[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/288514#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/288514","headline":"\u30d9\u30f3\u30be\u30ad\u30ce\u30f3 – Wikipedia","name":"\u30d9\u30f3\u30be\u30ad\u30ce\u30f3 – Wikipedia","description":"before-content-x4 \u30aa\u30eb\u30c8-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u5de6\uff09\u3068\u30d1\u30e9-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u53f3\uff09 \u30d9\u30f3\u30be\u30ad\u30ce\u30f3 (benzoquinone) \u3068\u306f\u3001\u5206\u5b50\u5f0fC6H4O2\u3067\u8868\u3055\u308c\u308b\u6709\u6a5f\u5316\u5408\u7269\u3067\u3042\u308a\u3001\u70ad\u7d20\u306e\u307f\u3067\u69cb\u6210\u3055\u308c\u305f1\u3064\u306e6\u54e1\u74b0\u304b\u3089\u306a\u308b\u30ad\u30ce\u30f3\u3067\u3042\u308b\u30022\u7a2e\u985e\u306e\u69cb\u9020\u7570\u6027\u4f53\u304c\u5b58\u5728\u3057\u30011,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u30d1\u30e9-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001p-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001\u30d1\u30e9-\u30ad\u30ce\u30f3\u3001just quinone\uff09\u304c\u4e00\u822c\u7684\u3067\u3042\u308a\u30011,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u30aa\u30eb\u30c8-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001o-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001\u30aa\u30eb\u30c8-\u30ad\u30ce\u30f3\uff09\u306f\u4e00\u822c\u7684\u3067\u306f\u306a\u3044\u3002 after-content-x4 Table of Contents 1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6]\u5408\u6210[\u7de8\u96c6]\u6709\u6a5f\u5408\u6210\u3078\u306e\u5229\u7528[\u7de8\u96c6]\u91cd\u5408\u7981\u6b62\u5264[\u7de8\u96c6]\u95a2\u9023\u7269\u8cea[\u7de8\u96c6]1,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6] 1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6] \u7d14\u7c8b\u306a1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u5869\u7d20\u306b\u4f3c\u305f\u7279\u5fb4\u7684\u306a\u523a\u6fc0\u81ed\u306e\u3059\u308b\u9ec4\u8272\u7d50\u6676\u3092\u5f62\u6210\u3059\u308b\u3002\u7d14\u7c8b\u3067\u306a\u3044\u3082\u306e\u306f\u30011,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3068\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u306e1\uff1a1\u306e\u6df7\u5408\u7269\u3067\u3042\u308b\u30ad\u30f3\u30d2\u30c9\u30ed\u30f3\u304c\u4e0d\u7d14\u7269\u3068\u3057\u3066\u542b\u307e\u308c\u308b\u305f\u3081\u3001\u3057\u3070\u3057\u6697\u8272\u3092\u5448\u3059\u308b\u3002\u3053\u306e6\u54e1\u74b0\u5316\u5408\u7269\u306f\u30011,4-\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u306e\u9178\u5316\u8a98\u5c0e\u4f53\u3068\u3057\u3066\u5f97\u3089\u308c\u308b[1]\u30021,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306e\u5206\u5b50\u306f\u591a\u6570\u306e\u6027\u8cea\u3092\u6709\u3057\u3066\u3044\u308b\u3002\u30b1\u30c8\u30f3\u306e\u6027\u8cea\u3068\u3057\u3066\u30aa\u30ad\u30b7\u30e0\u3092\u5f62\u6210\u3057\u3001\u9178\u5316\u5264\u306e\u6027\u8cea\u3068\u3057\u3066\uff08\u9178\u5316\u5264\u3068\u3057\u3066\u53cd\u5fdc\u3057\u305f\u969b\u306b\u81ea\u8eab\u306f\u9084\u5143\u3055\u308c\u308b\u305f\u3081\uff09\u30b8\u30d2\u30c9\u30ed\u30ad\u30b7\u8a98\u5c0e\u4f53\uff081,4-\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\uff09\u3092\u5f62\u6210\u3057\u3001\u30a2\u30eb\u30b1\u30f3\u306e\u6027\u8cea\u3068\u3057\u3066\u4ed8\u52a0\u53cd\u5fdc\u3092\u7d4c\u3066\u03b1,\u03b2-\u4e0d\u98fd\u548c\u30b1\u30c8\u30f3\u3092\u5f62\u6210\u3059\u308b\u30021,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u5f37\u3044\u9271\u9178\u304a\u3088\u3073\u30a2\u30eb\u30ab\u30ea\u306e\u4e21\u65b9\u306b\u5bfe\u3057\u3066\u654f\u611f\u3067\u3042\u308a\u3001\u5316\u5408\u7269\u306e\u7e2e\u5408\u3068\u5206\u89e3\u306e\u539f\u56e0\u3068\u306a\u308b\u3002 after-content-x4 \u5408\u6210[\u7de8\u96c6] 1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u30a2\u30cb\u30ea\u30f3\u3084p-\u30d5\u30a7\u30cb\u30ec\u30f3\u30b8\u30a2\u30df\u30f3\u3092\u9178\u5316\u3055\u305b\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u5f97\u3089\u308c\u308b[2]\u3002\u307e\u305f\u3001\u30d5\u30a7\u30ce\u30fc\u30eb\u3092\u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u6eb6\u5a92\u4e2d\u306b\u304a\u3044\u3066\u904e\u9178\u5316\u6c34\u7d20\u3067\u9178\u5316\u3055\u305b\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u30ab\u30c6\u30b3\u30fc\u30eb\u3001\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u3068\u306e\u6df7\u5408\u7269\u3068\u3057\u3066\u5f97\u3089\u308c\u308b[3]\u3002 \u6709\u6a5f\u5408\u6210\u3078\u306e\u5229\u7528[\u7de8\u96c6] 1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u6709\u6a5f\u5408\u6210\u306b\u304a\u3044\u3066\u6c34\u7d20\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u304a\u3088\u3073\u9178\u5316\u5264\u3068\u3057\u3066\u7528\u3044\u3089\u308c\u308b[4]\u3002\u307e\u305f\u3001\u8131\u6c34\u7d20\u5264\u3068\u3057\u3066\u3082\u5229\u7528\u3067\u304d\u308b\u3002\u30c7\u30a3\u30fc\u30eb\u30b9\u30fb\u30a2\u30eb\u30c0\u30fc\u53cd\u5fdc\u306b\u304a\u3051\u308b\u89aa\u30b8\u30a8\u30f3\u4f53\u3068\u3057\u3066\u3082\u7528\u3044\u3089\u308c\u308b[5]\u3002 \u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u7121\u6c34\u9162\u9178\u304a\u3088\u3073\u786b\u9178\u3068\u53cd\u5fdc\u3057\u3066\u30d2\u30c9\u30ed\u30ad\u30b7\u30ad\u30ce\u30fc\u30eb\u306e3\u9162\u9178\u5869\u3092\u4e0e\u3048\u3001\u3053\u306e\u53cd\u5fdc\u306f1898\u5e74\u306b\u3053\u308c\u3092\u521d\u3081\u3066\u8a18\u8ff0\u3057\u305fJohannes Thiele\u306b\u3061\u306a\u3093\u3067Thiele","datePublished":"2022-04-26","dateModified":"2022-04-26","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/66\/Benzoquinones.png\/300px-Benzoquinones.png","url":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/6\/66\/Benzoquinones.png\/300px-Benzoquinones.png","height":"168","width":"300"},"url":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/288514","about":["Wiki"],"wordCount":2876,"articleBody":"     (adsbygoogle = window.adsbygoogle || []).push({});before-content-x4  \u30aa\u30eb\u30c8-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u5de6\uff09\u3068\u30d1\u30e9-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u53f3\uff09\u30d9\u30f3\u30be\u30ad\u30ce\u30f3 (benzoquinone) \u3068\u306f\u3001\u5206\u5b50\u5f0fC6H4O2\u3067\u8868\u3055\u308c\u308b\u6709\u6a5f\u5316\u5408\u7269\u3067\u3042\u308a\u3001\u70ad\u7d20\u306e\u307f\u3067\u69cb\u6210\u3055\u308c\u305f1\u3064\u306e6\u54e1\u74b0\u304b\u3089\u306a\u308b\u30ad\u30ce\u30f3\u3067\u3042\u308b\u30022\u7a2e\u985e\u306e\u69cb\u9020\u7570\u6027\u4f53\u304c\u5b58\u5728\u3057\u30011,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u30d1\u30e9-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001p-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001\u30d1\u30e9-\u30ad\u30ce\u30f3\u3001just quinone\uff09\u304c\u4e00\u822c\u7684\u3067\u3042\u308a\u30011,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\uff08\u30aa\u30eb\u30c8-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001o-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3001\u30aa\u30eb\u30c8-\u30ad\u30ce\u30f3\uff09\u306f\u4e00\u822c\u7684\u3067\u306f\u306a\u3044\u3002       (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4Table of Contents1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6]\u5408\u6210[\u7de8\u96c6]\u6709\u6a5f\u5408\u6210\u3078\u306e\u5229\u7528[\u7de8\u96c6]\u91cd\u5408\u7981\u6b62\u5264[\u7de8\u96c6]\u95a2\u9023\u7269\u8cea[\u7de8\u96c6]1,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3[\u7de8\u96c6]\u7d14\u7c8b\u306a1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u5869\u7d20\u306b\u4f3c\u305f\u7279\u5fb4\u7684\u306a\u523a\u6fc0\u81ed\u306e\u3059\u308b\u9ec4\u8272\u7d50\u6676\u3092\u5f62\u6210\u3059\u308b\u3002\u7d14\u7c8b\u3067\u306a\u3044\u3082\u306e\u306f\u30011,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3068\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u306e1\uff1a1\u306e\u6df7\u5408\u7269\u3067\u3042\u308b\u30ad\u30f3\u30d2\u30c9\u30ed\u30f3\u304c\u4e0d\u7d14\u7269\u3068\u3057\u3066\u542b\u307e\u308c\u308b\u305f\u3081\u3001\u3057\u3070\u3057\u6697\u8272\u3092\u5448\u3059\u308b\u3002\u3053\u306e6\u54e1\u74b0\u5316\u5408\u7269\u306f\u30011,4-\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u306e\u9178\u5316\u8a98\u5c0e\u4f53\u3068\u3057\u3066\u5f97\u3089\u308c\u308b[1]\u30021,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306e\u5206\u5b50\u306f\u591a\u6570\u306e\u6027\u8cea\u3092\u6709\u3057\u3066\u3044\u308b\u3002\u30b1\u30c8\u30f3\u306e\u6027\u8cea\u3068\u3057\u3066\u30aa\u30ad\u30b7\u30e0\u3092\u5f62\u6210\u3057\u3001\u9178\u5316\u5264\u306e\u6027\u8cea\u3068\u3057\u3066\uff08\u9178\u5316\u5264\u3068\u3057\u3066\u53cd\u5fdc\u3057\u305f\u969b\u306b\u81ea\u8eab\u306f\u9084\u5143\u3055\u308c\u308b\u305f\u3081\uff09\u30b8\u30d2\u30c9\u30ed\u30ad\u30b7\u8a98\u5c0e\u4f53\uff081,4-\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\uff09\u3092\u5f62\u6210\u3057\u3001\u30a2\u30eb\u30b1\u30f3\u306e\u6027\u8cea\u3068\u3057\u3066\u4ed8\u52a0\u53cd\u5fdc\u3092\u7d4c\u3066\u03b1,\u03b2-\u4e0d\u98fd\u548c\u30b1\u30c8\u30f3\u3092\u5f62\u6210\u3059\u308b\u30021,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u5f37\u3044\u9271\u9178\u304a\u3088\u3073\u30a2\u30eb\u30ab\u30ea\u306e\u4e21\u65b9\u306b\u5bfe\u3057\u3066\u654f\u611f\u3067\u3042\u308a\u3001\u5316\u5408\u7269\u306e\u7e2e\u5408\u3068\u5206\u89e3\u306e\u539f\u56e0\u3068\u306a\u308b\u3002 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Thiele\u306b\u3061\u306a\u3093\u3067Thiele reaction\u3068\u547c\u3070\u308c\u308b[6]\u3002\u3053\u308c\u306f\u5168\u5408\u6210\u306b\u304a\u3044\u3066\u767a\u898b\u3055\u308c\u305f[7]\u3002\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306f\u30aa\u30ec\u30d5\u30a3\u30f3\u30fb\u30e1\u30bf\u30bb\u30b7\u30b9\u53cd\u5fdc\u4e2d\u306e\u4e8c\u91cd\u7d50\u5408\u306e\u7d44\u307f\u63db\u3048\u3092\u6291\u5236\u3059\u308b\u305f\u3081\u306b\u3082\u7528\u3044\u3089\u308c\u308b\u3002       (adsbygoogle = window.adsbygoogle || 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mendocina (en)\u306e\u83cc\u682a\u306f\u5b89\u606f\u9999\u9178\u306e\u4ee3\u8b1d\u306b\u3088\u3063\u3066\u30ab\u30c6\u30b3\u30fc\u30eb\u3092\u4ecb\u3057\u3066\u6700\u7d42\u751f\u6210\u7269\u3068\u3057\u30661,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3092\u5f97\u3066\u3044\u308b[13]\u3002^ H. W. Underwood, Jr. and W. L. Walsh (1943). “Quinone”. Organic Syntheses (\u82f1\u8a9e).; Collective Volume, 2, p.\u00a0553^ a b c d e f \u5316\u5b66\u5927\u8f9e\u5178\u7de8\u96c6\u59d4\u54e1\u4f1a, ed (1981). \u5316\u5b66\u5927\u8f9e\u51788\u7e2e\u5237\u7248 (\u7b2c26\u7248 ed.). \u5171\u7acb\u51fa\u7248. pp.\u00a0p.518. ISBN\u00a04320040155\u00a0^ \u539f\u7530\u5e78\u660e (2008). \u30ec\u30a2\u30e1\u30bf\u30eb\u306e\u4ee3\u66ff\u6750\u6599\u3068\u30ea\u30b5\u30a4\u30af\u30eb. \u30b7\u30fc\u30a8\u30e0\u30b7\u30fc\u51fa\u7248. pp.\u00a0pp.153-154. ISBN\u00a04781300022\u00a0^ Yang, T.-K.; Shen, C.-Y. \u201c1,4-Benzoquinone\u201d in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. doi:10.1002\/047084289.^ Oda, M.; Kawase, T.; Okada, T.; Enomoto, T. (1998). “2-Cyclohexene-1,4-dione”. Organic Syntheses (\u82f1\u8a9e).; Collective Volume, 9, p.\u00a0186^ Ueber die Einwirkung von Essigs\u00e4ure-anhydrid auf Chinon und auf Dibenzoylstyrol (pp. 1247\u20131249) Johannes Thiele Berichte der deutschen chemischen Gesellschaft Volume 31, Issue 1, pages 1247\u20131249 1898 doi:10.1002\/cber.189803101226^ Stereoselective Total Synthesis and Enantioselective Formal Synthesis of the Antineoplastic Sesquiterpene Quinone Metachromin A Wanda P. Almeida, and Carlos Roque D. Correia J. Braz. Chem. Soc., Vol. 10, No. 5, 401\u2013414, 1999 doi:10.1590\/S0103-50531999000500011.^ \u524d\u7530\u8c4a (2008). \u70ad\u7d20\u7e4a\u7dad\u306e\u5fdc\u7528\u3068\u5e02\u5834. \u30b7\u30fc\u30a8\u30e0\u30b7\u30fc\u51fa\u7248. pp.\u00a0p.60. ISBN\u00a09784781300061\u00a0^ E. A. Braude E. A.; Fawcett, J. S. (1963). “1,4-Naphthoquinone”. Organic Syntheses (\u82f1\u8a9e).; Collective Volume, 4, p.\u00a0698^ Vogel, E.; Klug, W.; Breuer, A. (1988). “1,6-Methano[10]annulene”. Organic Syntheses (\u82f1\u8a9e).; Collective Volume, 6, p.\u00a0731^ Harman, R. E. (1963). “Chloro-p-benzoquinone”. Organic Syntheses (\u82f1\u8a9e).; Collective Volume, 4, p.\u00a0148^ a b Magdziak, D., Rodriguez, A. A.; Van De Water, R. W.; Pettus, T. R. R. (2002). \u201cRegioselective oxidation of phenols to o-quinones with o-iodoxybenzoic acid (IBX)\u201d. Org. Lett. 4 (2):  285\u2013288. doi:10.1021\/ol017068j. PMC\u00a01557836. PMID\u00a011796071. https:\/\/www.ncbi.nlm.nih.gov\/pmc\/articles\/PMC1557836\/.\u00a0^ a b   Chanda Parulekar and Suneela Mavinkurve (2006), Formation of ortho-benzoquinone from sodium benzoate by Pseudomonas mendocina P2d.  Indian Journal of Experimental Biology, volume 44, pages 157–162. Online version accessed on 2010-02-04.^ Enzymatic Browning in Fruits, Vegetables and Seafoods Archived 2011\u5e748\u670822\u65e5, at the Wayback Machine.Section 2.3.2\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]\u30df\u30a4\u30c7\u30e9\u30b4\u30df\u30e0\u30b7 – \u4f53\u5185\u306b\u904e\u9178\u5316\u6c34\u7d20\u3068\u30d2\u30c9\u30ed\u30ad\u30ce\u30f3\u3092\u8caf\u3081\u3066\u304a\u304d\u3001\u3053\u308c\u3089\u3092\u53cd\u5fdc\u3055\u305b\u84b8\u6c17\u3068\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u304b\u3089\u6210\u308b\u9ad8\u6e29\u306e\u6c17\u4f53\u3092\u5674\u5c04\u3059\u308b\u3002     (adsbygoogle = window.adsbygoogle || []).push({});after-content-x4"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki29\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki29\/archives\/288514#breadcrumbitem","name":"\u30d9\u30f3\u30be\u30ad\u30ce\u30f3 – Wikipedia"}}]}]