[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/287987#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/287987","headline":"\u30d5\u30ed\u30b9\u30c8\u30fb\u30e0\u30b9\u30ea\u30f3\u5186 – Wikipedia","name":"\u30d5\u30ed\u30b9\u30c8\u30fb\u30e0\u30b9\u30ea\u30f3\u5186 – Wikipedia","description":"\u30d5\u30ed\u30b9\u30c8\u5186\uff08\u30d5\u30ed\u30b9\u30c8\u3048\u3093\u3001\u72ec: Frost-Kreis\uff09\u306f\u3001\u5358\u74b0\u5316\u5408\u7269\u304c\u82b3\u9999\u65cf\u6027\u3092\u6301\u3064\u304b\u3069\u3046\u304b\u3092\u5224\u65ad\u3059\u308b\u305f\u3081\u306e\u30b0\u30e9\u30d5\u7684\u624b\u6cd5\u3067\u3042\u308b\u3002 \u30a2\u30e1\u30ea\u30ab\u4eba\u5316\u5b66\u8005\u30a2\u30fc\u30b5\u30fc\u30fbA\u30fb\u30d5\u30ed\u30b9\u30c8\uff08\u30c9\u30a4\u30c4\u8a9e\u7248\uff09\u3068\u30dc\u30ea\u30b9\u30fb\u30e0\u30b9\u30ea\u30f3\u306b\u3088\u308a\u958b\u767a\u3055\u308c\u305f[1]\u3002\u5e73\u9762\u5358\u74b0\u5316\u5408\u7269\u306e\u8ecc\u9053\u30a8\u30cd\u30eb\u30ae\u30fc\u304a\u3088\u3073\u5171\u5f79\u5206\u5b50\u5168\u4f53\u306e\u5b89\u5b9a\u6027\u3092\u898b\u7a4d\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002 Table of Contents \u30d2\u30e5\u30c3\u30b1\u30eb\u5247[\u7de8\u96c6]\u30d5\u30ed\u30b9\u30c8\u5186\u306e\u69cb\u6210[\u7de8\u96c6]\u30b7\u30af\u30ed\u30d7\u30ed\u30da\u30cb\u30eb\u30ab\u30c1\u30aa\u30f3\u30fb\u30a2\u30cb\u30aa\u30f3\u306e\u4f8b[\u7de8\u96c6]\u30b7\u30af\u30ed\u30d6\u30bf\u30b8\u30a8\u30f3\u306e\u4f8b[\u7de8\u96c6] \u30d2\u30e5\u30c3\u30b1\u30eb\u5247[\u7de8\u96c6] 20\u4e16\u7d00\u524d\u534a\u306b\u91cf\u5b50\u5316\u5b66\u304c\u5275\u59cb\u3055\u308c\u308b\u3068\u3001\u82b3\u9999\u65cf\u306e\u57fa\u6e96\u304c\u8003\u6848\u3055\u308c\u305f\u30021930\u5e74\u4ee3\u3001\u30a8\u30fc\u30ea\u30d2\u30fb\u30d2\u30e5\u30c3\u30b1\u30eb\u306b\u3088\u308a\u6b21\u306e\u3088\u3046\u306a\u57fa\u6e96\u304c\u767a\u8868\u3055\u308c\u3001\u30d2\u30e5\u30c3\u30b1\u30eb\u5247\u3068\u547c\u3070\u308c\u3066\u3044\u308b\u3002 \u82b3\u9999\u65cf\u3068\u306f (4n\u00a0+\u00a02) \u500b\u306e\u03c0\u96fb\u5b50\u3092\u6301\u3064\u5e73\u9762\u5358\u74b0\u5206\u5b50\u3067\u3042\u308b\u3002 \u03c0\u96fb\u5b50\u3068\u306f\u3001\u5206\u5b50\u9762\u306b\u6cbf\u3063\u3066\u5b58\u5728\u305b\u305a\u3001\u305d\u306e\u4e0a\u4e0b\u306b\u5206\u5e03\u3059\u308b\u96fb\u5b50\u3092\u3044\u3046[2]\u3002 \u5b9f\u9a13\u7684\u306b\u89b3\u6e2c\u3055\u308c\u3066\u3044\u308b\u30d9\u30f3\u30bc\u30f3\uff08\u7d44\u6210\u5f0f: C6H6\uff09\u306e\u7279\u7570\u7684\u5b89\u5b9a\u6027\u306f\u82b3\u9999\u65cf\u7d50\u5408\u306e\u539f\u578b\u3067\u3042\u308b\u304c\u3001\u30d2\u30e5\u30c3\u30b1\u30eb\u306f\u3053\u306e\u7406\u7531\u304c\u7d50\u5408\u6027\u5206\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u304c(4\u00a0\u00b7\u00a01\u00a0+\u00a02\u00a0=\u00a06) \u500b\u306e\u03c0\u96fb\u5b50\u306b\u3088\u3063\u3066\u4e8c\u91cd\u5360\u6709\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u3067\u3042\u308b\u3068\u660e\u3089\u304b\u306b\u3057\u305f\u3002LCAO\u6cd5\u3092\u7528\u3044\u308b\u3068\u3001\u69cb\u6210\u539f\u5b50\u306e\u539f\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u3092\u300c\u6df7\u5408\u300d\u3059\u308b\uff08\u30b7\u30e5\u30ec\u30fc\u30c7\u30a3\u30f3\u30ac\u30fc\u65b9\u7a0b\u5f0f\u306e\u89e3\u540c\u58eb\u306e\u8a08\u7b97\u4e0a\u7dda\u5f62\u7d50\u5408\u3092\u3068\u308b\uff09\u3002\u5206\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u306f\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u975e\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u53cd\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u306b\u5206\u985e\u3055\u308c\u3001\u30d5\u30f3\u30c8\u306e\u898f\u5247\u306b\u5f93\u3063\u3066\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u4f4e\u3044\u9806\u306b\u5360\u6709\u3055\u308c\u308b\u3002 \u30d5\u30ed\u30b9\u30c8\u5186\u306e\u69cb\u6210[\u7de8\u96c6] n\u54e1\u74b0\u3092\u3001\u9802\u70b9\u304c\u4e0b\u306b\u5411\u304f\u3088\u3046\u66f8\u304d\u3001\u305d\u306e\u9802\u70b9\u3092\u901a\u308b\u5186\u3092\u66f8\u304f\u3002\u30d5\u30ed\u30b9\u30c8\u306b\u3088\u308b\u8868\u8a18\u306b\u5f93\u3048\u3070\u3001\u3053\u306e\u5186\u306e\u534a\u5f84\u306f 2\u03b2\u3068\u3059\u308b\u3002\u8ecc\u9053 m\u00a0=\u00a00","datePublished":"2022-04-26","dateModified":"2022-04-26","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/11\/book.png","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/c\/cb\/Frost-01.png\/600px-Frost-01.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/c\/cb\/Frost-01.png\/600px-Frost-01.png","height":"186","width":"600"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/287987","about":["Wiki"],"wordCount":1176,"articleBody":"\u30d5\u30ed\u30b9\u30c8\u5186\uff08\u30d5\u30ed\u30b9\u30c8\u3048\u3093\u3001\u72ec: Frost-Kreis\uff09\u306f\u3001\u5358\u74b0\u5316\u5408\u7269\u304c\u82b3\u9999\u65cf\u6027\u3092\u6301\u3064\u304b\u3069\u3046\u304b\u3092\u5224\u65ad\u3059\u308b\u305f\u3081\u306e\u30b0\u30e9\u30d5\u7684\u624b\u6cd5\u3067\u3042\u308b\u3002 \u30a2\u30e1\u30ea\u30ab\u4eba\u5316\u5b66\u8005\u30a2\u30fc\u30b5\u30fc\u30fbA\u30fb\u30d5\u30ed\u30b9\u30c8\uff08\u30c9\u30a4\u30c4\u8a9e\u7248\uff09\u3068\u30dc\u30ea\u30b9\u30fb\u30e0\u30b9\u30ea\u30f3\u306b\u3088\u308a\u958b\u767a\u3055\u308c\u305f[1]\u3002\u5e73\u9762\u5358\u74b0\u5316\u5408\u7269\u306e\u8ecc\u9053\u30a8\u30cd\u30eb\u30ae\u30fc\u304a\u3088\u3073\u5171\u5f79\u5206\u5b50\u5168\u4f53\u306e\u5b89\u5b9a\u6027\u3092\u898b\u7a4d\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002  Table of Contents\u30d2\u30e5\u30c3\u30b1\u30eb\u5247[\u7de8\u96c6]\u30d5\u30ed\u30b9\u30c8\u5186\u306e\u69cb\u6210[\u7de8\u96c6]\u30b7\u30af\u30ed\u30d7\u30ed\u30da\u30cb\u30eb\u30ab\u30c1\u30aa\u30f3\u30fb\u30a2\u30cb\u30aa\u30f3\u306e\u4f8b[\u7de8\u96c6]\u30b7\u30af\u30ed\u30d6\u30bf\u30b8\u30a8\u30f3\u306e\u4f8b[\u7de8\u96c6]\u30d2\u30e5\u30c3\u30b1\u30eb\u5247[\u7de8\u96c6]20\u4e16\u7d00\u524d\u534a\u306b\u91cf\u5b50\u5316\u5b66\u304c\u5275\u59cb\u3055\u308c\u308b\u3068\u3001\u82b3\u9999\u65cf\u306e\u57fa\u6e96\u304c\u8003\u6848\u3055\u308c\u305f\u30021930\u5e74\u4ee3\u3001\u30a8\u30fc\u30ea\u30d2\u30fb\u30d2\u30e5\u30c3\u30b1\u30eb\u306b\u3088\u308a\u6b21\u306e\u3088\u3046\u306a\u57fa\u6e96\u304c\u767a\u8868\u3055\u308c\u3001\u30d2\u30e5\u30c3\u30b1\u30eb\u5247\u3068\u547c\u3070\u308c\u3066\u3044\u308b\u3002\u82b3\u9999\u65cf\u3068\u306f (4n\u00a0+\u00a02) \u500b\u306e\u03c0\u96fb\u5b50\u3092\u6301\u3064\u5e73\u9762\u5358\u74b0\u5206\u5b50\u3067\u3042\u308b\u3002\u03c0\u96fb\u5b50\u3068\u306f\u3001\u5206\u5b50\u9762\u306b\u6cbf\u3063\u3066\u5b58\u5728\u305b\u305a\u3001\u305d\u306e\u4e0a\u4e0b\u306b\u5206\u5e03\u3059\u308b\u96fb\u5b50\u3092\u3044\u3046[2]\u3002\u5b9f\u9a13\u7684\u306b\u89b3\u6e2c\u3055\u308c\u3066\u3044\u308b\u30d9\u30f3\u30bc\u30f3\uff08\u7d44\u6210\u5f0f: C6H6\uff09\u306e\u7279\u7570\u7684\u5b89\u5b9a\u6027\u306f\u82b3\u9999\u65cf\u7d50\u5408\u306e\u539f\u578b\u3067\u3042\u308b\u304c\u3001\u30d2\u30e5\u30c3\u30b1\u30eb\u306f\u3053\u306e\u7406\u7531\u304c\u7d50\u5408\u6027\u5206\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u304c(4\u00a0\u00b7\u00a01\u00a0+\u00a02\u00a0=\u00a06) \u500b\u306e\u03c0\u96fb\u5b50\u306b\u3088\u3063\u3066\u4e8c\u91cd\u5360\u6709\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u3067\u3042\u308b\u3068\u660e\u3089\u304b\u306b\u3057\u305f\u3002LCAO\u6cd5\u3092\u7528\u3044\u308b\u3068\u3001\u69cb\u6210\u539f\u5b50\u306e\u539f\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u3092\u300c\u6df7\u5408\u300d\u3059\u308b\uff08\u30b7\u30e5\u30ec\u30fc\u30c7\u30a3\u30f3\u30ac\u30fc\u65b9\u7a0b\u5f0f\u306e\u89e3\u540c\u58eb\u306e\u8a08\u7b97\u4e0a\u7dda\u5f62\u7d50\u5408\u3092\u3068\u308b\uff09\u3002\u5206\u5b50\u30aa\u30fc\u30d3\u30bf\u30eb\u306f\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u975e\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u53cd\u7d50\u5408\u6027\u30aa\u30fc\u30d3\u30bf\u30eb\u3068\u306b\u5206\u985e\u3055\u308c\u3001\u30d5\u30f3\u30c8\u306e\u898f\u5247\u306b\u5f93\u3063\u3066\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u4f4e\u3044\u9806\u306b\u5360\u6709\u3055\u308c\u308b\u3002  \u30d5\u30ed\u30b9\u30c8\u5186\u306e\u69cb\u6210[\u7de8\u96c6]n\u54e1\u74b0\u3092\u3001\u9802\u70b9\u304c\u4e0b\u306b\u5411\u304f\u3088\u3046\u66f8\u304d\u3001\u305d\u306e\u9802\u70b9\u3092\u901a\u308b\u5186\u3092\u66f8\u304f\u3002\u30d5\u30ed\u30b9\u30c8\u306b\u3088\u308b\u8868\u8a18\u306b\u5f93\u3048\u3070\u3001\u3053\u306e\u5186\u306e\u534a\u5f84\u306f 2\u03b2\u3068\u3059\u308b\u3002\u8ecc\u9053 m\u00a0=\u00a00 \u301c n \u306e\u8ecc\u9053\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u305d\u308c\u305e\u308c\u3001 sin(m\u00a0\u00b7\u00a0360\u00b0\/n\u00a0\u2212\u00a090\u00b0)\u00b7\u00a02\u03b2 \u3082\u3057\u304f\u306f sin(m\u00a0\u00b7\u00a02 \u03c0\/n\u00a0\u2212\u00a0\u03c0\/2)\u00b7\u00a02\u03b2\u3068\u3044\u3046\u516c\u5f0f\u306b\u5f93\u3063\u3066\u5f97\u3089\u308c\u308b\u3002\u30b7\u30af\u30ed\u30d7\u30ed\u30da\u30cb\u30eb\u30ab\u30c1\u30aa\u30f3\u30fb\u30a2\u30cb\u30aa\u30f3\u306e\u4f8b[\u7de8\u96c6]\u307e\u305a\u3001\u6a2a\u8ef8\u4e0a\u306b\u4e2d\u5fc3\u3092\u3082\u3064\u534a\u5f84 2\u03b2 \u306e\u5186\u3092\u63cf\u304f\u3002\u3053\u306e\u5186\u306e\u4e0a\u306bn\u54e1\u74b0\u3092\u9802\u70b9\u304c\u4e0b\u306b\u5411\u304f\u3088\u3046\u306b\u63cf\u304f\u3002n\u54e1\u74b0\u3068\u5186\u306e\u63a5\u70b9\u304c\u5206\u5b50\u8ecc\u9053\u306e\u76f8\u5bfe\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u8868\u308f\u3059\u3002  \u30d2\u30e5\u30c3\u30b1\u30eb\u306b\u3088\u308c\u3070\u3001\u7cfb\u304c\u82b3\u9999\u65cf\u3068\u306a\u308b\u306e\u306f\u3001\u5168\u3066\u306e\u7d50\u5408\u6027\u8ecc\u9053\u304c\u4e8c\u91cd\u5360\u6709\u3055\u308c\u3066\u3044\u308b\u3088\u3046\u306a\u5834\u5408\u3067\u3042\u308b\u3002  \u30b7\u30af\u30ed\u30d7\u30ed\u30da\u30cb\u30eb\u30ab\u30c1\u30aa\u30f3 C3H3+ \u306f\u82b3\u9999\u65cf\u3068\u306a\u308b\u3002\u975e\u5c40\u5728\u5316\u306b\u3088\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u5229\u5f97 \u0394E \u306f 2e\u2212\u00b7(\u22122\u03b2)\u00a0=\u00a0\u22124\u03b2\u306e\u3088\u3046\u306b\u6c42\u3081\u3089\u308c\u308b\u3002\u5bfe\u3057\u3066\u30b7\u30af\u30ed\u30d7\u30ed\u30da\u30cb\u30eb\u30a2\u30cb\u30aa\u30f3 C3H3\u2212 \u306f\u30b8\u30e9\u30b8\u30ab\u30eb\u69cb\u9020\u3092\u6301\u3061\u3001\u0394E\u00a0=\u00a0\u03b2\u00a0+\u00a0\u03b2\u00a0\u2212\u00a02\u03b2\u00a0=\u00a00 \u3068\u306a\u308b\u3002  \u30b7\u30af\u30ed\u30d6\u30bf\u30b8\u30a8\u30f3\u306e\u4f8b[\u7de8\u96c6]  \u03c0\u96fb\u5b50\u306e\u975e\u5c40\u5728\u5316\u306b\u3088\u308a\u30b8\u30e9\u30b8\u30ab\u30eb\u69cb\u9020\u304c\u5f97\u3089\u308c\u308b\u5834\u5408\u3082\u3042\u308b\u3002\u30b7\u30af\u30ed\u30d6\u30bf\u30b8\u30a8\u30f3\u306f\u82b3\u9999\u65cf\u3067\u306f\u306a\u3044[3][4]\u3002^ Frost, Arthur A.; Musulin, Boris (1953). \u201cA Mnemonic Device for Molecular Orbital Energies\u201d. J. Chem. Phys. 21 (3):  572\u2013573. doi:10.1063\/1.1698970.\u00a0^ Nguy\u00ean Trong Anh (1972). Die Woodward-Hofmann-Regel und ihre Anwendung. Verlag Chemie. ISBN\u00a0978-3527254309\u00a0 ^ \u201cAromatic Compounds (Overview)\u201d. ChemgaPedia. 2018\u5e748\u67088\u65e5\u95b2\u89a7\u3002 ^  H\u00fcckel-MO: Aromaten, H\u00fcckel-Regel). http:\/\/www.chemgapedia.de\/vsengine\/vlu\/vsc\/de\/ch\/15\/thc\/hueckel\/tc032_hueckel_regel.vlu.html 2018\u5e748\u67088\u65e5\u95b2\u89a7\u3002\u00a0"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki20\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki20\/archives\/287987#breadcrumbitem","name":"\u30d5\u30ed\u30b9\u30c8\u30fb\u30e0\u30b9\u30ea\u30f3\u5186 – Wikipedia"}}]}]