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This page provides supplementary chemical data on 1,2-dichloroethane.
Table of Contents
Structure and properties[edit]
Thermodynamic properties[edit]
Phase behavior
Triple point
237.2 K (–35.9 °C), ? Pa
Critical point
561.6 K (288.5 °C), 5380 kPa
Std enthalpy change of fusion, ΔfusHo
8.8366 kJ/mol at –35.9 °C
Std entropy change of fusion, ΔfusSo
37.25 J/(mol·K) at –35.9 °C
Std enthalpy change of vaporization, ΔvapHo
33.91 kJ/mol at 20 °C
Std entropy change of vaporization, ΔvapSo
? J/(mol·K)
Solid properties
Std enthalpy change of formation, ΔfHosolid
? kJ/mol
Standard molar entropy, Sosolid
? J/(mol K)
Heat capacity, cp
? J/(mol K)
Liquid properties
Std enthalpy change of formation, ΔfHoliquid
–169.7 kJ/mol
Standard molar entropy, Soliquid
208.53 J/(mol K)
Enthalpy of combustion, ΔcHoliquid
–1236.4 kJ/mol
Heat capacity, cp
129.0 J/(mol K)
Gas properties
Std enthalpy change of formation, ΔfHogas
–125.4 kJ/mol
Standard molar entropy, Sogas
? J/(mol K)
Heat capacity, cp
77.5 J/(mol K) at 25 °C
Vapor pressure of liquid[edit]
P in mm Hg
1
10
40
100
400
760
1520
3800
7600
15200
30400
45600
T in °C
–44.5(s)
–13.6
10.0
29.4
64.0
83.4
108.1
147.8
183.5
226.5
272.0
—
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. The (s) annotation indicates temperature is equilibrium of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid.
log10 of 1,2-dichloroethane vapor pressure. Uses formula: obtained from CHERIC[5]
Distillation data[edit]
See also:
Vapor-liquid equilibrium of 1,2-Dichloroethylene/ Methanol[6] P = 96.7 kPa
BP Temp. °C
% by mole methanol
liquid
vapor
63.3
100.00
100.00
60.2
92.01
82.50
59.3
79.52
72.06
58.9
69.03
66.43
59.1
63.50
63.50
59.0
59.02
63.27
59.3
47.91
63.25
59.6
43.02
62.55
61.8
15.03
54.15
66.7
6.01
42.03
82.15
0.00
0.0
Vapor-liquid equilibrium of 1,2-Dichloroethylene/ Ethanol[6] P = 760 mm Hg
BP Temp. °C
% by mole ethanol
liquid
vapor
79.9
3.0
13.0
78.0
4.2
19.5
76.7
7.3
23.3
74.1
11.3
31.5
72.6
15.2
36.0
70.9
28.3
43.6
70.5
34.5
45.2
70.2
42.5
47.8
70.1
48.8
49.8
70.2
59.8
53.5
70.8
70.5
58.2
71.4
76.5
62.8
72.1
81.7
67.0
74.7
92.3
81.7
75.7
94.8
86.5
77.3
97.8
94.5
Vapor-liquid equilibrium of 1,2-Dichloroethylene/ Toluene[6] P = 760 mm Hg
BP Temp. °C
% by mole dichloroethane
liquid
vapor
85.5
89.7
94.2
87.5
80.1
89.2
89.1
69.8
82.1
91.3
60.5
78.2
92.9
54.0
72.5
94.6
48.2
66.3
97.1
39.8
60.3
97.8
36.4
55.0
101.5
26.2
42.4
102.7
20.0
34.8
105.7
14.0
27.5
108.1
7.0
16.9
109.1
1.8
6.6
Vapor-liquid equilibrium of 1,2-Dichloroethylene/ Cyclohexane[6] P = 760 mm Hg
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