[{"@context":"http:\/\/schema.org\/","@type":"BlogPosting","@id":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/8296#BlogPosting","mainEntityOfPage":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/8296","headline":"\u91cd\u306a\u308a\u7a4d\u5206 – Wikipedia","name":"\u91cd\u306a\u308a\u7a4d\u5206 – Wikipedia","description":"\u91cf\u5b50\u5316\u5b66\u306b\u304a\u3044\u3066\u3001\u91cd\u306a\u308a\u7a4d\u5206\uff08\u304b\u3055\u306a\u308a\u305b\u304d\u3076\u3093\u3001\u82f1: overlap integral\uff09\u3068\u306f\u539f\u5b50\u8ecc\u9053\u306e\u7a4d\u3092\u542b\u3080\u95a2\u6570\u306e\u7a4d\u5206\u3067\u3042\u308b\u3002 Table of Contents \u76ee\u6b21\u91cd\u306a\u308a\u884c\u5217[\u7de8\u96c6]\u53c2\u8003\u6587\u732e[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6] \u76ee\u6b21 1 \u6982\u8981 2 \u91cd\u306a\u308a\u884c\u5217 3 \u53c2\u8003\u6587\u732e 4 \u95a2\u9023\u9805\u76ee \u5206\u5b50\u3084\u56fa\u4f53\u306e\u306a\u304b\u306e\u96fb\u5b50\u306e\u72b6\u614b\u3092\u8868\u3059\u6ce2\u52d5\u95a2\u6570\u3092\u3001\u898f\u683c\u5316\u3055\u308c\u305f\u539f\u5b50\u8ecc\u9053\u95a2\u6570\u3092\u7d20\u6750\u3068\u3057\u3066\u4f5c\u308b\u3053\u3068\u304c\u591a\u3044\u3002\u3053\u306e\u3068\u304d\u6ce2\u52d5\u95a2\u6570\u3092\u7528\u3044\u3066\u30a8\u30cd\u30eb\u30ae\u30fc\u306a\u3069\u306e\u7269\u7406\u91cf\u3092\u8a08\u7b97\u3059\u308b\u305f\u3081\u306b\u306f\u3001\u539f\u5b50\u8ecc\u9053\u306e\u7a4d\u3092\u542b\u3080\u95a2\u6570\u306e\u7a4d\u5206\uff08\u5206\u5b50\u7a4d\u5206\uff09\u304c\u5fc5\u8981\u306b\u306a\u308b\uff0e\u5206\u5b50\u7a4d\u5206\u306e\u306a\u304b\u3067\u6700\u3082\u3088\u304f\u73fe\u308c\u308b\u7a4d\u5206\u306f\u3001\u539f\u5b50A\u306b\u4e2d\u5fc3\u3092\u3082\u3064\u539f\u5b50\u8ecc\u9053\u95a2\u6570 \u03c7A(r){displaystyle chi _{A}(mathbf","datePublished":"2019-11-02","dateModified":"2019-11-02","author":{"@type":"Person","@id":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/author\/lordneo#Person","name":"lordneo","url":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/author\/lordneo","image":{"@type":"ImageObject","@id":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","url":"https:\/\/secure.gravatar.com\/avatar\/c9645c498c9701c88b89b8537773dd7c?s=96&d=mm&r=g","height":96,"width":96}},"publisher":{"@type":"Organization","name":"Enzyklop\u00e4die","logo":{"@type":"ImageObject","@id":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","url":"https:\/\/wiki.edu.vn\/wiki4\/wp-content\/uploads\/2023\/08\/download.jpg","width":600,"height":60}},"image":{"@type":"ImageObject","@id":"https:\/\/wikimedia.org\/api\/rest_v1\/media\/math\/render\/svg\/84277f74113a4b4fb931378948d0417a87930982","url":"https:\/\/wikimedia.org\/api\/rest_v1\/media\/math\/render\/svg\/84277f74113a4b4fb931378948d0417a87930982","height":"","width":""},"url":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/8296","about":["Wiki"],"wordCount":2080,"articleBody":"\u91cf\u5b50\u5316\u5b66\u306b\u304a\u3044\u3066\u3001\u91cd\u306a\u308a\u7a4d\u5206\uff08\u304b\u3055\u306a\u308a\u305b\u304d\u3076\u3093\u3001\u82f1: overlap integral\uff09\u3068\u306f\u539f\u5b50\u8ecc\u9053\u306e\u7a4d\u3092\u542b\u3080\u95a2\u6570\u306e\u7a4d\u5206\u3067\u3042\u308b\u3002  Table of Contents\u76ee\u6b21\u91cd\u306a\u308a\u884c\u5217[\u7de8\u96c6]\u53c2\u8003\u6587\u732e[\u7de8\u96c6]\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]\u76ee\u6b21  1 \u6982\u89812 \u91cd\u306a\u308a\u884c\u52173 \u53c2\u8003\u6587\u732e4 \u95a2\u9023\u9805\u76ee\u5206\u5b50\u3084\u56fa\u4f53\u306e\u306a\u304b\u306e\u96fb\u5b50\u306e\u72b6\u614b\u3092\u8868\u3059\u6ce2\u52d5\u95a2\u6570\u3092\u3001\u898f\u683c\u5316\u3055\u308c\u305f\u539f\u5b50\u8ecc\u9053\u95a2\u6570\u3092\u7d20\u6750\u3068\u3057\u3066\u4f5c\u308b\u3053\u3068\u304c\u591a\u3044\u3002\u3053\u306e\u3068\u304d\u6ce2\u52d5\u95a2\u6570\u3092\u7528\u3044\u3066\u30a8\u30cd\u30eb\u30ae\u30fc\u306a\u3069\u306e\u7269\u7406\u91cf\u3092\u8a08\u7b97\u3059\u308b\u305f\u3081\u306b\u306f\u3001\u539f\u5b50\u8ecc\u9053\u306e\u7a4d\u3092\u542b\u3080\u95a2\u6570\u306e\u7a4d\u5206\uff08\u5206\u5b50\u7a4d\u5206\uff09\u304c\u5fc5\u8981\u306b\u306a\u308b\uff0e\u5206\u5b50\u7a4d\u5206\u306e\u306a\u304b\u3067\u6700\u3082\u3088\u304f\u73fe\u308c\u308b\u7a4d\u5206\u306f\u3001\u539f\u5b50A\u306b\u4e2d\u5fc3\u3092\u3082\u3064\u539f\u5b50\u8ecc\u9053\u95a2\u6570\u03c7A(r){displaystyle chi _{A}(mathbf {r} )}\u3068\u539f\u5b50B\u306b\u4e2d\u5fc3\u3092\u3082\u3064\u539f\u5b50\u8ecc\u9053\u95a2\u6570\u03c7B(r){displaystyle chi _{B}(mathbf {r} )}\u306b\u95a2\u3059\u308b\u7a4d\u5206  S=\u222b\u03c7A\u2217(r)\u03c7B(r)d\u03c4{displaystyle S=int chi _{A}^{*}(mathbf {r} )chi _{B}(mathbf {r} )dtau }\u3067\u3042\u308b\u3002\u03c7A{displaystyle chi _{A}}\u3068\u03c7B{displaystyle chi _{B}}\u304c\u5168\u304f\u91cd\u306a\u3089\u306a\u3044\u3068\u304d\u306fS=0{displaystyle S=0}\u3067\u3001\u5b8c\u5168\u306b\u91cd\u306a\u308b\u3068\u304d\u306fS=1{displaystyle S=1}\u3067\u3042\u308b\u3002S{displaystyle S}\u306f0\u30681\u306e\u9593\u306e\u5927\u304d\u3055\u3092\u3082\u3064\u91cf\u3067\u3001\u03c7A{displaystyle chi _{A}}\u3068\u03c7B{displaystyle chi _{B}}\u306e\u91cd\u306a\u308a\u306e\u7a0b\u5ea6\u3092\u8868\u3059\u3068\u8003\u3048\u3089\u308c\u308b\u306e\u3067\u91cd\u306a\u308a\u7a4d\u5206\uff08\u307e\u305f\u306f\u91cd\u7573\u7a4d\u5206\uff09\u3068\u3044\u3046\u3002\u5316\u5b66\u53cd\u5fdc\u3092\u8aac\u660e\u3059\u308b\u96fb\u5b50\u5bfe\u7406\u8ad6\u306b\u304a\u3044\u3066\u306f\u3001\u91cd\u306a\u308a\u7a4d\u5206\u304c\u5927\u304d\u3044\u307b\u3069\u5b89\u5b9a\u306a\u96fb\u5b50\u5bfe\u3092\u4f5c\u308a\u3084\u3059\u3044\u3068\u3044\u308f\u308c\u3066\u3044\u308b\u3002\u4e00\u65b9\u3001\u5927\u304d\u306a\u5206\u5b50\u3092\u6271\u3046\u3068\u304d\u306a\u3069\u3067\u3001\u5316\u5b66\u7d50\u5408\u3092\u4f5c\u3063\u3066\u3044\u306a\u3044\u539f\u5b50\u8ecc\u9053\u306e\u91cd\u306a\u308a\u7a4d\u5206\u3092\u7701\u7565\u3059\u308b\u3053\u3068\u3082\u3057\u3070\u3057\u3070\u884c\u308f\u308c\u308b\u3002\u3053\u306e\u3088\u3046\u306a\u53d6\u308a\u6271\u3044\u306e\u5f53\u5426\u306f\u8b70\u8ad6\u306e\u4f59\u5730\u306e\u3042\u308b\u3068\u3053\u308d\u3067\u3042\u308b\u304c\u3001\u5b9f\u9a13\u7d50\u679c\u3092\u7406\u8ad6\u7684\u306b\u8aac\u660e\u3059\u308b\u3068\u3044\u3046\u610f\u5473\u3067\u306f\u90fd\u5408\u306e\u826f\u3044\u3053\u3068\u3082\u591a\u3044\u3002\u5316\u5b66\u7d50\u5408\u3092\u8aac\u660e\u3057\u305f\u8349\u5206\u3051\u306e\u30cf\u30a4\u30c8\u30e9\u30fc\u3001\u30ed\u30f3\u30c9\u30f3\u3001\u6749\u6d66\u7fa9\u52dd\u306e\u8ad6\u6587\u3067\u306f\u3001S2{displaystyle S^{2}}\u306e\u3053\u3068\u3092S{displaystyle S}\u3068\u66f8\u3044\u3066\u3042\u308b\u306e\u3067\u6ce8\u610f\u3092\u8981\u3059\u308b\u3002\u91cd\u306a\u308a\u7a4d\u5206\u306f\u539f\u5b50\u6838\u5185\u306b\u304a\u3051\u308b\u6838\u5b50\u306e\u6ce2\u52d5\u95a2\u6570\u306b\u3064\u3044\u3066\u3082\u539f\u5b50\u3068\u540c\u3058\u3088\u3046\u306b\u7528\u3044\u3089\u308c\u308b\u3002\u91cd\u306a\u308a\u884c\u5217[\u7de8\u96c6]\u91cd\u306a\u308a\u884c\u5217\uff08\u82f1: overlap matrix\uff09\u306f\u3001\u91cf\u5b50\u5316\u5b66\u306b\u304a\u3044\u3066\u4f7f\u308f\u308c\u308b\u6b63\u65b9\u884c\u5217\u3067\u3042\u308b\u3002\u5206\u5b50\u306e\u96fb\u5b50\u69cb\u9020\u8a08\u7b97\u306b\u304a\u3044\u3066\u7528\u3044\u3089\u308c\u308b\u539f\u5b50\u8ecc\u9053\u57fa\u5e95\u95a2\u6570\u7cfb\u3068\u3044\u3063\u305f\u91cf\u5b50\u7cfb\u306e\u4e00\u9023\u306e\u57fa\u5e95\u30d9\u30af\u30c8\u30eb\u306e\u76f8\u4e92\u95a2\u4fc2\u3092\u8a18\u8ff0\u3059\u308b\u305f\u3081\u306b\u7528\u3044\u3089\u308c\u308b\u3002\u5177\u4f53\u7684\u306b\u306f\u3001\u3082\u3057\u30d9\u30af\u30c8\u30eb\u304c\u4e92\u3044\u306b\u76f4\u4ea4\u3057\u3066\u3044\u308b\u3068\u3059\u308b\u3068\u3001\u91cd\u306a\u308a\u884c\u5217\u306f\u5bfe\u89d2\u884c\u5217\u3068\u306a\u308b\u3002\u52a0\u3048\u3066\u3001\u3082\u3057\u57fa\u5e95\u30d9\u30af\u30c8\u30eb\u304c\u6b63\u898f\u76f4\u4ea4\u7cfb\u3092\u5f62\u6210\u3059\u308b\u3068\u3059\u308b\u3068\u3001\u91cd\u306a\u308a\u884c\u5217\u306f\u5358\u4f4d\u884c\u5217\u3068\u306a\u308b\u3002\u91cd\u306a\u308a\u884c\u5217\u306f\u5e38\u306bn\u00d7n\u884c\u5217\uff08n\u306f\u7528\u3044\u3089\u308c\u308b\u57fa\u5e95\u95a2\u6570\u306e\u6570\uff09\u3067\u3042\u308b\u3002\u3053\u308c\u306f\u30b0\u30e9\u30e0\u884c\u5217\u306e\u4e00\u7a2e\u3067\u3042\u308b\u3002\u4e00\u822c\u306b\u3001\u500b\u3005\u306e\u91cd\u306a\u308a\u884c\u5217\u8981\u7d20\u306f1\u3064\u306e\u91cd\u306a\u308a\u7a4d\u5206\u3068\u3057\u3066\u5b9a\u7fa9\u3055\u308c\u308b\u3002Sjk=\u27e8bj|bk\u27e9=\u222b\u03a8j\u2217\u03a8kd\u03c4{displaystyle S_{jk}=langle b_{j}|b_{k}rangle =int Psi _{j}^{*}Psi _{k},dtau }\u4e0a\u5f0f\u306b\u304a\u3044\u3066\u3001|bj\u27e9{displaystyle left|b_{j}rightrangle }\u306f\u3001j\u756a\u76ee\u306e\u57fa\u5e95\u30b1\u30c3\u30c8\uff08\u30d9\u30af\u30c8\u30eb\uff09\u3001\u03a8j{displaystyle Psi _{j}}\u306f\u3001\u03a8j(x)=\u27e8x|bj\u27e9{displaystyle Psi _{j}(x)=leftlangle x|b_{j}rightrangle }\u3068\u5b9a\u7fa9\u3055\u308c\u308bj\u756a\u76ee\u306e\u6ce2\u52d5\u95a2\u6570\u3067\u3042\u308b\u3002\u5177\u4f53\u7684\u306b\u306f\u3001\u57fa\u5e95\u7cfb\u304c\u6b63\u898f\u5316\u3055\u308c\u308b\u3068\uff08\u76f4\u4ea4\u3067\u3042\u308b\u5fc5\u8981\u306f\u306a\u3044\uff09\u3001\u5bfe\u89d2\u8981\u7d20\u306f\u3042\u3089\u3086\u308b\u70b9\u3067\u7b49\u3057\u304f1\u3068\u306a\u308a\u3001\u975e\u5bfe\u89d2\u8981\u7d20\u306e\u5927\u304d\u3055\u306f\u3001\u30b3\u30fc\u30b7\u30fc\uff1d\u30b7\u30e5\u30ef\u30eb\u30c4\u306e\u4e0d\u7b49\u5f0f\u306e\u901a\u308a\u57fa\u5e95\u7cfb\u306b\u304a\u3044\u3066\u4e00\u6b21\u5f93\u5c5e\u304c\u3042\u308b\u6642\u304b\u3064\u305d\u306e\u6642\u306b\u9650\u308a\u30011\u4ee5\u4e0b\u3068\u306a\u308b\u3002\u3055\u3089\u306b\u3001\u3053\u306e\u884c\u5217\u306f\u5e38\u306b\u6b63\u5b9a\u5024\u884c\u5217\u3067\u3042\u308b\u3002\u3059\u306a\u308f\u3061\u3001\u56fa\u6709\u5024\u306f\u5168\u3066\u53b3\u5bc6\u306b\u6b63\u306e\u5024\u3068\u306a\u308b\u3002\u53c2\u8003\u6587\u732e[\u7de8\u96c6]\u300e\u7269\u7406\u5b66\u8f9e\u5178\u300f \u57f9\u98a8\u9928\u30011984\u5e74\u95a2\u9023\u9805\u76ee[\u7de8\u96c6]\u30ed\u30fc\u30bf\u30fc\u30f3\u65b9\u7a0b\u5f0f\u30cf\u30fc\u30c8\u30ea\u30fc-\u30d5\u30a9\u30c3\u30af\u65b9\u7a0b\u5f0f"},{"@context":"http:\/\/schema.org\/","@type":"BreadcrumbList","itemListElement":[{"@type":"ListItem","position":1,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki6\/#breadcrumbitem","name":"Enzyklop\u00e4die"}},{"@type":"ListItem","position":2,"item":{"@id":"https:\/\/wiki.edu.vn\/jp\/wiki6\/archives\/8296#breadcrumbitem","name":"\u91cd\u306a\u308a\u7a4d\u5206 – Wikipedia"}}]}]