[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/106241#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/106241","headline":"\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d – Wikipedia","name":"\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d – Wikipedia","description":"\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\uff08\u30b9\u30de\u30a4\u30eb\u30b9\u3066\u3093\u3044\u3001\u82f1: Smiles rearrangement\uff09\u306f\u3001\u6709\u6a5f\u53cd\u5fdc\u304a\u3088\u3073\u8ee2\u4f4d\u53cd\u5fdc\u306e\u4e00\u3064\u3067\u3042\u308b[1]\u3002\u5206\u5b50\u5185\u82b3\u9999\u65cf\u6c42\u6838\u7f6e\u63db\u53cd\u5fdc\u306b\u5206\u985e\u3055\u308c\u308b\u3002 X\u306f\u30b9\u30eb\u30db\u30f3\u3001\u30b9\u30eb\u30d5\u30a3\u30c9\u3001\u30a8\u30fc\u30c6\u30eb\u306a\u3069\u30a2\u30ec\u30fc\u30f3\u304b\u3089\u8131\u96e2\u3067\u304d\u308b\u4efb\u610f\u306e\u7f6e\u63db\u57fa\u3002\u5b98\u80fd\u57fa\u9396\u306e\u672b\u7aef\u306eY\u306f\u30a2\u30eb\u30b3\u30fc\u30eb\u3084\u30a2\u30df\u30f3\u3001\u30c1\u30aa\u30fc\u30eb\u306a\u3069\u306e\u6c42\u6838\u6027\u304c\u5f37\u3044\u57fa\u3002 \u4ed6\u306e\u82b3\u9999\u65cf\u6c42\u6838\u7f6e\u63db\u53cd\u5fdc\u306e\u3088\u3046\u306b\u30aa\u30eb\u30c8\u4f4d\u306e\u6975\u6027\u52b9\u679c\u306b\u3088\u308b\u6d3b\u6027\u5316\u3092\u5fc5\u8981\u3068\u3059\u308b\u3002 \u30c8\u30eb\u30fc\u30b9\u30fb\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u3068\u547c\u3070\u308c\u308b\u6539\u826f\u578b\u306f\u3001\u6709\u6a5f\u30ea\u30c1\u30a6\u30e0\u3092\u4f7f\u3046\u3053\u3068\u306b\u3088\u308a\u5165\u3063\u3066\u304f\u308b\u6c42\u6838\u6027\u57fa\u306e\u5f37\u3044\u4ed8\u52a0\u7684\u6d3b\u6027\u3092\u5fc5\u8981\u3068\u3057\u306a\u3044\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u30a2\u30ea\u30fc\u30eb\u30b9\u30eb\u30db\u30f3\u304b\u3089n-\u30d6\u30c1\u30eb\u30ea\u30c1\u30a6\u30e0\u306e\u4f5c\u7528\u306b\u3088\u308b\u30b9\u30eb\u30d5\u30a3\u30f3\u9178\u3078\u306e\u5909\u63db\u306b\u3088\u3063\u3066\u5b9f\u8a3c\u3055\u308c\u305f[2]\u3002 \u3053\u306e\u53cd\u5fdc\u306f\u30a2\u30eb\u30ad\u30eb\u30ea\u30c1\u30a6\u30e0\u3068\u305d\u306e\u30aa\u30eb\u30c8\u4f4d\u306e\u30b9\u30eb\u30db\u30f3\u3068\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u5fc5\u8981\u3068\u3059\u308b\u3002 \u6982\u5ff5\u7684\u306b\u95a2\u9023\u3059\u308b\u53cd\u5fdc\u306b\u30c1\u30e3\u30c3\u30d7\u30de\u30f3\u8ee2\u4f4d\u304c\u3042\u308b\u3002 \u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u306e\u30e9\u30b8\u30ab\u30eb\u7248\u304c2015\u5e74\u306bStephenson\u306b\u3088\u3063\u3066\u5831\u544a\u3055\u308c\u305f[3]\u3002 \u6797\u8ee2\u4f4d\u306f\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u306e\u967d\u30a4\u30aa\u30f3\u7248\u3068\u8003\u3048\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002 ^ Levy, Arthur A.; Rains, Harry C.; Smiles, Samuel (1931).","datePublished":"2022-03-23","dateModified":"2022-03-23","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/d5\/Smiles_rearrangement.svg\/400px-Smiles_rearrangement.svg.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/d\/d5\/Smiles_rearrangement.svg\/400px-Smiles_rearrangement.svg.png","height":"109","width":"400"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/106241","about":["Wiki"],"wordCount":920,"articleBody":"\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\uff08\u30b9\u30de\u30a4\u30eb\u30b9\u3066\u3093\u3044\u3001\u82f1: Smiles rearrangement\uff09\u306f\u3001\u6709\u6a5f\u53cd\u5fdc\u304a\u3088\u3073\u8ee2\u4f4d\u53cd\u5fdc\u306e\u4e00\u3064\u3067\u3042\u308b[1]\u3002\u5206\u5b50\u5185\u82b3\u9999\u65cf\u6c42\u6838\u7f6e\u63db\u53cd\u5fdc\u306b\u5206\u985e\u3055\u308c\u308b\u3002  X\u306f\u30b9\u30eb\u30db\u30f3\u3001\u30b9\u30eb\u30d5\u30a3\u30c9\u3001\u30a8\u30fc\u30c6\u30eb\u306a\u3069\u30a2\u30ec\u30fc\u30f3\u304b\u3089\u8131\u96e2\u3067\u304d\u308b\u4efb\u610f\u306e\u7f6e\u63db\u57fa\u3002\u5b98\u80fd\u57fa\u9396\u306e\u672b\u7aef\u306eY\u306f\u30a2\u30eb\u30b3\u30fc\u30eb\u3084\u30a2\u30df\u30f3\u3001\u30c1\u30aa\u30fc\u30eb\u306a\u3069\u306e\u6c42\u6838\u6027\u304c\u5f37\u3044\u57fa\u3002\u4ed6\u306e\u82b3\u9999\u65cf\u6c42\u6838\u7f6e\u63db\u53cd\u5fdc\u306e\u3088\u3046\u306b\u30aa\u30eb\u30c8\u4f4d\u306e\u6975\u6027\u52b9\u679c\u306b\u3088\u308b\u6d3b\u6027\u5316\u3092\u5fc5\u8981\u3068\u3059\u308b\u3002\u30c8\u30eb\u30fc\u30b9\u30fb\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u3068\u547c\u3070\u308c\u308b\u6539\u826f\u578b\u306f\u3001\u6709\u6a5f\u30ea\u30c1\u30a6\u30e0\u3092\u4f7f\u3046\u3053\u3068\u306b\u3088\u308a\u5165\u3063\u3066\u304f\u308b\u6c42\u6838\u6027\u57fa\u306e\u5f37\u3044\u4ed8\u52a0\u7684\u6d3b\u6027\u3092\u5fc5\u8981\u3068\u3057\u306a\u3044\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u30a2\u30ea\u30fc\u30eb\u30b9\u30eb\u30db\u30f3\u304b\u3089n-\u30d6\u30c1\u30eb\u30ea\u30c1\u30a6\u30e0\u306e\u4f5c\u7528\u306b\u3088\u308b\u30b9\u30eb\u30d5\u30a3\u30f3\u9178\u3078\u306e\u5909\u63db\u306b\u3088\u3063\u3066\u5b9f\u8a3c\u3055\u308c\u305f[2]\u3002  \u3053\u306e\u53cd\u5fdc\u306f\u30a2\u30eb\u30ad\u30eb\u30ea\u30c1\u30a6\u30e0\u3068\u305d\u306e\u30aa\u30eb\u30c8\u4f4d\u306e\u30b9\u30eb\u30db\u30f3\u3068\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u5fc5\u8981\u3068\u3059\u308b\u3002\u6982\u5ff5\u7684\u306b\u95a2\u9023\u3059\u308b\u53cd\u5fdc\u306b\u30c1\u30e3\u30c3\u30d7\u30de\u30f3\u8ee2\u4f4d\u304c\u3042\u308b\u3002\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u306e\u30e9\u30b8\u30ab\u30eb\u7248\u304c2015\u5e74\u306bStephenson\u306b\u3088\u3063\u3066\u5831\u544a\u3055\u308c\u305f[3]\u3002\u6797\u8ee2\u4f4d\u306f\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d\u306e\u967d\u30a4\u30aa\u30f3\u7248\u3068\u8003\u3048\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002  ^ Levy, Arthur A.; Rains, Harry C.; Smiles, Samuel (1931). \u201cCCCCLII.\u2014The rearrangement of hydroxy-sulphones. Part I\u201d. J. Chem. Soc.:  3264\u20133269. doi:10.1039\/JR9310003264.\u00a0^ William E. Truce, William J. Ray, Oscar L. Norman, and Daniel B. Eickemeyer (‘1958). \u201cRearrangements of Aryl Sulfones. I. The Metalation and Rearrangement of Mesityl Phenyl Sulfone\u201d. J. Am. Chem. Soc. 80 (14):  3625 – 3629. doi:10.1021\/ja01547a038.\u00a0^ Douglas, James J.; Albright, Haley; Sevrin, Martin J.; Cole, Kevin P.; Stephenson, Corey R. J. (2015). \u201cA Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 Antagonist\u201d. Angew. Chem. Int. Ed.. doi:10.1002\/anie.201507369.\u00a0\u53c2\u8003\u6587\u732e[\u7de8\u96c6]"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki22\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki22\/archives\/106241#breadcrumbitem","name":"\u30b9\u30de\u30a4\u30eb\u30b9\u8ee2\u4f4d – Wikipedia"}}]}]