[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/1119#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/1119","headline":"\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 – Wikipedia","name":"\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 – Wikipedia","description":"\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 Diphenylphosphinous chloride[1] \u5225\u79f0 diphenylchlorophosphine \u8b58\u5225\u60c5\u5831 CAS\u767b\u9332\u756a\u53f7 1079-66-9 PubChem 66180 \u7279\u6027 \u5316\u5b66\u5f0f C12H10ClP \u30e2\u30eb\u8cea\u91cf 220.64 g\/mol \u5916\u89b3 \u7121\u8272\u304b\u3089\u6de1\u9ec4\u8272\u6db2\u4f53 \u5bc6\u5ea6 1.229","datePublished":"2018-06-30","dateModified":"2018-06-30","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/cd810e53c1408c38cc766bc14e7ce26a?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/cd810e53c1408c38cc766bc14e7ce26a?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/2\/22\/Ph2PCl.png\/200px-Ph2PCl.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/2\/22\/Ph2PCl.png\/200px-Ph2PCl.png","height":"147","width":"200"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/1119","about":["Wikipedia"],"wordCount":2283,"articleBody":"\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3Diphenylphosphinous chloride[1]\u5225\u79f0diphenylchlorophosphine\u8b58\u5225\u60c5\u5831CAS\u767b\u9332\u756a\u53f71079-66-9PubChem66180\u7279\u6027\u5316\u5b66\u5f0fC12H10ClP\u30e2\u30eb\u8cea\u91cf220.64 g\/mol\u5916\u89b3\u7121\u8272\u304b\u3089\u6de1\u9ec4\u8272\u6db2\u4f53\u5bc6\u5ea61.229 g cm\u22123\u6cb8\u70b9320\u00a0\u00b0C\u6c34\u3078\u306e\u6eb6\u89e3\u5ea6\u53cd\u5fdc\u3059\u308b\u5371\u967a\u6027GHS\u30d4\u30af\u30c8\u30b0\u30e9\u30e0GHS\u30b7\u30b0\u30ca\u30eb\u30ef\u30fc\u30c9\u5371\u967a(DANGER)H\u30d5\u30ec\u30fc\u30baH290, H302, H314, H318, H412P\u30d5\u30ec\u30fc\u30baP234, P260, P264, P270, P273, P280, P301+312, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P330\u7279\u8a18\u306a\u304d\u5834\u5408\u3001\u30c7\u30fc\u30bf\u306f\u5e38\u6e29 (25\u00a0\u00b0C)\u30fb\u5e38\u5727 (100\u00a0kPa) \u306b\u304a\u3051\u308b\u3082\u306e\u3067\u3042\u308b\u3002\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 (Chlorodiphenylphosphine) \u306f\u3001\u5316\u5b66\u5f0f (C6H5)2PCl \u3067\u8868\u3055\u308c\u308b\u6709\u6a5f\u30ea\u30f3\u5316\u5408\u7269\u3067\u3042\u308b\u3002Ph2PCl \u3068\u7565\u3055\u308c\u308b\u3002\u7121\u8272\u306e\u6cb9\u72b6\u6db2\u4f53\u3067\u3001\u306b\u3093\u306b\u304f\u69d8\u306e\u523a\u6fc0\u6027\u306e\u5302\u3044\u304c\u3042\u308a\u3001ppb \u306e\u30ec\u30d9\u30eb\u3067\u3082\u611f\u3058\u53d6\u308c\u308b\u3068\u8a00\u308f\u308c\u3066\u3044\u308b\u3002\u591a\u304f\u306e\u914d\u4f4d\u5b50\u3092\u542b\u3080\u5206\u5b50\u306b Ph2P\u57fa\u3092\u5c0e\u5165\u3059\u308b\u305f\u3081\u306e\u6709\u7528\u306a\u8a66\u85ac\u3067\u3042\u308b[2]\u3002\u4ed6\u306e\u30cf\u30ed\u30db\u30b9\u30d5\u30a3\u30f3\u3068\u540c\u69d8\u306b\u3001Ph2PCl\u306f\u3001\u6c34\u306a\u3069\u306e\u591a\u304f\u306e\u6c42\u6838\u8a66\u85ac\u3068\u53cd\u5fdc\u3057\u3001\u7a7a\u6c17\u4e2d\u3067\u3082\u5bb9\u6613\u306b\u9178\u5316\u3055\u308c\u308b\u3002\u5408\u6210\u3068\u53cd\u5fdc[\u7de8\u96c6]\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001\u30d9\u30f3\u30bc\u30f3\u3068\u4e09\u5869\u5316\u30ea\u30f3\u304b\u3089\u5546\u696d\u898f\u6a21\u3067\u751f\u7523\u3055\u308c\u308b\u3002\u30d9\u30f3\u30bc\u30f3\u306f 600\u2103\u524d\u5f8c\u306e\u6975\u7aef\u306a\u6e29\u5ea6\u3067\u4e09\u5869\u5316\u30ea\u30f3\u3068\u53cd\u5fdc\u3057\u3001\u30b8\u30af\u30ed\u30ed\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 (PhPCl2) \u3068 HCl\u3092\u751f\u6210\u3059\u308b\u3002\u9ad8\u6e29\u306e\u6c17\u76f8\u3067\u306e PhPCl2\u306e\u518d\u5206\u914d\u3067\u3001\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u304c\u5f97\u3089\u308c\u308b[2][3]\u30022 PhPCl2 \u2192 Ph2PCl + PCl3\u307e\u305f\u306f\u3001\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001\u30c8\u30ea\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u3068\u4e09\u5869\u5316\u30ea\u30f3\u3092\u51fa\u767a\u7269\u8cea\u3068\u3057\u3066\u518d\u5206\u914d\u53cd\u5fdc\u306b\u3088\u3063\u3066\u8abf\u88fd\u3055\u308c\u308b\u3002PCl3 +  2 PPh3 \u2192 2 Ph2PCl\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001\u52a0\u6c34\u5206\u89e3\u306b\u3088\u3063\u3066\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u30aa\u30ad\u30b7\u30c9\u3092\u4e0e\u3048\u308b\u3002\u30ca\u30c8\u30ea\u30a6\u30e0\u3067\u9084\u5143\u3059\u308b\u3068\u30c6\u30c8\u30e9\u30d5\u30a7\u30cb\u30eb\u30b8\u30db\u30b9\u30d5\u30a3\u30f3\uff08\u82f1\u8a9e\u7248\uff09\u304c\u5f97\u3089\u308c\u308b\u30022 Ph2PCl  +  2 Na \u2192 [Ph2P]2 +  2 NaCl\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001\u4ed6\u306e\u30af\u30ed\u30ed\u30db\u30b9\u30d5\u30a3\u30f3\u3068\u3068\u3082\u306b\u3001\u3055\u307e\u3056\u307e\u306a\u30db\u30b9\u30d5\u30a3\u30f3\u306e\u5408\u6210\u306b\u4f7f\u7528\u3055\u308c\u308b\u3002\u4ee3\u8868\u7684\u306a\u30eb\u30fc\u30c8\u306f\u30b0\u30ea\u30cb\u30e3\u30fc\u30eb\u8a66\u85ac\u3078\u306e\u4f7f\u7528\u3067\u3042\u308b[3]\u3002Ph2PCl + MgRX   \u2192    Ph2PR  +  MgClXPh2PCl\u3068\u306e\u53cd\u5fdc\u304b\u3089\u751f\u6210\u3055\u308c\u308b\u30db\u30b9\u30d5\u30a3\u30f3\u985e\u306f\u3055\u3089\u306b\u958b\u767a\u3055\u308c\u3001\u8fb2\u85ac\uff08\u4f8b\u3048\u3070EPN\u306e\u3088\u3046\u306a)\u3001\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u306e\u5b89\u5b9a\u5264\uff08Sandostab P-EPQ\uff09\u3001\u3055\u307e\u3056\u307e\u306a\u30cf\u30ed\u30b2\u30f3\u5316\u5408\u7269\u89e6\u5a92\u3001\u96e3\u71c3\u5264\uff08\u74b0\u72b6\u30db\u30b9\u30d5\u30a3\u30ce\u30ab\u30eb\u30dc\u30f3\u9178\u7121\u6c34\u7269\uff09\u3068\u3057\u3066\u4f7f\u308f\u308c\u308b\u3002\u307e\u305f\u3001\u7d2b\u5916\u7dda\u786c\u5316\u5857\u6599\u30b7\u30b9\u30c6\u30e0\uff08\u6b6f\u79d1\u6750\u6599\u3067\u4f7f\u7528\uff09\u306b\u3082\u4f7f\u308f\u308c\u3001Ph2PCl\u3092\u7523\u696d\u754c\u3067\u91cd\u8981\u306a\u4e2d\u9593\u4f53\u306b\u3057\u3066\u3044\u308b[2][3]\u3002\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30c9\u8a98\u5c0e\u4f53\u306e\u524d\u99c6\u4f53\u3068\u3057\u3066[\u7de8\u96c6]\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001\u30b8\u30aa\u30ad\u30b5\u30f3\u306e\u9084\u6d41\u4e0b\u3067\u91d1\u5c5e\u30ca\u30c8\u30ea\u30a6\u30e0\u3068\u306e\u53cd\u5fdc\u3092\u4ecb\u3057\u3066\u3001\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30c9\u30ca\u30c8\u30ea\u30a6\u30e0\u306e\u5408\u6210\u306b\u4f7f\u7528\u3055\u308c\u308b[4]\u3002Ph2PCl  +  2 Na   \u2192   Ph2PNa  +  NaCl\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306f\u3001Ph2PCl \u3068 LiAlH4 \u306e\u53cd\u5fdc\u3067\u5f97\u3089\u308c\u308b\u3002\u901a\u5e38\u3001\u5f8c\u8005\u306f\u904e\u5270\u306b\u7528\u3044\u3089\u308c\u308b[5]\u30024 Ph2PCl  +  LiAlH4  \u2192  4 Ph2PH  +  LiCl  +  AlCl3Ph2PNa \u3068 PH2PH \u306f\u4e21\u65b9\u3068\u3082\u6709\u6a5f\u30db\u30b9\u30d5\u30a3\u30f3\u914d\u4f4d\u5b50\u306e\u5408\u6210\u306b\u7528\u3044\u3089\u308c\u308b\u3002\u7279\u6027\u8a55\u4fa1[\u7de8\u96c6]\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u306e\u54c1\u8cea\u306f\u3001\u3057\u3070\u3057\u3070 31P NMR \u30b9\u30da\u30af\u30c8\u30eb\u3067\u30c1\u30a7\u30c3\u30af\u3055\u308c\u308b[6]\u3002\u5316\u5408\u726931P \u30b1\u30df\u30ab\u30eb\u30b7\u30d5\u30c8(ppm vs 85% H3PO4)PPh3-6PPh2Cl81.5PPhCl2165PCl3218^ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. pp.\u00a0926. doi:10.1039\/9781849733069. ISBN\u00a0978-0-85404-182-4\u00a0^ a b c Quin, L. D. A Guide to Organophosphorus Chemistry; Wiley IEEE: New York, 2000; pp 44-69. 0-471-31824-8^ a b c Svara, J.; Weferling, N.; Hofmann, T. “Phosphorus Compounds, Organic,” In ‘Ullmann’s Encyclopedia of Industrial Chemistry, 7th ed.; Wiley-VCH: 2008; doi:10.1002\/14356007.a19_545.pub2; Accessed: February 18, 2008.^ Roy, Jackson W; Thomson, RJ; MacKay.m.f, . (1985). \u201cThe Stereochemistry of Organometallic Compounds. XXV. The Stereochemistry of Displacements of Secondary Methanesulfonate and p-Toluene-sulfonate esters by Diphenylphosphide Ions. X-ray Crystal Structure of (5\u03b1-Cholestan-3\u03b1-yl)diphenylphosphine Oxide\u201d. Australian Journal of Chemistry 38 (1):  111\u201318. doi:10.1071\/CH9850111.\u00a0^ Stepanova, Valeria A.; Dunina, Valery V.; Smoliakova, Irina P. (2009). \u201cReactions of Cyclopalladated Complexes with Lithium Diphenylphosphide\u201d. Organometallics 28 (22):  6546\u20136558. doi:10.1021\/om9005615.\u00a0^ O. K\u00fchl “Phosphorus-31 NMR Spectroscopy” Springer, Berlin, 2008. 978-3-540-79118-8"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki2\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki2\/archives\/1119#breadcrumbitem","name":"\u30af\u30ed\u30ed\u30b8\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3 – Wikipedia"}}]}]