\u5206\u5b50\u304c\u5f62\u6210\u3055\u308c\u3066\u3044\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u5206\u5b50\u96f2\u3067\u306e\u4e3b\u306a\u30a4\u30aa\u30f3\uff0d\u5206\u5b50\u53cd\u5fdc[\u7de8\u96c6]\u30ef\u30c8\u30bd\u30f3 (W.D. Watson) [1]\u306f\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u3068\u3057\u3066\u4e8c\u3064\u306e\u30bf\u30a4\u30d7\u306e\u53cd\u5fdc\u3092\u63d0\u6848\u3057\u305f\u3002\uff08H3+ \u306e\u751f\u6210\u306b\u3064\u3044\u3066\u306f\u30d7\u30ed\u30c8\u30f3\u5316\u6c34\u7d20\u5206\u5b50#\u751f\u6210\u3092\u53c2\u7167\uff09(1) X+ + H2 \u2192 XH+ + H(2) Y + H3+ \u2192 YH+ + H2(1)\u306e\u5f62\u5f0f\u306e\u53cd\u5fdc\u4f8b\u3068\u3057\u3066\u3001\u661f\u9593\u7a7a\u9593\u3067 H,He \u306b\u3064\u3065\u3044\u3066\u5b58\u5728\u91cf\u306e\u591a\u3044 C\u539f\u5b50\u306e\u30a4\u30aa\u30f3 C+ \u3092 X+ \u3068\u3059\u308b\u306a\u3089\u3070\u3001C+ + H2 \u2192 CH+ + H\u3055\u3089\u306b\u7d9a\u3044\u3066\u3001CH+ + H2 \u2192 CH2+ + HCH2+ + H2 \u2192 CH3+ + H\u307e\u3067\u304c\u767a\u71b1\u53cd\u5fdc\u3067\u751f\u6210\u3059\u308b\u3002(2)\u306e\u5f62\u5f0f\u306e\u53cd\u5fdc\u306f\u6c34\u7d20\u5206\u5b50 (H2) \u3088\u308a\u3082\u3001\u30d7\u30ed\u30c8\u30f3 (H+) \u3068\u306e\u7d50\u5408\u529b\u304c\uff08\u30d7\u30ed\u30c8\u30f3\u89aa\u548c\u5ea6\uff09\u304c\u5927\u304d\u3044\u539f\u5b50\u3084\u5206\u5b50\u304c Y \u3067\u3042\u308c\u3070\u969c\u58c1\u304c\u4f4e\u304f\u767a\u71b1\u53cd\u5fdc\u306b\u306a\u308b\u306e\u3067\u3001\u5bb9\u6613\u306b\u8d77\u3053\u308a\u3046\u308b\u3002\u305f\u3068\u3048\u3070\u3001\u661f\u9593\u7a7a\u9593\u3067 C \u540c\u69d8\u306b\u5b58\u5728\u91cf\u306e\u591a\u3044 O,N\u539f\u5b50\u306b\u3064\u3044\u3066\u8003\u3048\u3066\u307f\u308b\u3068\u3001O + H3+ \u2192 OH+ + H2 or OH2+ + HN + H3+ \u2192 NH2+ + H\u3053\u308c\u3089\u306f\u767a\u71b1\u53cd\u5fdc\u3067\u3042\u308b\u3002\u3053\u306e\u3088\u3046\u306b\u3057\u3066\u3067\u304d\u305f\u30a4\u30aa\u30f3\u306f\u3055\u3089\u306b\u7d9a\u3044\u3066(1)\u306e\u5f62\u5f0f\u3067\u3001\u4f8b\u3048\u3070OH+ + H2 \u2192 OH2+ + H\u3068\u3044\u3046\u3088\u3046\u306b\u3055\u3089\u306a\u308b\u30a4\u30aa\u30f3\u3092\u5f62\u6210\u3057\u3066\u3044\u304f\u3002\u6700\u7d42\u7684\u306bYH+\u3068\u3044\u3046\u5206\u5b50\u306f\u96fb\u5b50\u3068\u518d\u7d50\u5408\u3057\u3001YH+ + e\u2212 \u2192 Y + H\u3068\u3044\u3046\u5f62\u3067\u4e2d\u6027\u5316\u3059\u308b\u3002\u5206\u5b50\u96f2\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u30e2\u30c7\u30eb[\u7de8\u96c6]\u30cf\u30fc\u30d7\u30b9\u30c8 (E. Herbst) \u3068\u30af\u30ec\u30f3\u30da\u30e9\u30fc (W. Klemperer) [2]\u306f1973\u5e74\u306b\u4e0a\u306b\u6319\u3052\u305f\u3088\u3046\u306a\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u3092\u542b\u3081\u305f\u304a\u3088\u305d100\u7a2e\u985e\u7a0b\u5ea6\u306e\u53cd\u5fdc\u3068\u3001\u5f53\u6642\u77e5\u3089\u308c\u3066\u3044\u305f\u539f\u5b50\u306e\u5b58\u5728\u91cf\u3092\u4eee\u5b9a\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u5206\u5b50\u96f2\u306b\u304a\u3044\u3066\u3069\u306e\u3088\u3046\u306a\u5206\u5b50\u304c\u3069\u308c\u3060\u3051\u751f\u6210\u3055\u308c\u308b\u304b\u306b\u3064\u3044\u3066\u6982\u7b97\u3092\u3057\u305f\u3002\u3053\u306e\u8a08\u7b97\u3067\u5f53\u6642\u89b3\u6e2c\u3055\u308c\u3066\u3044\u305f\u661f\u9593\u5206\u5b50 (CO, OH, NO, CN, HCN, HCO+, H2CO) \u306e\u5206\u5b50\u96f2\u3067\u306e\u5b58\u5728\u91cf\u3068\u3001\u3088\u3044\u4e00\u81f4\u3092\u793a\u3057\u305f\u3002\u3053\u306e\u3053\u3068\u304b\u3089\u3001\u5206\u5b50\u96f2\u306b\u304a\u3044\u3066\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc\u304c\u91cd\u8981\u3067\u3042\u308b\u3053\u3068\u304c\u793a\u3055\u308c\u305f\u3002^ a b W.D. Watson, “The Rate of Formation of Interstellar Molecules by Ion-Molecule Reactions.”, Astrophys. J. Lett. 183, L17 (1973)^ E. Herbst, W. Klemperer, “The Formation and Depletion of Molecules in Dense Interstellar Clouds.”, Astrophys. J. 185, 505 (1973).\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki15\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki15\/archives\/321829#breadcrumbitem","name":"\u30a4\u30aa\u30f3-\u5206\u5b50\u53cd\u5fdc – Wikipedia"}}]}]